SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Brakleen® Brake Parts Cleaner - Non-ChlorinatedProduct identifier
Other means of identification
Product code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name
Address
Telephone
General Information
Technical
Assistance
Customer Service
24-Hour Emergency
(CHEMTREC)
Website
05086
Brake cleaner
None known.
CRC Industries, Inc.
885 Louis Dr.
Warminster, PA 18974 US
215-674-4300
800-521-3168
800-272-4620
800-424-9300 (US)
703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Category 2Flammable liquids
Category 3Acute toxicity, oral
Category 4Acute toxicity, dermal
Category 4Acute toxicity, inhalation
Category 2Skin corrosion/irritation
Category 2Serious eye damage/eye irritation
Category 2Reproductive toxicity (the unborn child)
Category 1Specific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Signal word
Hazard statement
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
Danger
Highly flammable liquid and vapor. Toxic if swallowed. May be fatal if swallowed and enters
airways. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful
if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. May cause
damage to organs (brain, kidneys, liver, lungs) through prolonged or repeated exposure.
Suspected of damaging fertility or the unborn child. Causes damage to organs (eyes) by
ingestion. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
SDS US
1 / 12
Precautionary statement
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Use only with adequate ventilation; maintain ventilation during
use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh
air supply during use and while product is drying. If you experience any symptoms listed on this
label, increase ventilation or leave the area. Do not breathe mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid release to the environment.
Response
If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. If
on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If
skin irritation occurs: Get medical attention. If inhaled: Remove person to fresh air and keep
comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
attention. If exposed: Call a poison center/doctor. Wash contaminated clothing before reuse. If
exposed or concerned: Get medical attention. In case of fire: Do not use water jet as an
extinguisher, as this will spread the fire. Collect spillage.
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information
13.2% of the mixture consists of component(s) of unknown acute dermal toxicity. 13.19% of the mixture consists of component(s)
of unknown acute inhalation toxicity.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
67-64-1Acetone
67-56-1Methanol
142-82-5n-Heptane
108-88-3Toluene
589-34-43-Methylhexane
108-87-2Methylcyclohexane
64742-49-0Naphtha (petroleum), hydrotreated
light
110-82-7Cyclohexane
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of
a pocket mask equipped with a one-way valve or other proper respiratory medical device.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause
pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause
redness and pain. Prolonged exposure may cause chronic effects.
50 - 60
10 - 20
5 - 10
5 - 10
3 - 5
3 - 5
3 - 5
1 - 3
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
SDS US
2 / 12
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
General fire hazards
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed.
Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash
contaminated clothing before reuse.
Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. During fire, gases
hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Highly flammable liquid and vapor.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Transfer by mechanical means such as vacuum truck to a
salvage tank or other suitable container for recovery or safe disposal. Use appropriate containment
to avoid environmental contamination. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant
under the Clean Water Act and should be prevented from contaminating soil or from entering
sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases. Use appropriate containment to avoid
environmental contamination.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
SDS US
3 / 12
7. Handling and storage
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. OSHA Table Z-2 (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation.
Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take
precautionary measures against static discharges. All equipment used when handling the product
must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or
vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not
eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be
handled in closed systems, if possible. Use only outdoors or in a well-ventilated area. Wear
appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good
industrial hygiene practices. Avoid release to the environment. Wash contaminated clothing before
reuse. For product usage instructions, please see the product label.
Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using
common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters.
Ground/bond container and equipment. These alone may be insufficient to remove static
electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container.
Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from
incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
110-82-7)
108-87-2)
589-34-4)
110-82-7)
108-87-2)
ValueComponents Type
PEL 2400 mg/m3Acetone (CAS 67-64-1)
1000 ppm
PEL 1050 mg/m3Cyclohexane (CAS
300 ppm
PEL 260 mg/m3Methanol (CAS 67-56-1)
200 ppm
PEL 2000 mg/m3Methylcyclohexane (CAS
500 ppm
PEL 2000 mg/m3n-Heptane (CAS 142-82-5)
500 ppm
ValueComponents Type
Ceiling 300 ppmToluene (CAS 108-88-3)
TWA 200 ppm
ValueComponents Type
STEL 500 ppm3-Methylhexane (CAS
TWA 400 ppm
STEL 750 ppmAcetone (CAS 67-64-1)
TWA 500 ppm
TWA 100 ppmCyclohexane (CAS
STEL 250 ppmMethanol (CAS 67-56-1)
TWA 200 ppm
STEL 500 ppmMethylcyclohexane (CAS
TWA 400 ppm
STEL 500 ppmn-Heptane (CAS 142-82-5)
TWA 400 ppm
TWA 20 ppmToluene (CAS 108-88-3)
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
SDS US
4 / 12
US. NIOSH: Pocket Guide to Chemical Hazards
110-82-7)
ACGIH Biological Exposure Indices
108-87-2)
Biological limit values
ValueComponents Type
TWA 590 mg/m3Acetone (CAS 67-64-1)
250 ppm
TWA 1050 mg/m3Cyclohexane (CAS
300 ppm
STEL 325 mg/m3Methanol (CAS 67-56-1)
250 ppm
TWA 260 mg/m3
200 ppm
TWA 1600 mg/m3Methylcyclohexane (CAS
400 ppm
Ceiling 1800 mg/m3n-Heptane (CAS 142-82-5)
440 ppm
TWA 350 mg/m3
85 ppm
STEL 560 mg/m3Toluene (CAS 108-88-3)
150 ppm
TWA 375 mg/m3
100 ppm
ValueComponents Determinant Specimen Sampling Time
Acetone (CAS 67-64-1)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
50 mg/l Acetone Urine
15 mg/l Methanol Urine
0.3 mg/g o-Cresol, with
hydrolysis
0.03 mg/l Toluene Urine
0.02 mg/l Toluene Blood
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
Toluene (CAS 108-88-3) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Methanol (CAS 67-56-1) Skin designation applies.
Toluene (CAS 108-88-3) Skin designation applies.
US - Tennessee OELs: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
Methanol (CAS 67-56-1) Can be absorbed through the skin.
Appropriate engineering
controls
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Creatinine in
urine
*
*
*
*
*
Skin protection
Hand protection
Other
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
Wear protective gloves such as: Neoprene. Nitrile. Polyvinyl alcohol (PVA).
Wear appropriate chemical resistant clothing.
SDS US
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Respiratory protection
Skin contact
Thermal hazards
General hygiene
considerations
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Keep away from food and drink. Always observe good personal
hygiene measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Liquid.
Clear.
Solvent.
Not available.
Not available.
-195.9 °F (-126.6 °C) estimated
132.9 °F (56.1 °C) estimated
< 0 °F (< -17.8 °C) Tag Closed Cup
Fast.
Not available.
1.1 % estimated
36 % estimated
169.5 hPa estimated
> 1 (air = 1)
0.78
Slightly soluble.
Not available.
539.6 °F (282 °C) estimated
Not available.
Not available.
100 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
Inhalation
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.
Acids. Alkalies. Amines. Ammonia. Halogens. Peroxides. Aluminum. Magnesium. Zinc. Strong
oxidizing agents. Reducing agents.
Carbon oxides. Formaldehyde.
Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure by
inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Harmful in contact with skin. Causes skin irritation.
SDS US
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Eye contact
Causes serious eye irritation.
cause redness and pain.
Respiratory sensitization
Carcinogenicity
Chronic effects
Acute
Ingestion
Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are
stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Droplets of the product
aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Headache. May cause drowsiness and dizziness. Nausea, vomiting. Aspiration may cause
pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging,
tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May
Information on toxicological effects
Acute toxicity
May be fatal if swallowed and enters airways. Harmful if inhaled. Harmful in contact with skin.
Narcotic effects. May cause respiratory irritation.
Brakleen® Brake Parts Cleaner - Non-Chlorinated
Acute
Dermal
LD50 Rabbit 6982 mg/kg estimated
Inhalation
LC50 Rat 9284 ppm, 4 hours estimated
Oral
LD50 Human 294 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes serious eye irritation.
irritation
Not a respiratory sensitizer.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Specific target organ toxicity single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard
Suspected of damaging fertility. Suspected of damaging the unborn child.
Causes damage to organs: Eyes. May cause respiratory irritation. May cause drowsiness and
dizziness.
May cause damage to organs through prolonged or repeated exposure: Liver. Kidneys. Brain.
Lungs.
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,
may cause chemical pneumonia, pulmonary injury or death.
May cause damage to organs through prolonged or repeated exposure.
Test ResultsProduct Species
63 mg/l, 4 Hours estimated
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Brakleen® Brake Parts Cleaner - Non-Chlorinated
Aquatic
Components Test ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
Toxic to aquatic life with long lasting effects.
EC50Crustacea 25591.9844 mg/l, 48 hours estimatedDaphnia
LC50Fish 36.0859 mg/l, 96 hours estimatedFish
EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna)
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Components Test ResultsSpecies
Acute
Acute
Partition coefficient n-octanol / water (log Kow)
LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Cyclohexane (CAS 110-82-7)
Aquatic
LC50Fish 23.03 - 42.07 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Methanol (CAS 67-56-1)
Aquatic
LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Methylcyclohexane (CAS 108-87-2)
Aquatic
LC50Fish 5.8 mg/l, 96 hoursStriped bass (Morone saxatilis)
n-Heptane (CAS 142-82-5)
Aquatic
LC50Fish 2.1 - 2.98 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Toluene (CAS 108-88-3)
Aquatic
EC50Crustacea 5.46 - 9.83 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 8.11 mg/l, 96 hoursCoho salmon,silver salmon
(Oncorhynchus kisutch)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
Acetone -0.24
Cyclohexane 3.44
Methanol -0.77
Methylcyclohexane 3.61
n-Heptane 4.66
Toluene 2.73
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from
residues / unused products
Hazardous waste code
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Collect and reclaim or
dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose in accordance with all applicable regulations.
D001: Waste Flammable material with a flash point <140 F
F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent
F005: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
UN number
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
UN1992
SDS US
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UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Flammable liquids, toxic, n.o.s. (Acetone RQ = 9091 LBS, Heptane RQ = 1613 LBS), MARINE
POLLUTANT (Heptanes, Hexane)
3
6.1
3, 6.1
II
Yes
Read safety instructions, SDS and emergency procedures before handling.
IB2, T7, TP2, TP13
150
202
243
UN1992
Flammable liquid, toxic, n.o.s. (Acetone, Heptane)
3
6.1
II
No.
3HP
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1992
FLAMMABLE LIQUID, TOXIC, N.O.S. (Acetone, Heptane), MARINE POLLUTANT
3
6.1
II
Yes
F-E, S-D
Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1) Listed.
Cyclohexane (CAS 110-82-7) Listed.
Methanol (CAS 67-56-1) Listed.
Toluene (CAS 108-88-3) Listed.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
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CERCLA Hazardous Substances: Reportable quantity
Acetone (CAS 67-64-1) 5000 LBS
Cyclohexane (CAS 110-82-7) 1000 LBS
Methanol (CAS 67-56-1) 5000 LBS
Toluene (CAS 108-88-3) 1000 LBS
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
Acetone (CAS 67-64-1) 6532
Toluene (CAS 108-88-3) 6594
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1) 35 %WV
Toluene (CAS 108-88-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1) 6532
Toluene (CAS 108-88-3) 594
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Acetone (CAS 67-64-1)
Naphtha (petroleum), hydrotreated light (CAS 64742-49-0)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. Massachusetts RTK - Substance List
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
Toluene (CAS 108-88-3)
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
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US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
Benzene (CAS 71-43-2)
3-Methylhexane (CAS 589-34-4)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
Methanol (CAS 67-56-1)
Toluene (CAS 108-88-3)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
Cumene (CAS 98-82-8) Listed: April 6, 2010
Ethanal (CAS 75-07-0) Listed: April 1, 1988
Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004
Naphthalene (CAS 91-20-3) Listed: April 19, 2002
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Methanol (CAS 67-56-1) Listed: March 16, 2012
Toluene (CAS 108-88-3) Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
Toluene (CAS 108-88-3) Listed: August 7, 2009
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
45 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Brake Cleaner. This product is not compliant to be sold for use in
California and the following counties in Utah: Box Elder, Cache, Davis, Salt Lake, Tooele, Utah
and Weber. This product is compliant in all other states.
VOC content (CA)
VOC content (OTC)
45 %
45 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
NoAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
YesCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
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Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
04-23-2015
05-13-2015
Allison Cho
02
CRC # 991A
Health: 2*
Flammability: 3
Physical hazard: 0
Personal protection: B
Health: 2
Flammability: 3
Instability: 0
3
02
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Material name: Brakleen® Brake Parts Cleaner - Non-Chlorinated
05086 Version #: 02 Revision date: 05-13-2015 Issue date: 04-23-2015
SDS US
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