CRC 14036 User Manual

SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Product identifier FR Clothing Insect Repellent
Other means of identification
Product code
Registration number
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
14036
EPA: 1021-1746-55809
Insecticide for controlling mosquitos and ticks
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Liquefied gasGases under pressure
Category 2Skin corrosion/irritation
Category 2BSerious eye damage/eye irritation
Category 1Sensitization, skin
Category 1Hazardous to the aquatic environment, acute
hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Warning
Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Causes eye irritation. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Avoid breathing gas. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves.
If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Wash contaminated clothing before reuse. Collect spillage.
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
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Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
10.2% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 10.2% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
7732-18-5Water
68476-86-8Liquefied petroleum gas
64742-47-8Distillates (petroleum), hydrotreated
light
52645-53-1Permethrin
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a POISON CENTER or doctor/physician if you feel unwell. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible.
Wash off with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. For minor skin contact, avoid spreading material on unaffected skin. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Do not give any liquid to the person.
Dermatitis. Rash. Exposed individuals may experience eye tearing, redness, and discomfort. May cause an allergic skin reaction. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
80 - 90
10 - 20
5 - 10
0.5
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
Foam. Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors or mists. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
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Methods and materials for
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. NIOSH: Pocket Guide to Chemical Hazards
wash facilities and emergency shower must be available when handling this product.
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Absorb spillage with non-combustible, absorbent material. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with skin and eyes. Use only in well-ventilated areas. Wear appropriate personal protective equipment. For product usage instructions, please see the product label. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains.
Level 1 Aerosol.
Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from food or pet food. Always store pesticides in the original container. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
TWA 100 mg/m3Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Biological limit values
Appropriate engineering controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene considerations
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear protective gloves such as: Chemical resistant gloves.
Wear appropriate chemical resistant clothing.
In case of insufficient ventilation, wear suitable respiratory equipment. Air monitoring is needed to determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Do not eat, drink or smoke when using the product.
ValueComponents Type
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
Material name: FR Clothing Insect Repellent
2423 Version #: 03 Revision date: 03-27-2014 Issue date: 03-27-2014
Liquid.
Aerosol.
Milky white.
Petroleum distillates.
Not available.
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