CRC 03180 User Manual

SAFETY DATA SHEET
www.crcindustries.com
1. Identification
Product identifier Quick Clean™ Safety Solvent and Degreaser
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03180
General purpose degreaser
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Compressed gasGases under pressure
Category 2Skin corrosion/irritation
Category 1BCarcinogenicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
Contains gas under pressure; may explode if heated. Causes skin irritation. May cause drowsiness or dizziness. May cause cancer. Toxic to aquatic life with long lasting effects.
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Avoid breathing gas. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment.
If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical attention. Collect spillage.
Store locked up. Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
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Hazard(s) not otherwise
wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be
water pollutant under the Clean Water Act and should be prevented from contaminating soil or
classified (HNOC)
Supplemental information
When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene.
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
Perchloroethylene 127-18-4Tetrachloroethylene
124-38-9Carbon dioxide
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
90 - 100
1 - 5
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Rinse with water. Get medical attention if irritation develops and persists.
In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Irritation of nose and throat. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
Dry chemical, CO2, or water spray.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Exposure to high temperature may cause can to burst. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Avoid breathing gas. Do not touch damaged containers or spilled material unless
advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a
from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Collect spillage. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
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7. Handling and storage
well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. OSHA Table Z-2 (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
ACGIH Biological Exposure Indices
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label.
Level 1 Aerosol.
Contents under pressure. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49 °C/120 °F. Do not handle or store near an open flame, heat or other sources of ignition. Exposure to high temperature may cause can to burst. Store in a
8. Exposure controls/personal protection
Occupational exposure limits
PEL 9000 mg/m3Carbon dioxide (CAS
124-38-9)
ValueComponents Type
5000 ppm
Ceiling 200 ppmTetrachloroethylene (CAS
127-18-4)
TWA 100 ppm
STEL 30000 ppmCarbon dioxide (CAS
124-38-9)
TWA 5000 ppm STEL 100 ppmTetrachloroethylene (CAS
127-18-4)
TWA 25 ppm
STEL 54000 mg/m3Carbon dioxide (CAS
124-38-9)
TWA 9000 mg/m3
Biological limit values
ValueComponents Determinant Specimen Sampling Time
Tetrachloroethylene (CAS
0.5 mg/l Tetrachloroethy
127-18-4)
3 ppm Tetrachloroethy
* - For sampling details, please see the source document.
lene
lene
Blood
End-exhaled air
ValueComponents Type
ValueComponents Type
ValueComponents Type
30000 ppm
5000 ppm
*
*
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
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Exposure guidelines
wash facilities and emergency shower must be available when handling this product.
US - Minnesota Haz Subs: Skin designation applies
Tetrachloroethylene (CAS 127-18-4) Skin designation applies.
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Viton®. Polyvinyl alcohol (PVA). Nitrile. Silver Shield®
Wear appropriate chemical resistant clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Other information
Partition coefficient (oil/water)
Liquid.
Aerosol.
Colorless.
Irritating.
50 ppm
Not available.
-8.1 °F (-22.3 °C) estimated
250.3 °F (121.3 °C) estimated
None (Tag Closed Cup)
Very fast.
Not available.
Not available.
Not available.
1352.4 hPa estimated
5.76 (air = 1)
1.62
0.02 % (77 °F (25 °C))
Not available.
Not available.
Not available.
Not available.
97.7 % estimated
2.88
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
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10. Stability and reactivity
Skin contact
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as hydrogen chloride and possibly phosgene.
Strong oxidizing agents. Strong acids. Strong bases.
Hydrogen chloride. Trace amounts of chlorine and phosgene. Carbon oxides. Halogenated materials. Carbonyl halides.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Quick Clean™ Safety Solvent and Degreaser
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Prolonged inhalation may be harmful. May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation. May cause redness and pain.
Narcotic effects.
Test ResultsProduct Species
3305.1284 mg/kg estimated
20.4779 mg/l, 4 Hours estimated
2691.8162 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Tetrachloroethylene (CAS 127-18-4) 2A Probably carcinogenic to humans.
US. National Toxicology Program (NTP) Report on Carcinogens
Tetrachloroethylene (CAS 127-18-4) Reasonably Anticipated to be a Human Carcinogen.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
May be an aspiration hazard.
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
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Chronic effects
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
Partition coefficient n-octanol / water (log Kow)
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Quick Clean™ Safety Solvent and Degreaser
Aquatic
Components Test ResultsSpecies
Tetrachloroethylene (CAS 127-18-4)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Tetrachloroethylene 2.88
Mobility in soil
Other adverse effects
Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
LC50Fish 19.1805 mg/l, 96 hours estimatedFish
LC50Fish 4.73 - 5.27 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Not available.
Not available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
US RCRA Hazardous Waste U List: Reference
Tetrachloroethylene (CAS 127-18-4) U210
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.
D039: Waste Tetrachloroethylene F001: Waste Halogenated Solvent - Spent Halogenated Solvent Used in Degreasing F002: Waste Halogenated Solvent - Spent Halogenated Solvent
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Environmental hazards
Marine pollutant Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name
UN1950 Aerosols, poison, Packing Group III, Limited Quantity, MARINE POLLUTANT
2.2
6.1(PGIII)
2.2, 6.1 Not applicable.
Yes Read safety instructions, SDS and emergency procedures before handling. Not available. 306 None None
UN1950 Aerosols, non-flammable, containing substances in Division 6.1, Packing Group III, Limited
Quantity
Material name: Quick Clean™ Safety Solvent and Degreaser
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Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user
2.2
6.1 Not applicable. No. 2P Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo
Allowed.
aircraft
Cargo aircraft only
Allowed.
IMDG
UN number UN proper shipping name
UN1950 AEROSOLS, MARINE POLLUTANT
Transport hazard class(es)
Class
Subsidiary risk Packing group
2
6.1 Not applicable.
Environmental hazards
Marine pollutant EmS Special precautions for user
General information
Yes Not available. Read safety instructions, SDS and emergency procedures before handling.
DOT Regulated Marine Pollutant. IMDG Regulated Marine Pollutant.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Tetrachloroethylene (CAS 127-18-4)
CERCLA Hazardous Substance List (40 CFR 302.4)
Tetrachloroethylene (CAS 127-18-4)
CERCLA Hazardous Substances: Reportable quantity
Tetrachloroethylene (CAS 127-18-4) 100 LBS
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Tetrachloroethylene (CAS 127-18-4)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Not regulated.
Not regulated.
Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No
No
Material name: Quick Clean™ Safety Solvent and Degreaser
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US state regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Carbon dioxide (CAS 124-38-9)
Tetrachloroethylene (CAS 127-18-4)
US. Massachusetts RTK - Substance List
Carbon dioxide (CAS 124-38-9)
Tetrachloroethylene (CAS 127-18-4)
US. Pennsylvania Worker and Community Right-to-Know Law
Tetrachloroethylene (CAS 127-18-4)
Carbon dioxide (CAS 124-38-9)
US. Rhode Island RTK
Tetrachloroethylene (CAS 127-18-4)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Tetrachloroethylene (CAS 127-18-4) Listed: April 1, 1988
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
0 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a General Purpose Degreaser (aerosol). This product is not compliant to be sold for use in California, Connecticut, Delaware, The District of Columbia, Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Jersey, New York, and Rhode Island. This product is compliant in all other states.
VOC content (CA)
VOC content (OTC)
0 %
0 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
09-18-2013
08-07-2014
Allison Cho
02
CRC # 491G
SDS US
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HMIS® ratings
002
NFPA ratings
NFPA ratings
Health: 2* Flammability: 0 Physical hazard: 0 Personal protection: B
Health: 2 Flammability: 0 Instability: 0
Disclaimer
CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Quick Clean™ Safety Solvent and Degreaser
03180 Version #: 02 Revision date: 08-07-2014 Issue date: 09-18-2013
SDS US
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