CRC 03065 User Manual

SAFETY DATA SHEET
www.crcindustries.com
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if
1. Identification
Product identifier Food Grade Belt Dressing
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03065
Belt dressing
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Category 1Flammable aerosols
Liquefied gasGases under pressure
Category 2Reproductive toxicity (fertility)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Do not breathe mist or vapor. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical attention.
Material name: Food Grade Belt Dressing
1741 Version #: 01 Issue date: 02-12-2014
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Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
97.27% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-49-0Naphtha (petroleum), hydrotreated
light
68476-86-8Liquefied Petroleum Gas
107-83-52-Methylpentane
9003-29-6Isobutylene polymer
110-54-3n-Hexane
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Wash off with soap and water. Take off contaminated clothing and wash before reuse.
Rinse with plenty of water.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
40 - 50
20 - 30
10 - 20
5 - 10
1 - 3
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Water spray. Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. In the event of fire, cool tanks with water spray.
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate personal protective equipment. Do not breathe gas. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Material name: Food Grade Belt Dressing
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Methods and materials for
waste disposal, see section 13 of the SDS.
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
ACGIH Biological Exposure Indices
containment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin and eyes. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children.
8. Exposure controls/personal protection
Occupational exposure limits
PEL 1800 mg/m3n-Hexane (CAS 110-54-3)
STEL 1000 ppm2-Methylpentane (CAS
107-83-5)
TWA 500 ppm TWA 50 ppmn-Hexane (CAS 110-54-3)
Ceiling 1800 mg/m32-Methylpentane (CAS
107-83-5)
TWA 350 mg/m3
TWA 180 mg/m3n-Hexane (CAS 110-54-3)
Biological limit values
ValueComponents Type
500 ppm
ValueComponents Type
ValueComponents Type
510 ppm
100 ppm
50 ppm
ValueComponents Determinant Specimen Sampling Time
n-Hexane (CAS 110-54-3)
0.4 mg/l 2,5-Hexanedio n,
without
Urine
hydrolysis
* - For sampling details, please see the source document.
Material name: Food Grade Belt Dressing
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*
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Exposure guidelines
wash work clothing and protective equipment to remove contaminants.
US - California OELs: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton®.
Wear appropriate chemical resistant clothing.
Wear positive pressure self-contained breathing apparatus (SCBA). Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Light amber.
Mild solvent.
Not available.
Not available.
-244.7 °F (-153.7 °C) estimated
118.4 °F (48 °C) estimated
< 0 °F (< -17.8 °C) Tag Closed Cup
Fast.
Not available.
1 % estimated
8 % estimated
1682.1 hPa estimated
> 1 (air = 1)
0.64 estimated
Negligible.
Not available.
489.2 °F (254 °C) estimated
Not available.
Not available.
92.8 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Material name: Food Grade Belt Dressing
1741 Version #: 01 Issue date: 02-12-2014
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
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Incompatible materials
Ingestion
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Hazardous decomposition
Chlorine.
Carbon oxides.
products
11. Toxicological information
Information on likely routes of exposure
May be fatal if swallowed and enters airways.
Inhalation
Skin contact
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Food Grade Belt Dressing
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May cause damage to organs by inhalation.
Prolonged skin contact may cause temporary irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
Direct contact with eyes may cause temporary irritation.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
May be fatal if swallowed and enters airways. Narcotic effects.
Test ResultsProduct Species
3558.8184 mg/kg estimated
11984.4893 ppm, 4 hours estimated
315.9885 mg/l, 4 hours estimated
23333.2285 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
Suspected of damaging fertility.
Narcotic effects.
single exposure
Specific target organ toxicity -
May cause damage to organs through prolonged or repeated exposure.
repeated exposure
May be fatal if swallowed and enters airways.
Chronic effects
Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Food Grade Belt Dressing
Components Test ResultsSpecies
Isobutylene polymer (CAS 9003-29-6)
Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
LC50Fish 1621.4834 mg/l, 96 hours estimatedFish
Material name: Food Grade Belt Dressing
1741 Version #: 01 Issue date: 02-12-2014
EC50Crustacea > 10000 mg/l, 48 hoursDaphnia magna
> 1000 mg/l, 48 hours
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Components Test ResultsSpecies
Acute
Partition coefficient n-octanol / water (log Kow)
Aquatic
LC50Fish > 1000 mg/l, 96 hoursFathead minnow (Pimephales promelas)
(Oncorhynchus mykiss)
n-Hexane (CAS 110-54-3)
Aquatic
LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
No data available.
2-Methylpentane 3.74 n-Hexane 3.9
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
This material and its container must be disposed of as hazardous waste. If discarded, this product is considered a RCRA ignitable waste, D001. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.
D001: Waste Flammable material with a flash point <140 F
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
> 10000 mg/l, 96 hoursRainbow trout,donaldson trout
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number UN proper shipping name
UN1950 Aerosols, flammable, Limited Quantity
2.1
-
2.1 Not applicable. Read safety instructions, SDS and emergency procedures before handling. N82 306 None None
UN1950 Aerosols, flammable, Limited Quantity
2.1
­Not applicable. No. 10L Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1950 AEROSOLS, LIMITED QUANTITY
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Transport hazard class(es)
Class
Subsidiary risk Packing group
2
­Not applicable.
Environmental hazards
Marine pollutant EmS Special precautions for user
No. Not available. Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
n-Hexane (CAS 110-54-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
n-Hexane (CAS 110-54-3)
CERCLA Hazardous Substances: Reportable quantity
n-Hexane (CAS 110-54-3) 5000 lbs
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
n-Hexane (CAS 110-54-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
US state regulations
US. New Jersey RTK - Substances: Listed substance
2-Methylpentane (CAS 107-83-5)
n-Hexane (CAS 110-54-3)
US. Massachusetts RTK - Substance List
2-Methylpentane (CAS 107-83-5)
n-Hexane (CAS 110-54-3)
US. Pennsylvania RTK - Hazardous Substances
2-Methylpentane (CAS 107-83-5)
n-Hexane (CAS 110-54-3)
US. Rhode Island RTK
n-Hexane (CAS 110-54-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
Not regulated.
Not regulated.
Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
No
Material name: Food Grade Belt Dressing
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Volatile organic compounds (VOC) regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
EPA
VOC content (40 CFR
100 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
Not regulated
92.8 %
92.8 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Disclaimer
02-12-2014
Allison Cho
01
CRC # 439C/D
Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B
Health: 2 Flammability: 4 Instability: 0
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Food Grade Belt Dressing
1741 Version #: 01 Issue date: 02-12-2014
SDS US
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