Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause
drowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (nervous
system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Harmful to
aquatic life with long lasting effects.
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
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Precautionary statement
with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Do not apply while equipment is energized.
Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights
and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation;
maintain ventilation during use and until all vapors are gone. Open doors and windows or use
other means to ensure a fresh air supply during use and while product is drying. If you experience
any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Do
not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention. If exposed or concerned: Get medical attention.
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to
temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and
grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
3. Composition/information on ingredients
Mixtures
light
CAS number%Chemical nameCommon name and synonyms
67-64-1Acetone
64742-49-0Naphtha (petroleum), hydrotreated
107-83-52-Methylpentane
124-38-9Carbon dioxide
110-54-3n-Hexane
40 - 50
30 - 40
5 - 10
5 - 10
1 - 3
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Wash off with soap and plenty of water. Take off contaminated clothing and wash before reuse.
Get medical attention if irritation develops and persists.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may
cause pulmonary edema and pneumonitis.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat.
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness
and pain. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
None known.
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
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Specific hazards arising from
without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
waterways, sewer, basements or confined areas.
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
the chemical
Contents under pressure. Pressurized container may explode when exposed to heat or flame. This
product is a poor conductor of electricity and can become electrostatically charged. If sufficient
charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation
may be significantly increased by the presence of small quantities of water or other contaminants.
Material will float and may ignite on surface of water. During fire, gases hazardous to health may
be formed.
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
General fire hazards
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when
exposed to heat or flame.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Remove all possible sources of ignition in the surrounding area. Many gases are
heavier than air and will spread along ground and collect in low or confined areas (sewers,
basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not
breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing
equipment. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to
avoid environmental contamination. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is
remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases. Use appropriate containment to avoid
environmental contamination.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Minimize fire risks from flammable and combustible materials (including
combustible dust and static accumulating liquids) or dangerous reactions with incompatible
materials. Handling operations that can promote accumulation of static charges include but are not
limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank
and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations.
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around
energized equipment. The metal container will conduct electricity if it contacts a live source. This
may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor.
Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure.
Pregnant or breastfeeding women must not handle this product. Should be handled in closed
systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe
good industrial hygiene practices. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. This material can accumulate static charge which may cause
spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to
remove static electricity. Secure cylinders in an upright position at all times, close all valves when
not in use. Store in a well-ventilated place. Store away from incompatible materials (see Section
10 of the SDS).
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
3 / 10
8. Exposure controls/personal protection
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
ACGIH Biological Exposure Indices
wash facilities and emergency shower must be available when handling this product.
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
n-Hexane (CAS 110-54-3)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
n-Hexane (CAS 110-54-3)Can be absorbed through the skin.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
n,
without
hydrolysis
Urine
510 ppm
100 ppm
250 ppm
30000 ppm
5000 ppm
50 ppm
*
*
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
4 / 10
Individual protection measures, such as personal protective equipment
wash work clothing and protective equipment to remove contaminants.
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton®.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards
General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Not available.
Solvent.
Not available.
Not available.
-244.7 °F (-153.7 °C) estimated
118.4 °F (48 °C) estimated
< 0 °F (< -17.8 °C) Tag Closed Cup
Fast.
Not available.
1 % estimated
12.8 % estimated
4543.8 hPa estimated
> 1 (air = 1)
0.77 estimated
Negligible.
Not available.
489.2 °F (254 °C) estimated
Not available.
Not available.
92.5 %
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Chlor-Free® Degreaser
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
TDL0Human12.5405 g/kg estimated
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat.
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness
May be fatal if swallowed and enters airways. Narcotic effects.
Test ResultsProductSpecies
4504.1494 mg/kg estimated
22466.334 ppm, 4 hours estimated
54.2562 mg/l, 4 Hours estimated
4725.2861 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes serious eye irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
Suspected of damaging fertility.
May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard
May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through
prolonged or repeated exposure.
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,
may cause chemical pneumonia, pulmonary injury or death.
Chronic effects
Prolonged inhalation may be harmful. May cause damage to organs through prolonged or
repeated exposure.
12. Ecological information
Ecotoxicity
ProductTest ResultsSpecies
Chlor-Free® Degreaser
Aquatic
Harmful to aquatic life with long lasting effects.
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
No data available.
2-Methylpentane3.74
Acetone-0.24
n-Hexane3.9
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from
residues / unused products
If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or
dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not
puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not
contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance
Hazardous waste code
Contaminated packaging
D001: Waste Flammable material with a flash point <140 F
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
UN1950
Aerosols, flammable, Limited Quantity
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable, Limited Quantity
2.1
Not applicable.
No.
10L
Read safety instructions, SDS and emergency procedures before handling.
Allowed.
SDS US
7 / 10
Cargo aircraft only
Allowed.
IMDG
UN number
UN proper shipping name
UN1950
AEROSOLS, LIMITED QUANTITY
Transport hazard class(es)
Class
Subsidiary risk
Packing group
2
Not applicable.
Environmental hazards
Marine pollutant
EmS
Special precautions for user
No.
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
Acetone (CAS 67-64-1)6532
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Acetone (CAS 67-64-1)35 %WV
DEA Exempt Chemical Mixtures Code Number
Acetone (CAS 67-64-1)6532
Food and Drug
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Not regulated.
Not regulated.
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
No
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
8 / 10
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
2-Methylpentane (CAS 107-83-5)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
n-Hexane (CAS 110-54-3)
US. Massachusetts RTK - Substance List
2-Methylpentane (CAS 107-83-5)
Acetone (CAS 67-64-1)
Carbon dioxide (CAS 124-38-9)
n-Hexane (CAS 110-54-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
2-Methylpentane (CAS 107-83-5)
Carbon dioxide (CAS 124-38-9)
n-Hexane (CAS 110-54-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
n-Hexane (CAS 110-54-3)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2)Listed: February 27, 1987
Cumene (CAS 98-82-8)Listed: April 6, 2010
Ethanal (CAS 75-07-0)Listed: April 1, 1988
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2)Listed: December 26, 1997
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
46.3 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a General Purpose Degreaser (aerosol). This product is not compliant
to be sold for use in California and the following counties in Utah: Box Elder, Cache, Davis, Salt
Lake, Tooele, Utah and Weber. This product is compliant in all other states.
VOC content (CA)
VOC content (OTC)
46.3 %
46.3 %
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Substances (EINECS)
YesAustraliaAustralian Inventory of Chemical Substances (AICS)
YesCanadaDomestic Substances List (DSL)
NoCanadaNon-Domestic Substances List (NDSL)
YesChinaInventory of Existing Chemical Substances in China (IECSC)
YesEuropeEuropean Inventory of Existing Commercial Chemical
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
YesKoreaExisting Chemicals List (ECL)
YesNew ZealandNew Zealand Inventory
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
9 / 10
Country(s) or regionInventory nameOn inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
08-19-2014
08-26-2014
Allison Cho
02
CRC # 463D-E
Health: 2*
Flammability: 4
Physical hazard: 0
Personal protection: B
Health: 2
Flammability: 4
Instability: 0
4
02
YesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) Inventory
Disclaimer
CRC cannot anticipate all conditions under which this information and its product, or the products
of other manufacturers in combination with its product, may be used. It is the user’s responsibility
to ensure safe conditions for handling, storage and disposal of the product, and to assume liability
for loss, injury, damage or expense due to improper use. The information contained in this
document applies to this specific material as supplied. It may not be valid for this material if it is
used in combination with any other materials. This information is accurate to the best of CRC
Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any
product, read all warnings and directions on the label. For further clarification of any information
contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC
Industries.
Material name: Chlor-Free® Degreaser
03185 Version #: 02 Revision date: 08-26-2014 Issue date: 08-19-2014
SDS US
10 / 10
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