SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Product identifier FR Clothing Insect Repellent
Other means of identification
Product code
Registration number
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name
Address
Telephone
General Information
Technical
Assistance
Customer Service
24-Hour Emergency
(CHEMTREC)
Website
14036
EPA: 1021-1746-55809
Insecticide for controlling mosquitos and ticks
None known.
CRC Industries, Inc.
885 Louis Dr.
Warminster, PA 18974 US
215-674-4300
800-521-3168
800-272-4620
800-424-9300 (US)
703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Liquefied gasGases under pressure
Category 2Skin corrosion/irritation
Category 2BSerious eye damage/eye irritation
Category 1Sensitization, skin
Category 1Hazardous to the aquatic environment, acute
hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Warning
Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic
skin reaction. Causes eye irritation. Very toxic to aquatic life. Toxic to aquatic life with long lasting
effects.
Do not puncture or incinerate container. Do not expose to heat or store at temperatures above
49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to
ensure a fresh air supply during use and while product is drying. If you experience any symptoms
listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Avoid
breathing gas. Wash thoroughly after handling. Avoid release to the environment. Wear protective
gloves.
If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention. Wash contaminated
clothing before reuse. Collect spillage.
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
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Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
10.2% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 10.2% of the mixture
consists of component(s) of unknown long-term hazards to the aquatic environment.
Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause
can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
7732-18-5Water
68476-86-8Liquefied petroleum gas
64742-47-8Distillates (petroleum), hydrotreated
light
52645-53-1Permethrin
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air. Call a POISON CENTER or doctor/physician if you feel unwell. If person is not
breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if
possible.
Wash off with soap and water. In case of eczema or other skin disorders: Seek medical attention
and take along these instructions. For minor skin contact, avoid spreading material on unaffected
skin. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Never give anything by mouth to a victim who is unconscious or is having
convulsions. Do not induce vomiting without advice from poison control center. IF SWALLOWED:
Call a POISON CENTER or doctor/physician if you feel unwell. Do not give any liquid to the
person.
Dermatitis. Rash. Exposed individuals may experience eye tearing, redness, and discomfort. May
cause an allergic skin reaction. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.
80 - 90
10 - 20
5 - 10
0.5
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Foam. Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation
of vapors or mists. Avoid breathing gas. Do not touch damaged containers or spilled material
unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities
should be advised if significant spillages cannot be contained. For personal protection, see section
8 of the SDS.
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Methods and materials for
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. NIOSH: Pocket Guide to Chemical Hazards
wash facilities and emergency shower must be available when handling this product.
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Stop the flow of material, if this is without risk. Absorb spillage with non-combustible, absorbent
material. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with
absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around
energized equipment. The metal container will conduct electricity if it contacts a live source. This
may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or
vapor. Avoid breathing gas. Avoid contact with skin and eyes. Use only in well-ventilated areas.
Wear appropriate personal protective equipment. For product usage instructions, please see the
product label. Observe good industrial hygiene practices. Avoid release to the environment. Do not
empty into drains.
Level 1 Aerosol.
Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C as
can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. Store in a well-ventilated place. Store away from food or pet food.
Always store pesticides in the original container. Store away from incompatible materials (see
Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
TWA 100 mg/m3Distillates (petroleum),
hydrotreated light (CAS
64742-47-8)
Biological limit values
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear protective gloves such as: Chemical resistant gloves.
Wear appropriate chemical resistant clothing.
In case of insufficient ventilation, wear suitable respiratory equipment. Air monitoring is needed to
determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Do not eat, drink or smoke when using the product.
ValueComponents Type
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
Liquid.
Aerosol.
Milky white.
Petroleum distillates.
Not available.
SDS US
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pH
Ingestion
Inhalation
Skin contact
Eye contact
Acute toxicity
Melting point/freezing point
Initial boiling point and boiling
6.8
32 °F (0 °C) estimated
212 °F (100 °C) estimated
range
Flash point
Evaporation rate
Flammability (solid, gas)
None.
Not available.
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not applicable.
(%)
Flammability limit - upper
Not applicable.
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
501.6 hPa estimated
> 1 (air = 1)
0.98
Partially miscible.
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Not available.
Not available.
4.5 cP (73.4 °F (23 °C))
96.2 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
Strong acids. Strong oxidizing agents. Strong bases.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Expected to be a low ingestion hazard.
No adverse effects due to inhalation are expected.
Causes skin irritation. May cause an allergic skin reaction.
Causes eye irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
FR Clothing Insect Repellent
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Dermatitis. Rash. May cause redness and pain. May cause an allergic skin reaction. Exposed
individuals may experience eye tearing, redness, and discomfort.
May cause an allergic skin reaction.
Test ResultsProduct Species
> 5000 mg/kg
> 20 mg/l, 4 hours
Material name: FR Clothing Insect Repellent
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Oral
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Partition coefficient n-octanol / water (log Kow)
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes eye irritation.
irritation
Based on available data, the classification criteria are not met.
Skin sensitization
Germ cell mutagenicity
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Permethrin (CAS 52645-53-1) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Specific target organ toxicity -
Not available.
Not available.
single exposure
Specific target organ toxicity -
Not available.
repeated exposure
Based on available data, the classification criteria are not met.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
FR Clothing Insect Repellent
Aquatic
Components Test ResultsSpecies
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Aquatic
Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Accumulation in aquatic
organisms is expected.
EC50Crustacea 5.0529 mg/l, 48 hours estimatedDaphnia
LC50Fish 4.9393 mg/l, 96 hours estimatedFish
Test ResultsProduct Species
> 5000 mg/kg
LC50Fish 45 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Permethrin (CAS 52645-53-1)
Aquatic
EC50Crustacea 0.0006 - 0.0025 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 0.0013 - 0.0022 mg/l, 96 hoursApache trout (Oncorhynchus gilae
apache)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
No data available.
Permethrin 6.5
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
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13. Disposal considerations
waste agency for disposal instructions. Contents under pressure. Do not puncture, incinerate or
waterways or ditches with chemical or used container. Dispose in accordance with all applicable
Disposal of waste from
residues / unused products
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33).
If empty: Place in trash or offer for recycling this container. If partly filled: Call your local solid
crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds,
regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
UN1950
Aerosols, non-flammable, Limited Quantity
2.2
-
2.2
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
306
None
None
UN1950
Aerosols, non-flammable, Limited Quantity
2.2
Not applicable.
No.
2L
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1950
AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANT
2
Not applicable.
Yes
Not available.
Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
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US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
Food and Drug
Not regulated.
Administration (FDA)
US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)
FIFRA Information
This chemical is a pesticide product registered by the United States Environmental Protection
Agency and is subject to certain labeling requirements under federal pesticide law. These
requirements differ from the classification criteria and hazard information required for safety data
sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information
required on the pesticide label is reproduced below. The pesticide label also includes other
important information, including directions for use.
Signal word
Caution.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. New Jersey Worker and Community Right-to-Know Act
Permethrin (CAS 52645-53-1)
US. Massachusetts RTK - Substance List
None.
US. Pennsylvania Worker and Community Right-to-Know Law
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
US. Rhode Island RTK
None.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
YesAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
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Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Disclaimer
Revision Information
03-27-2014
03-27-2014
Allison Cho
03
Not available.
Health: 2
Flammability: 1
Physical hazard: 0
Personal protection: B
Health: 2
Flammability: 1
Instability: 0
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Physical & Chemical Properties: Multiple Properties
Toxicological Information: Toxicological Property Data
Regulatory Information: United States
GHS: Classification
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
SDS US
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