Category 2Reproductive toxicity (the unborn child)
Category 1Specific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Signal word
Hazard statement
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
Danger
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Toxic if
swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious
eye irritation. May cause drowsiness or dizziness. May cause damage to organs (liver, kidneys,
lungs, brain) through prolonged or repeated exposure. Suspected of damaging the unborn child.
Causes damage to organs (eyes) by ingestion. Toxic to aquatic life. Toxic to aquatic life with long
lasting effects.
SDS US
1 / 13
Precautionary statement
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Do not apply while equipment is energized.
Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights
and heaters. Vapors will accumulate readily and may ignite. Do not breathe gas. Use only with
adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors
and windows or use other means to ensure a fresh air supply during use and while product is
drying. If you experience any symptoms listed on this label, increase ventilation or leave the area.
Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when
using this product. Wear protective gloves/protective clothing/eye protection/face protection.
Avoid release to the environment.
Response
If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. If
on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off
contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep
comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
attention. If exposed: Call a poison center/doctor. If exposed or concerned: Get medical attention.
Collect spillage.
Storage
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to
temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Disposal
Hazard(s) not otherwise
classified (HNOC)
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information
15.9% of the mixture consists of component(s) of unknown acute oral toxicity.
When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as
formaldehyde.
3. Composition/information on ingredients
Mixtures
CAS number%Common name and synonymsChemical name
67-56-1Methanol
108-88-3Toluene
67-64-1Acetone
589-34-43-Methylhexane
124-38-9Carbon dioxide
142-82-5n-Heptane
108-87-2Methylcyclohexane
64742-49-0Naphtha (petroleum), hydrotreated
light
110-82-7Cyclohexane
100-41-4Ethylbenzene
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of
a pocket mask equipped with a one-way valve or other proper respiratory medical device.
40 - 50
10 - 20
5 - 15
5 - 10
5 - 10
5 - 10
3 - 5
3 - 5
1 - 3
< 0.2
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
2 / 13
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
General fire hazards
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat.
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Upper respiratory tract irritation.
Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance.
Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
None known.
Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This
product is a poor conductor of electricity and can become electrostatically charged. If sufficient
charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation
may be significantly increased by the presence of small quantities of water or other contaminants.
Material will float and may ignite on surface of water. During fire, gases hazardous to health may
be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when
exposed to heat or flame.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are
heavier than air and will spread along ground and collect in low or confined areas (sewers,
basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not
breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing
equipment. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to
avoid environmental contamination. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with
absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases. Use appropriate containment to avoid
environmental contamination.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
3 / 13
7. Handling and storage
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. OSHA Table Z-2 (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Minimize fire risks from flammable and combustible materials (including
combustible dust and static accumulating liquids) or dangerous reactions with incompatible
materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button
is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not
smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,
or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around
energized equipment. The metal container will conduct electricity if it contacts a live source. This
may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor.
Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not
taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must
not handle this product. Should be handled in closed systems, if possible. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. For
product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to
remove static electricity. Store in a well-ventilated place. Store away from incompatible materials
(see Section 10 of the SDS).
Methanol (CAS 67-56-1)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1)Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
Methanol (CAS 67-56-1)Can be absorbed through the skin.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene. Polyvinyl alcohol (PVA).
Wear appropriate chemical resistant clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards
General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Keep away from food and drink. Always observe good personal
hygiene measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
*
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
Liquid.
Aerosol.
Clear.
Solvent.
Not available.
Not available.
-195.9 °F (-126.6 °C) estimated
132.9 °F (56.1 °C) estimated
0 °F (-17.8 °C) Tag Closed Cup
Fast.
Not available.
1 % estimated
SDS US
6 / 13
Flammability limit - upper
Skin contact
Eye contact
Acute toxicity
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
36 % estimated
4438 hPa estimated
> 1 (air = 1)
0.84 estimated
Slightly soluble.
Not available.
539.6 °F (282 °C) estimated
Not available.
Not available.
92.4 % estimated
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.
When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal
corrosive gases such as formaldehyde.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Brakleen® Brake Parts Cleaner - Non-Chlorinated
Acute
Dermal
LD50Rabbit6702 mg/kg estimated
Inhalation
LC50Rat58 mg/l, 4 Hours estimated
Oral
LD50Human110 mg/kg estimated
May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. Headache. Nausea, vomiting.
Causes skin irritation.
Causes serious eye irritation.
Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are
stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Droplets of the product
aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Aspiration may cause
pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.
May be fatal if swallowed and enters airways. Narcotic effects.
Rat5943 mg/kg estimated
Test ResultsProductSpecies
Skin corrosion/irritation
Serious eye damage/eye
irritation
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
* Estimates for product may be based on additional component data not shown.
Causes skin irritation.
Causes serious eye irritation.
SDS US
7 / 13
Respiratory sensitization
Not a respiratory sensitizer.
Carcinogenicity
Acute
Acute
Acute
Acute
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Based on available data, the classification criteria are not met.
Reproductive toxicity
Specific target organ toxicity -
Suspected of damaging the unborn child.
Causes damage to organs (eyes) by ingestion. May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard
May cause damage to organs through prolonged or repeated exposure: Liver. Kidneys. Lungs.
Brain.
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,
may cause chemical pneumonia, pulmonary injury or death.
Chronic effects
May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may
be harmful. Prolonged exposure may cause chronic effects.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from
residues / unused products
This material and its container must be disposed of as hazardous waste. Collect and reclaim or
dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not
puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not
contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
D001: Waste Flammable material with a flash point <140 F
F005: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
UN1950
Aerosols, flammable, Limited Quantity
2.1
6.1(PGIII)
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable, containing substances in Division 6.1, Packing Group III
2.1
6.1(PGIII)
Not applicable.
No.
10P
Read safety instructions, SDS and emergency procedures before handling.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
9 / 13
Other information
Passenger and cargo
Allowed.
aircraft
Cargo aircraft only
Allowed.
IMDG
UN number
UN proper shipping name
UN1950
AEROSOLS, MARINE POLLUTANT
Transport hazard class(es)
Class
Subsidiary risk
Packing group
2
6.1(PGIII)
Not applicable.
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Yes
Not available.
Read safety instructions, SDS and emergency procedures before handling.
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Ethylbenzene (CAS 100-41-4)
US. Massachusetts RTK - Substance List
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Toluene (CAS 108-88-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Benzene (CAS 71-43-2)
Ethylbenzene (CAS 100-41-4)
3-Methylhexane (CAS 589-34-4)
Carbon dioxide (CAS 124-38-9)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2)Listed: February 27, 1987
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
11 / 13
Cumene (CAS 98-82-8)Listed: April 6, 2010
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Ethanal (CAS 75-07-0)Listed: April 1, 1988
Ethylbenzene (CAS 100-41-4)Listed: June 11, 2004
Naphthalene (CAS 91-20-3)Listed: April 19, 2002
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Methanol (CAS 67-56-1)Listed: March 16, 2012
Toluene (CAS 108-88-3)Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
Toluene (CAS 108-88-3)Listed: August 7, 2009
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
84 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Brake Cleaner. This product is not compliant to be sold for use in
California, Connecticut, Delaware, the District of Columbia, Illinois, Indiana, Maine, Maryland,
Massachusetts, Michigan, New Hampshire, New Jersey, New York, Ohio, Pennsylvania, Rhode
Island and parts of Utah and Virginia.
VOC content (CA)
VOC content (OTC)
84 %
84 %
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustraliaAustralian Inventory of Chemical Substances (AICS)
NoCanadaDomestic Substances List (DSL)
YesCanadaNon-Domestic Substances List (NDSL)
YesChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial Chemical
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
YesJapanInventory of Existing and New Chemical Substances (ENCS)
YesKoreaExisting Chemicals List (ECL)
YesNew ZealandNew Zealand Inventory
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
05-13-2015
Allison Cho
01
CRC # 483A
Health: 3*
Flammability: 4
Physical hazard: 0
Personal protection: B
Health: 3
Flammability: 4
Instability: 0
SDS US
12 / 13
NFPA ratings
4
03
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
13 / 13
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