CRC 05088 User Manual

SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Brakleen® Brake Parts Cleaner - Non-ChlorinatedProduct identifier
Other means of identification
Product code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
05088
Brake parts cleaner
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Category 1Flammable aerosols
Compressed gasGases under pressure
Category 3Acute toxicity, oral
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 2Reproductive toxicity (the unborn child)
Category 1Specific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Signal word
Hazard statement
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
Danger
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Toxic if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. May cause damage to organs (liver, kidneys, lungs, brain) through prolonged or repeated exposure. Suspected of damaging the unborn child. Causes damage to organs (eyes) by ingestion. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
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Precautionary statement
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Do not breathe gas. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment.
Response
If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If exposed: Call a poison center/doctor. If exposed or concerned: Get medical attention. Collect spillage.
Storage
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Disposal
Hazard(s) not otherwise classified (HNOC)
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information
15.9% of the mixture consists of component(s) of unknown acute oral toxicity. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as formaldehyde.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
67-56-1Methanol
108-88-3Toluene
67-64-1Acetone
589-34-43-Methylhexane
124-38-9Carbon dioxide
142-82-5n-Heptane
108-87-2Methylcyclohexane
64742-49-0Naphtha (petroleum), hydrotreated
light
110-82-7Cyclohexane
100-41-4Ethylbenzene
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
40 - 50
10 - 20
5 - 15
5 - 10
5 - 10
5 - 10
3 - 5
3 - 5
1 - 3
< 0.2
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
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Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Upper respiratory tract irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.
Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Prevent product from entering drains. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
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7. Handling and storage
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. OSHA Table Z-2 (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
124-38-9)
110-82-7)
100-41-4)
108-87-2)
ValueComponents Type
PEL 2400 mg/m3Acetone (CAS 67-64-1)
1000 ppm
PEL 9000 mg/m3Carbon dioxide (CAS
5000 ppm
PEL 1050 mg/m3Cyclohexane (CAS
300 ppm
PEL 435 mg/m3Ethylbenzene (CAS
100 ppm
PEL 260 mg/m3Methanol (CAS 67-56-1)
200 ppm
PEL 2000 mg/m3Methylcyclohexane (CAS
500 ppm
PEL 2000 mg/m3n-Heptane (CAS 142-82-5)
500 ppm
ValueComponents Type
Ceiling 300 ppmToluene (CAS 108-88-3) TWA 200 ppm
ValueComponents Type
STEL 500 ppm3-Methylhexane (CAS
589-34-4)
TWA 400 ppm STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm STEL 30000 ppmCarbon dioxide (CAS
124-38-9)
TWA 5000 ppm
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
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US. ACGIH Threshold Limit Values
110-82-7)
US. NIOSH: Pocket Guide to Chemical Hazards
ACGIH Biological Exposure Indices
100-41-4)
108-87-2)
124-38-9)
110-82-7)
100-41-4)
108-87-2)
Biological limit values
ValueComponents Type
TWA 100 ppmCyclohexane (CAS
TWA 20 ppmEthylbenzene (CAS
STEL 250 ppmMethanol (CAS 67-56-1) TWA 200 ppm STEL 500 ppmMethylcyclohexane (CAS
TWA 400 ppm STEL 500 ppmn-Heptane (CAS 142-82-5) TWA 400 ppm TWA 20 ppmToluene (CAS 108-88-3)
ValueComponents Type
TWA 590 mg/m3Acetone (CAS 67-64-1)
250 ppm
STEL 54000 mg/m3Carbon dioxide (CAS
30000 ppm
TWA 9000 mg/m3
5000 ppm
TWA 1050 mg/m3Cyclohexane (CAS
300 ppm
STEL 545 mg/m3Ethylbenzene (CAS
125 ppm
TWA 435 mg/m3
100 ppm
STEL 325 mg/m3Methanol (CAS 67-56-1)
250 ppm
TWA 260 mg/m3
200 ppm
TWA 1600 mg/m3Methylcyclohexane (CAS
400 ppm
Ceiling 1800 mg/m3n-Heptane (CAS 142-82-5)
440 ppm
TWA 350 mg/m3
85 ppm
STEL 560 mg/m3Toluene (CAS 108-88-3)
150 ppm
TWA 375 mg/m3
100 ppm
ValueComponents Determinant Specimen Sampling Time
Acetone (CAS 67-64-1) Ethylbenzene (CAS
50 mg/l Acetone Urine
0.15 g/g Sum of
100-41-4)
Methanol (CAS 67-56-1) Toluene (CAS 108-88-3)
15 mg/l Methanol Urine
0.3 mg/g o-Cresol, with
0.03 mg/l Toluene Urine
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
mandelic acid and phenylglyoxylic acid
hydrolysis
Creatinine in urine
Creatinine in urine
* *
* *
*
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ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
wash facilities and emergency shower must be available when handling this product.
0.02 mg/l Toluene Blood
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Methanol (CAS 67-56-1) Skin designation applies. Toluene (CAS 108-88-3) Skin designation applies.
US - Tennessee OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene. Polyvinyl alcohol (PVA).
Wear appropriate chemical resistant clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
*
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
Liquid.
Aerosol.
Clear.
Solvent.
Not available.
Not available.
-195.9 °F (-126.6 °C) estimated
132.9 °F (56.1 °C) estimated
0 °F (-17.8 °C) Tag Closed Cup
Fast.
Not available.
1 % estimated
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Flammability limit - upper
Skin contact
Eye contact
Acute toxicity
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
36 % estimated
4438 hPa estimated
> 1 (air = 1)
0.84 estimated
Slightly soluble.
Not available.
539.6 °F (282 °C) estimated
Not available.
Not available.
92.4 % estimated
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as formaldehyde.
Acids. Alkalies. Reducing agents. Strong oxidizing agents. Hypochlorites. Peroxides. Aluminum. Magnesium. Sodium. Zinc.
Carbon oxides. Formaldehyde.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Brakleen® Brake Parts Cleaner - Non-Chlorinated
Acute
Dermal
LD50 Rabbit 6702 mg/kg estimated
Inhalation
LC50 Rat 58 mg/l, 4 Hours estimated
Oral
LD50 Human 110 mg/kg estimated
May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Causes skin irritation.
Causes serious eye irritation.
Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.
May be fatal if swallowed and enters airways. Narcotic effects.
Rat 5943 mg/kg estimated
Test ResultsProduct Species
Skin corrosion/irritation
Serious eye damage/eye irritation
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
* Estimates for product may be based on additional component data not shown.
Causes skin irritation.
Causes serious eye irritation.
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Respiratory sensitization
Not a respiratory sensitizer.
Carcinogenicity
Acute
Acute
Acute
Acute
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Based on available data, the classification criteria are not met.
Reproductive toxicity
Specific target organ toxicity -
Suspected of damaging the unborn child.
Causes damage to organs (eyes) by ingestion. May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity ­repeated exposure
Aspiration hazard
May cause damage to organs through prolonged or repeated exposure: Liver. Kidneys. Lungs. Brain.
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death.
Chronic effects
May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Brakleen® Brake Parts Cleaner - Non-Chlorinated
Aquatic
Components Test ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
Cyclohexane (CAS 110-82-7)
Aquatic
Ethylbenzene (CAS 100-41-4)
Aquatic
Toxic to aquatic life with long lasting effects.
EC50Crustacea 5512.6509 mg/l, 48 hours estimatedDaphnia
LC50Fish 37.092 mg/l, 96 hours estimatedFish
EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout
LC50Fish 23.03 - 42.07 mg/l, 96 hoursFathead minnow (Pimephales promelas)
(Oncorhynchus mykiss)
Methanol (CAS 67-56-1)
Aquatic
Methylcyclohexane (CAS 108-87-2)
Aquatic
n-Heptane (CAS 142-82-5)
Aquatic
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
EC50Crustacea 2.1 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 12.1 mg/l, 96 hoursFathead minnow (Pimephales promelas)
LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
LC50Fish 5.8 mg/l, 96 hoursStriped bass (Morone saxatilis)
LC50Fish 2.1 - 2.98 mg/l, 96 hoursFathead minnow (Pimephales promelas)
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Components Test ResultsSpecies
Partition coefficient n-octanol / water (log Kow)
with all applicable regulations.
Toluene (CAS 108-88-3)
Aquatic
EC50Crustacea 5.46 - 9.83 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 8.11 mg/l, 96 hoursCoho salmon,silver salmon
(Oncorhynchus kisutch)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
Acetone -0.24 Cyclohexane 3.44 Ethylbenzene 3.15 Methanol -0.77 Methylcyclohexane 3.61 n-Heptane 4.66 Toluene 2.73
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
This material and its container must be disposed of as hazardous waste. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user
D001: Waste Flammable material with a flash point <140 F F005: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
UN1950 Aerosols, flammable, Limited Quantity
2.1
6.1(PGIII)
2.1 Not applicable. Read safety instructions, SDS and emergency procedures before handling. N82 306 None None
UN1950 Aerosols, flammable, containing substances in Division 6.1, Packing Group III
2.1
6.1(PGIII) Not applicable. No. 10P Read safety instructions, SDS and emergency procedures before handling.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
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Other information
Passenger and cargo
Allowed.
aircraft
Cargo aircraft only
Allowed.
IMDG
UN number UN proper shipping name
UN1950 AEROSOLS, MARINE POLLUTANT
Transport hazard class(es)
Class
Subsidiary risk Packing group
2
6.1(PGIII) Not applicable.
Environmental hazards
Marine pollutant EmS Special precautions for user
Yes Not available. Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Cyclohexane (CAS 110-82-7)
Ethylbenzene (CAS 100-41-4)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Methanol (CAS 67-56-1) Listed.
Toluene (CAS 108-88-3) Listed.
CERCLA Hazardous Substances: Reportable quantity
Acetone (CAS 67-64-1) 5000 LBS
Cyclohexane (CAS 110-82-7) 1000 LBS
Methanol (CAS 67-56-1) 5000 LBS
Toluene (CAS 108-88-3) 1000 LBS
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number
Acetone (CAS 67-64-1) 6532
Toluene (CAS 108-88-3) 6594
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Toluene (CAS 108-88-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Not regulated.
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Toluene (CAS 108-88-3) 594
Xylene (CAS 1330-20-7)
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))
Acetone (CAS 67-64-1)
Naphtha (petroleum), hydrotreated light (CAS 64742-49-0)
Ethylbenzene (CAS 100-41-4)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Ethylbenzene (CAS 100-41-4)
US. Massachusetts RTK - Substance List
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Toluene (CAS 108-88-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Benzene (CAS 71-43-2)
Ethylbenzene (CAS 100-41-4)
3-Methylhexane (CAS 589-34-4)
Carbon dioxide (CAS 124-38-9)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
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Cumene (CAS 98-82-8) Listed: April 6, 2010
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Ethanal (CAS 75-07-0) Listed: April 1, 1988 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 Naphthalene (CAS 91-20-3) Listed: April 19, 2002
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997 Methanol (CAS 67-56-1) Listed: March 16, 2012 Toluene (CAS 108-88-3) Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
Toluene (CAS 108-88-3) Listed: August 7, 2009
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
84 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Brake Cleaner. This product is not compliant to be sold for use in California, Connecticut, Delaware, the District of Columbia, Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Hampshire, New Jersey, New York, Ohio, Pennsylvania, Rhode Island and parts of Utah and Virginia.
VOC content (CA)
VOC content (OTC)
84 %
84 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
YesCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
05-13-2015
Allison Cho
01
CRC # 483A
Health: 3* Flammability: 4 Physical hazard: 0 Personal protection: B
Health: 3 Flammability: 4 Instability: 0
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NFPA ratings
4
03
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05088 Version #: 01 Issue date: 05-13-2015
SDS US
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