CRC 03086 User Manual

SAFETY DATA SHEET
www.crcindustries.com
with adequate ventilation. Open doors and windows or use other means to ensure a fresh air
with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing
1. Identification
Product identifier Food Grade Penetrating Oil
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03086
Machine oil and lubricant
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Category 2Flammable aerosols
Compressed gasGases under pressure
Category 2Skin corrosion/irritation
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Not classified.
Not classified.
Danger
Flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Use
supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Avoid breathing gas. Wash hands thoroughly after handling. Wear protective gloves. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell.
Storage
Disposal
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
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Hazard(s) not otherwise
waste disposal, see section 13 of the SDS.
classified (HNOC)
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-47-8Distillates (petroleum), hydrotreated
light
8042-47-5White mineral oil (petroleum)
124-38-9Carbon dioxide
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Rinse with water. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Skin irritation. May cause redness and pain. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
60 - 70
30 - 40
1 - 3
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Powder. Alcohol resistant foam. Water. Water spray. Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may rupture when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. In the event of fire, cool tanks with water spray.
Flammable aerosol.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Avoid breathing gas. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
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7. Handling and storage
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
wash facilities and emergency shower must be available when handling this product.
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with skin. Avoid contact with eyes. Avoid contact with clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children.
8. Exposure controls/personal protection
Occupational exposure limits
124-38-9)
(petroleum) (CAS 8042-47-5)
124-38-9)
(petroleum) (CAS 8042-47-5)
124-38-9)
hydrotreated light (CAS 64742-47-8)
(petroleum) (CAS 8042-47-5)
Biological limit values
Appropriate engineering controls
Type
ValueComponents
Form
PEL 9000 mg/m3Carbon dioxide (CAS
5000 ppm
PEL 5 mg/m3 Mist.White mineral oil
Type
ValueComponents
Form
STEL 30000 ppmCarbon dioxide (CAS
TWA 5000 ppm TWA 5 mg/m3 Inhalable fraction.White mineral oil
Type
ValueComponents
Form
STEL 54000 mg/m3Carbon dioxide (CAS
30000 ppm
TWA 9000 mg/m3
5000 ppm
TWA 100 mg/m3Distillates (petroleum),
STEL 10 mg/m3 Mist.White mineral oil
TWA 5 mg/m3 Mist.
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
Wear safety glasses with side shields (or goggles).
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Skin protection
wash work clothing and protective equipment to remove contaminants.
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene.
Wear appropriate chemical resistant clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Clear.
Odorless.
Not available.
Not available.
-72.4 °F (-58 °C) estimated
424.4 °F (218 °C) estimated
200 °F (93.3 °C) Tag Closed Cup
Very slow.
Not available.
0.6 % estimated
5.5 % estimated
903.2 hPa estimated
> 1 (air = 1)
0.82 estimated
Negligible.
Not available.
392 °F (200 °C) estimated
Not available.
Not available.
98.4 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
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11. Toxicological information
Ingestion
Skin contact
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Chronic effects
Acute
Information on likely routes of exposure
May be fatal if swallowed and enters airways.
Inhalation
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Food Grade Penetrating Oil
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful.
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
May be fatal if swallowed and enters airways. Narcotic effects.
Test ResultsProduct Species
2312.1357 mg/kg estimated
61577.1328 ppm, 4 hours estimated
12.7064 mg/l, 4 Hours estimated
6512.9658 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
White mineral oil (petroleum) (CAS 8042-47-5) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Narcotic effects.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
May be fatal if swallowed and enters airways.
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Food Grade Penetrating Oil
Aquatic
Toxic to aquatic life.
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
LC50Fish 6.7735 mg/l, 96 hours estimatedFish
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Components Test ResultsSpecies
Acute
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Aquatic
LC50Fish 2.2 mg/l, 96 hoursBluegill (Lepomis macrochirus)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty container can be recycled. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group
UN1950 Aerosols, flammable, Limited Quantity
2.1
-
2.1 Not applicable. Read safety instructions, SDS and emergency procedures before handling. N82 306 None None
UN1950 Aerosols, flammable, Limited Quantity
2.1
­Not applicable. No. 10L Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1950 AEROSOLS, LIMITED QUANTITY
2
­Not applicable.
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
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Environmental hazards
Marine pollutant EmS Special precautions for user
No. F-D, S-U Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Carbon dioxide (CAS 124-38-9)
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
US. Massachusetts RTK - Substance List
Carbon dioxide (CAS 124-38-9)
White mineral oil (petroleum) (CAS 8042-47-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Carbon dioxide (CAS 124-38-9)
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
White mineral oil (petroleum) (CAS 8042-47-5)
US. Rhode Island RTK
None.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
Not regulated.
Not regulated.
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
No
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Volatile organic compounds (VOC) regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
EPA
VOC content (40 CFR
98.4 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
This product is regulated as a Penetrant. This product is compliant for use in all 50 states.
0 %
0 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
Disclaimer
02-06-2014
11-20-2014
Allison Cho
03
CRC # 555B-C
Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: B
Health: 1 Flammability: 2 Instability: 0
2
01
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Food Grade Penetrating Oil
03086 Version #: 03 Revision date: 11-20-2014 Issue date: 02-06-2014
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