CRC 03060 User Manual

Page 1
SAFETY DATA SHEET
www.crcindustries.com
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if
1. Identification
Product identifier Screwloose® Super Penetrant
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03060
General purpose penetrant
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Category 1Flammable aerosols
Compressed gasGases under pressure
Category 2Skin corrosion/irritation
Category 2Serious eye damage/eye irritation
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Not classified.
Not classified.
Danger
swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Toxic to aquatic life.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Avoid breathing gas, mist or vapor. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Wear protective gloves and eye/face protection. Wash hands thoroughly after handling. Avoid release to the environment.
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
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Response
with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing
with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-47-8Distillates (petroleum), hydrotreated
light
8052-41-3Stoddard Solvent
64741-88-4Distillates (petroleum),
solvent-refined heavy paraffinic
29911-27-1Dipropylene glycol monopropyl
ether (dpmp)
124-38-9Carbon dioxide
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
50 - 60
20 - 30
5 - 10
3 - 5
1 - 3
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause drowsiness or dizziness. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
Powder. Alcohol resistant foam. Water. Water spray. Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may rupture when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
General fire hazards
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
Extremely flammable aerosol.
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6. Accidental release measures
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
which may cause spark and become an ignition source. Store away from incompatible materials
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Avoid breathing gas. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid breathing gas. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label.
Conditions for safe storage, including any incompatibilities
Level 3 Aerosol.
Store in a well-ventilated place. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge
(see Section 10 of the SDS). Keep out of the reach of children.
8. Exposure controls/personal protection
Occupational exposure limits
Type
PEL 9000 mg/m3Carbon dioxide (CAS
124-38-9)
PEL 5 mg/m3 Mist.Distillates (petroleum), solvent-refined heavy paraffinic (CAS 64741-88-4)
PEL 2900 mg/m3Stoddard Solvent (CAS 8052-41-3)
ValueComponents
5000 ppm
2000 mg/m3 500 ppm
500 ppm
Form
Type
STEL 30000 ppmCarbon dioxide (CAS 124-38-9)
TWA 5000 ppm
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum), solvent-refined heavy paraffinic (CAS 64741-88-4)
TWA 100 ppmStoddard Solvent (CAS 8052-41-3)
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
ValueComponents
Form
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US. NIOSH: Pocket Guide to Chemical Hazards
Type
wash facilities and emergency shower must be available when handling this product.
wash work clothing and protective equipment to remove contaminants.
STEL 54000 mg/m3Carbon dioxide (CAS 124-38-9)
TWA 9000 mg/m3
TWA 100 mg/m3Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Ceiling 1800 mg/m3Distillates (petroleum), solvent-refined heavy paraffinic (CAS 64741-88-4)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
Ceiling 1800 mg/m3Stoddard Solvent (CAS 8052-41-3)
TWA 350 mg/m3
Biological limit values
Appropriate engineering controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
ValueComponents
30000 ppm
5000 ppm
Form
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene.
Wear appropriate chemical resistant clothing.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Liquid.
Aerosol.
Clear. Light amber.
Petroleum.
Not available.
Not available.
-121 °F (-85 °C) estimated
315 °F (157.2 °C) estimated
141 °F (60.6 °C) Tag Closed Cup
Slow
Not available.
0.6 % estimated
6 % estimated
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
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Vapor pressure
Ingestion
Skin contact
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Vapor density
Relative density
Solubility (water)
Partition coefficient
1431.7 hPa estimated
> 4 (air = 1)
0.82 estimated
Not available.
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
401 °F (205 °C) estimated
Not available.
Not available.
97.5 %
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
May be fatal if swallowed and enters airways.
Inhalation
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Screwloose® Super Penetrant
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful.
Causes skin irritation.
Causes serious eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
May be fatal if swallowed and enters airways. Narcotic effects.
Test ResultsProduct Species
2808.0522 mg/kg estimated
8.137 mg/l, 4 Hours estimated
6051.5747 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Germ cell mutagenicity
Reproductive toxicity
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
Causes skin irritation.
Causes serious eye irritation.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects.
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Specific target organ toxicity -
Aspiration hazard
Chronic effects
Acute
Acute
Acute
Partition coefficient n-octanol / water (log Kow)
single exposure
Specific target organ toxicity ­repeated exposure
Narcotic effects.
Not classified.
May be fatal if swallowed and enters airways.
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Screwloose® Super Penetrant
Aquatic
Components Test ResultsSpecies
Dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1)
Aquatic
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Aquatic
Toxic to aquatic life.
EC50Crustacea 2051.282 mg/l, 48 hours estimatedDaphnia
LC50Fish 3.7538 mg/l, 96 hours estimatedFish
EC50Crustacea > 100 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish > 100 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
LC50Fish 2.2 mg/l, 96 hoursBluegill (Lepomis macrochirus)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Dipropylene glycol monopropyl ether (dpmp) 0.87 OECD 107 Stoddard Solvent 3.16 - 7.15
Mobility in soil
Other adverse effects
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Empty container can be recycled. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk Label(s)
UN1950 Aerosols, flammable, limited quantity
2.1
-
2.1
Material name: Screwloose® Super Penetrant
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Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards
Marine pollutant EmS Special precautions for user
Not applicable. Read safety instructions, SDS and emergency procedures before handling. N82 306 None None
UN1950 Aerosols, flammable, limited quantity
2.1
­Not applicable. No. 10L Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1950 AEROSOLS, LIMITED QUANTITY
2
­Not applicable.
No. Not available. Read safety instructions, SDS and emergency procedures before handling.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Not regulated.
Not regulated.
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Section 311/312
Hazard categories
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
Carbon dioxide (CAS 124-38-9)
Stoddard Solvent (CAS 8052-41-3)
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
US. Massachusetts RTK - Substance List
Carbon dioxide (CAS 124-38-9)
Stoddard Solvent (CAS 8052-41-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Carbon dioxide (CAS 124-38-9)
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Stoddard Solvent (CAS 8052-41-3)
US. Rhode Island RTK
None.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
97.5 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
This product is regulated as a Penetrant. This product is compliant for use in all 50 states.
24.2 %
24.2 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
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16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
10-07-2013
03-30-2015
Allison Cho
02
CRC # 575H
Health: 2 Flammability: 4 Physical hazard: 0 Personal protection: B
Health: 2 Flammability: 4 Instability: 0
4
02
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Screwloose® Super Penetrant
03060 Version #: 02 Revision date: 03-30-2015 Issue date: 10-07-2013
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