Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Hazardous to the aquatic environment, acute
hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if
swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin
reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life.
Harmful to aquatic life with long lasting effects.
Material name: Insect Repellent
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Precautionary statement
32.11% of the mixture consists of component(s) of unknown acute oral toxicity. 32.11% of the mixture consists of component(s) of
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Do not apply while equipment is energized. Pressurized container:
Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will
accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during
use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh
air supply during use and while product is drying. If you experience any symptoms listed on this
label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must
not be allowed out of the workplace. Wear protective gloves/protective clothing. Wear eye/face
protection. Avoid release to the environment.
Response
If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with
plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated
clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
Storage
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to
temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Disposal
Hazard(s) not otherwise
classified (HNOC)
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information
unknown acute dermal toxicity. 72.39% of the mixture consists of component(s) of unknown long-term hazards to the aquatic
environment.
3. Composition/information on ingredients
Mixtures
CAS number%Common name and synonymsChemical name
67-63-0Isopropyl alcohol
134-62-3N,N-Diethyl-m-toluamide (DEET)
68476-86-8Liquefied Petroleum Gas
113-48-4Dicarboximide
136-45-8Dipropyl isocinchomeronate
67-64-1Acetone
57-55-6Propylene glycol
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated
clothing before reuse.
30 - 40
25.1
20 - 30
5 - 10
2.5
1 - 3
1 - 3
Material name: Insect Repellent
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5. Fire-fighting measures
water and will spread on the water surface. Stop the flow of material, if this is without risk. Prevent
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
General fire hazards
Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This
product is a poor conductor of electricity and can become electrostatically charged. If sufficient
charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation
may be significantly increased by the presence of small quantities of water or other contaminants.
Material will float and may ignite on surface of water. During fire, gases hazardous to health may
be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when
exposed to heat or flame.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are
heavier than air and will spread along ground and collect in low or confined areas (sewers,
basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid
breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ventilate closed spaces before entering them. Use appropriate containment to avoid
environmental contamination. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases. Use appropriate containment to avoid
environmental contamination.
Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized
container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective.
Do not spray on a naked flame or any other incandescent material. Do not smoke while using or
until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to
heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The
metal container will conduct electricity if it contacts a live source. This may result in injury to the
user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes,
skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. Wash
contaminated clothing before reuse. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to
remove static electricity. Store in a well-ventilated place. Store away from incompatible materials
(see Section 10 of the SDS).
Material name: Insect Repellent
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8. Exposure controls/personal protection
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
67-63-0)
* - For sampling details, please see the source document.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Viton®.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards
General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Keep away from food and drink. Always observe good personal
hygiene measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Contaminated work clothing should not be allowed out of the workplace.
ValueComponents
Form
*
*
Material name: Insect Repellent
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9. Physical and chemical properties
Inhalation
Skin contact
Eye contact
Ingestion
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Clear. Colorless.
Mild. Alcoholic.
Not available.
Not available.
-138.5 °F (-94.7 °C) estimated
132.9 °F (56.1 °C) estimated
75 °F (23.9 °C) Tag Closed Cup
Moderate.
Not available.
2 % estimated
12.8 % estimated
1234.3 hPa estimated
> 1 (air = 1)
0.8 estimated
Immiscible.
Not available.
700 °F (371.1 °C) estimated
Not available.
Not available.
67.3 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Material name: Insect Repellent
14011 Version #: 01 Issue date: 05-21-2015
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and
central nervous system effects. Harmful in contact with skin. Harmful if swallowed. Narcotic
effects. May cause an allergic skin reaction.
SDS US
5 / 10
Insect Repellent
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Acute
Acute
Dermal
LD50Rabbit1380 mg/kg estimated
Inhalation
LC50Rat40990 ppm, 4 hours estimated
Oral
LD50Rat1737 mg/kg estimated
TDL0Human117 g/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes serious eye irritation.
irritation
Not a respiratory sensitizer.
Skin sensitization
Germ cell mutagenicity
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not an aspiration hazard.
Test ResultsProductSpecies
12 mg/l, 4 Hours estimated
12. Ecological information
Ecotoxicity
ProductTest ResultsSpecies
Insect Repellent
Aquatic
ComponentsTest ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
Isopropyl alcohol (CAS 67-63-0)
Aquatic
N,N-Diethyl-m-toluamide (DEET) (CAS 134-62-3)
Aquatic
Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from
residues / unused products
If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or
dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not
puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not
contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
D001: Waste Flammable material with a flash point <140 F
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
UN1950
Aerosols, flammable, Limited Quantity
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable, Limited Quantity
2.1
Not applicable.
No.
10L
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
Material name: Insect Repellent
14011 Version #: 01 Issue date: 05-21-2015
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IMDG
UN number
UN proper shipping name
UN1950
AEROSOLS, LIMITED QUANTITY
Transport hazard class(es)
Class
Subsidiary risk
Packing group
2
Not applicable.
Environmental hazards
Marine pollutant
EmS
Special precautions for user
No.
Not available.
Read safety instructions, SDS and emergency procedures before handling.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
Acetone (CAS 67-64-1)6532
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)6532
Food and Drug
Administration (FDA)
US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA)
FIFRA Information
Signal word
Hazard statement
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Not regulated.
Not regulated.
This chemical is a pesticide product registered by the United States Environmental Protection
Agency and is subject to certain labeling requirements under federal pesticide law. These
requirements differ from the classification criteria and hazard information required for safety data
sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information
required on the pesticide label is reproduced below. The pesticide label also includes other
important information, including directions for use.
Warning.
Harmful if swallowed. Causes substantial but temporary eye injury.
This product is registered in all 50 United States and Puerto Rico. This product is not registered
outside of the United States and Puerto Rico.
Material name: Insect Repellent
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Propylene glycol (CAS 57-55-6)
Dipropyl isocinchomeronate (CAS 136-45-8)
Isopropyl alcohol (CAS 67-63-0)
US. Massachusetts RTK - Substance List
Acetone (CAS 67-64-1)
Isopropyl alcohol (CAS 67-63-0)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Isopropyl alcohol (CAS 67-63-0)
Propylene glycol (CAS 57-55-6)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Dipropyl isocinchomeronate (CAS 136-45-8)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2)Listed: February 27, 1987
Cumene (CAS 98-82-8)Listed: April 6, 2010
Dipropyl isocinchomeronate (CAS 136-45-8)Listed: May 1, 1996
Ethanal (CAS 75-07-0)Listed: April 1, 1988
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Toluene (CAS 108-88-3)Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
Toluene (CAS 108-88-3)Listed: August 7, 2009
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
64.9 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
This product is regulated as an Insect Repellent. This product is compliant for use in all 50 states.
64.9 %
64.9 %
Material name: Insect Repellent
14011 Version #: 01 Issue date: 05-21-2015
SDS US
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International Inventories
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Country(s) or regionInventory nameOn inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
05-21-2015
Allison Cho
01
CRC # 926
Health: 1
Flammability: 3
Physical hazard: 0
Personal protection: B
Health: 1
Flammability: 3
Instability: 0
3
01
YesAustraliaAustralian Inventory of Chemical Substances (AICS)
YesCanadaDomestic Substances List (DSL)
NoCanadaNon-Domestic Substances List (NDSL)
NoChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial Chemical
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
NoKoreaExisting Chemicals List (ECL)
YesNew ZealandNew Zealand Inventory
NoPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) Inventory
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Material name: Insect Repellent
14011 Version #: 01 Issue date: 05-21-2015
SDS US
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