Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
swallowed and enters airways. Causes serious eye irritation. May cause drowsiness or dizziness.
Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Do not apply while equipment is energized. Pressurized container:
Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will
accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during
use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh
air supply during use and while product is drying. If you experience any symptoms listed on this
label, increase ventilation or leave the area. Avoid breathing mist or vapor. Avoid breathing gas.
Wear eye/face protection. Wash hands thoroughly after handling. Avoid release to the
environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you
feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to
temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
SDS US
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Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
8.49% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 8.49% of the mixture
consists of component(s) of unknown long-term hazards to the aquatic environment.
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
3. Composition/information on ingredients
Mixtures
CAS number%Chemical nameCommon name and synonyms
67-64-1Acetone
124-38-9Carbon dioxide
589-34-43-Methylhexane
108-87-2Methylcyclohexane
142-82-5n-Heptane
110-82-7Cyclohexane
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Rinse skin with water/shower. Get medical attention if irritation develops and persists.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may
cause pulmonary edema and pneumonitis.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Vapors have a
narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or
dizziness.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
80 - 90
5 - 10
1 - 3
1 - 3
1 - 3
< 1
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
General fire hazards
Alcohol resistant foam. Water spray. Water fog. Carbon dioxide (CO2). Dry chemical powder,
carbon dioxide, sand or earth may be used for small fires only.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame. This
product is a poor conductor of electricity and can become electrostatically charged. If sufficient
charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation
may be significantly increased by the presence of small quantities of water or other contaminants.
Material will float and may ignite on surface of water.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate
protective equipment and clothing during clean-up. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Avoid
breathing gas. Ventilate closed spaces before entering them. Use appropriate containment to
avoid environmental contamination. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
SDS US
2 / 9
Methods and materials for
without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is
material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent
entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of
the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground. Use appropriate containment to avoid
environmental contamination.
Minimize fire risks from flammable and combustible materials (including combustible dust and
static accumulating liquids) or dangerous reactions with incompatible materials. Handling
operations that can promote accumulation of static charges include but are not limited to: mixing,
filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container
filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized
container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective.
Do not spray on a naked flame or any other incandescent material. Do not smoke while using or
until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to
heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The
metal container will conduct electricity if it contacts a live source. This may result in injury to the
user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas.
Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear
appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good
industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For
product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to
remove static electricity. Store in a well-ventilated place. Store away from incompatible materials
(see Section 10 of the SDS). Keep out of the reach of children.
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
ValueComponentsType
1000 ppm
5000 ppm
300 ppm
500 ppm
500 ppm
ValueComponentsType
SDS US
3 / 9
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
124-38-9)
ACGIH Biological Exposure Indices
wash work clothing and protective equipment to remove contaminants.
110-82-7)
108-87-2)
Biological limit values
ValueComponentsType
TWA400 ppm
ValueComponentsType
TWA590 mg/m3Acetone (CAS 67-64-1)
250 ppm
STEL54000 mg/m3Carbon dioxide (CAS
30000 ppm
TWA9000 mg/m3
5000 ppm
TWA1050 mg/m3Cyclohexane (CAS
300 ppm
TWA1600 mg/m3Methylcyclohexane (CAS
400 ppm
Ceiling1800 mg/m3n-Heptane (CAS 142-82-5)
440 ppm
TWA350 mg/m3
85 ppm
ValueComponentsDeterminantSpecimenSampling Time
Acetone (CAS 67-64-1)
50 mg/lAcetoneUrine
* - For sampling details, please see the source document.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Polyvinyl alcohol (PVA). Viton®.
Wear appropriate chemical resistant clothing.
In case of insufficient ventilation, wear suitable respiratory equipment. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards
General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Liquid.
Aerosol.
Clear. Colorless.
Solvent.
Not available.
Not available.
-195.9 °F (-126.6 °C) estimated
132.9 °F (56.1 °C) estimated
< 0 °F (< -17.8 °C) Tag Closed Cup
Fast.
Not available.
*
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
SDS US
4 / 9
Upper/lower flammability or explosive limits
Ingestion
Skin contact
Eye contact
Acute toxicity
Flammability limit - lower
1.1 % estimated
(%)
Flammability limit - upper
12.8 % estimated
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
5061 hPa estimated
> 2 (air = 1)
0.84 estimated
Slightly soluble.
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
539.6 °F (282 °C) estimated
Not available.
Not available.
91.5 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Brakleen® Non-Chlorinated Brake Parts Cleaner
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
TDL0Human3.5211 g/kg estimated
Chronic
Inhalation
NOELRat
Oral
NOELRat
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea.
Prolonged inhalation may be harmful.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
Causes serious eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting.
May be fatal if swallowed and enters airways. Narcotic effects.
Test ResultsProductSpecies
11501.0918 mg/kg estimated
38853.0078 ppm, 4 hours estimated
80.89 mg/l, 4 Hours estimated
6231.645 mg/kg estimated
23068.9746 ppm, 8 weeks estimated
121.4157 mg/kg, 90 days estimated
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
* Estimates for product may be based on additional component data not shown.
SDS US
5 / 9
Skin corrosion/irritation
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Acute
Partition coefficient n-octanol / water (log Kow)
Prolonged skin contact may cause temporary irritation. Repeated exposure may cause skin
dryness or cracking.
Serious eye damage/eye
Causes serious eye irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Narcotic effects.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
May be fatal if swallowed and enters airways.
Chronic effects
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
ProductTest ResultsSpecies
Brakleen® Non-Chlorinated Brake Parts Cleaner
Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Accumulation in aquatic
organisms is expected.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from
residues / unused products
Hazardous waste code
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
This material and its container must be disposed of as hazardous waste. Consult authorities before
disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material
to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical
or used container. Dispose in accordance with all applicable regulations.
D001: Waste Flammable material with a flash point <140 F
F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent
SDS US
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Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
UN1950
Aerosols, flammable, Limited Quantity
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
N82
306
304
None
UN1950
Aerosols, flammable, Limited Quantity
2.1
Not applicable.
No.
10L
Read safety instructions, SDS and emergency procedures before handling.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1)
CERCLA Hazardous Substances: Reportable quantity
Acetone (CAS 67-64-1)5000 lbs
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
Acetone (CAS 67-64-1)6532
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)35 % weight/volumn
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)6532
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. New Jersey RTK - Substances: Listed substance
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Cyclohexane (CAS 110-82-7)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Massachusetts RTK - Substance List
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Pennsylvania RTK - Hazardous Substances
3-Methylhexane (CAS 589-34-4)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
Cyclohexane (CAS 110-82-7)
Methylcyclohexane (CAS 108-87-2)
n-Heptane (CAS 142-82-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexane (CAS 110-82-7)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2)Listed: February 27, 1987
Cumene (CAS 98-82-8)Listed: April 6, 2010
Ethanal (CAS 75-07-0)Listed: April 1, 1988
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Toluene (CAS 108-88-3)Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
Toluene (CAS 108-88-3)Listed: August 7, 2009
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
9.2 %
51.100(s))
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
SDS US
8 / 9
Consumer products
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
This product is regulated as a Brake Cleaner. This product is compliant for use in all 50 states.
9.2 %
9.2 %
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustraliaAustralian Inventory of Chemical Substances (AICS)
NoCanadaDomestic Substances List (DSL)
YesCanadaNon-Domestic Substances List (NDSL)
YesChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial Chemical
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
YesKoreaExisting Chemicals List (ECL)
YesNew ZealandNew Zealand Inventory
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Disclaimer
03-04-2014
Allison Cho
01
CRC # 920B
Health: 2
Flammability: 4
Physical hazard: 0
Personal protection: B
Health: 2
Flammability: 4
Instability: 0
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Material name: Brakleen® Non-Chlorinated Brake Parts Cleaner
1809 Version #: 01 Issue date: 03-04-2014
SDS US
9 / 9
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