CRC 125-14411 User Manual

SAFETY DATA SHEET
www.crcindustries.com
CAS number
%
Chemical name
Common name and synonyms
water
1. Identification
HydroForce® Glass Cleaner - 1 qtProduct identifier
Other means of identification
Product Code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name
Address
Telephone
General Information
Technical Assistance
Customer Service
24-Hour Emergency (CHEMTREC)
Website
No. 14411 (Item# 1004964)
Glass cleaner
CRC Industries, Inc.
885 Louis Dr.
Warminster, PA 18974 US
215-674-4300
800-521-3168
800-272-4620
800-424-9300 (US)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
Not classified.
Not classified.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification.
Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use.
Wash hands after handling.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national regulations.
None.
3. Composition/information on ingredients
Mixtures
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
7732-18-5
111-76-22-butoxyethanol 1 - 3
67-63-0isopropyl alcohol 1 - 3
7664-41-7ammonia 0.1 - 1
90 - 100
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4. First-aid measures
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Move to fresh air. Call a physician if symptoms develop or persist.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur.
Direct contact with eyes may cause temporary irritation.
Treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. For product usage instructions, see the product label.
Store in a cool, dry place out of direct sunlight. Keep container tightly closed. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
ValueComponents Type
PEL 240 mg/m32-butoxyethanol (CAS
111-76-2)
PEL 35 mg/m3ammonia (CAS 7664-41-7)
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
50 ppm
50 ppm
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US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
67-63-0)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
ACGIH Biological Exposure Indices
with hydrolysis
111-76-2)
67-63-0)
111-76-2)
67-63-0)
ValueComponents Type
PEL 980 mg/m3isopropyl alcohol (CAS
400 ppm
ValueComponents Type
TWA 20 ppm2-butoxyethanol (CAS
STEL 35 ppmammonia (CAS 7664-41-7)
TWA 25 ppm
STEL 400 ppmisopropyl alcohol (CAS
TWA 200 ppm
ValueComponents Type
TWA 24 mg/m32-butoxyethanol (CAS
5 ppm
STEL 27 mg/m3ammonia (CAS 7664-41-7)
35 ppm
TWA 18 mg/m3
25 ppm
STEL 1225 mg/m3isopropyl alcohol (CAS
500 ppm
TWA 980 mg/m3
400 ppm
Biological limit values
ValueComponents Determinant Specimen Sampling Time
2-butoxyethanol (CAS 111-76-2)
isopropyl alcohol (CAS
200 mg/g Butoxyacetic
acid (BAA),
40 mg/l Acetone Urine
67-63-0) * - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-butoxyethanol (CAS 111-76-2) Skin designation applies.
US - Tennessee OELs: Skin designation
2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Creatinine in urine
*
*
Material name: HydroForce® Glass Cleaner - 1 qt
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Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Rubber.
Wear suitable protective clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor pressure temp.
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Percent volatile
Liquid.
Liquid.
Light blue.
Ammoniacal.
Not available.
10.6
-127.3 °F (-88.5 °C) estimated
180.5 °F (82.5 °C) estimated
None.
Slow.
Not available.
2.5 % estimated
25 % estimated
1 hPa estimated
77 °F (25 °C)
> 1 (air = 1)
0.99
Soluble.
Not available.
460.4 °F (238 °C) estimated
Not available.
99.8 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
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Conditions to avoid
Inhalation
Eye contact
Ingestion
Acute toxicity
Respiratory sensitization
Carcinogenicity
Incompatible materials
Hazardous decomposition
Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides. Aldehydes. Ketones. Organic acids.
products
11. Toxicological information
Information on likely routes of exposure
Based on available data, the classification criteria are not met.
Skin contact
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
HydroForce® Glass Cleaner - 1 qt
Acute
Dermal
ATEmix 30704.815073626403 mg/kg
Inhalation
Vapor
ATEmix
Oral
ATEmix 17766.949707441625 mg/kg
2-butoxyethanol (CAS 111-76-2)
Acute
Dermal
LD50 Rabbit 220 mg/kg
Oral
LD50 Rat 470 mg/kg
isopropyl alcohol (CAS 67-63-0)
Acute
Dermal
LD50 Rabbit 5030 - 7900 mg/kg
Inhalation
LC50 Rat 16000 ppm, 4 hours
Oral
LD50 Rat 4700 - 5800 mg/kg
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Direct contact with eyes may cause temporary irritation.
Test ResultsProduct Species
1000 mg/l
Test ResultsComponents Species
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Skin sensitization
Germ cell mutagenicity
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Not classifiable as to carcinogenicity to humans.
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IARC Monographs. Overall Evaluation of Carcinogenicity
Aspiration hazard
Further information
Partition coefficient n-octanol / water (log Kow)
2-butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
Specific target organ toxicity ­single exposure
Specific target organ toxicity ­repeated exposure
Chronic effects
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
May be harmful if absorbed through skin. Prolonged inhalation may be harmful.
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans.
This product has no known adverse effect on human health.
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of any ingredients in the mixture.
2-butoxyethanol 0.83 isopropyl alcohol 0.05
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Hazardous waste code
Contaminated packaging
This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
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US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
2-butoxyethanol (CAS 111-76-2)
CERCLA Hazardous Substance List (40 CFR 302.4)
2-butoxyethanol (CAS 111-76-2)
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
isopropyl alcohol (CAS 67-63-0) Low priority
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Chemical name CAS number Reportable
quantity (pounds)
Threshold planning quantity (pounds)
ammonia 7664-41-7 100 500
SARA 311/312 Hazardous
No
chemical
SARA 313 (TRI reporting)
Chemical name % by wt.
CAS number
2-butoxyethanol 1 - 3111-76-2 ammonia 0.1 - 17664-41-7
US state regulations
US. New Jersey Worker and Community Right-to-Know Act
2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) isopropyl alcohol (CAS 67-63-0)
US. Massachusetts RTK - Substance List
2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) isopropyl alcohol (CAS 67-63-0)
US. Pennsylvania Worker and Community Right-to-Know Law
2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) isopropyl alcohol (CAS 67-63-0)
US. Rhode Island RTK
ammonia (CAS 7664-41-7) isopropyl alcohol (CAS 67-63-0)
California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))
2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) isopropyl alcohol (CAS 67-63-0)
Threshold planning quantity, lower value (pounds)
Threshold planning quantity, upper value (pounds)
Material name: HydroForce® Glass Cleaner - 1 qt
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Volatile organic compounds (VOC) regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
EPA
VOC content (40 CFR
3 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Glass Cleaner (non-aerosol). This product is compliant for use in all 50 states.
VOC content (CA)
VOC content (OTC)
3 %
3 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
NoChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesTaiwan Taiwan Chemical Substance Inventory (TCSI)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
Disclaimer
Revision information
07-23-2020
Allison Yoon
01
CRC # 1752282
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc..
Product and Company Identification: Product Codes Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Toxicological information: Eye contact Toxicological information: Ingestion Toxicological information: Inhalation Regulatory Information: VOC Regulations Regulatory information: California Proposition 65 Other information, including date of preparation or last revision: Further information Material Attributes & Uses; Experimental Data: Material Attributes GHS: Classification
Material name: HydroForce® Glass Cleaner - 1 qt
No. 14411 (Item# 1004964) Version #: 01 Issue date: 07-23-2020
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