CRC 03030 User Manual

SAFETY DATA SHEET
www.crcindustries.com
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if
1. Identification
Product identifier Extreme Duty Silicone
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03030
Silicone-based multi-purpose lubricant
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Category 1Flammable aerosols
Liquefied gasGases under pressure
Category 2Skin corrosion/irritation
Category 2Reproductive toxicity (fertility)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
SDS US
1 / 9
Precautionary statement
with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If exposed or concerned: Get medical attention. Collect spillage.
Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
3. Composition/information on ingredients
Mixtures
light
HFC-152a 75-37-61,1-Difluoroethane
CAS number %Chemical name Common name and synonyms
64742-49-0Naphtha (petroleum), hydrotreated
107-83-52-Methylpentane
68957-05-1Chlorophenylmethylpolysiloxane
110-54-3n-Hexane
75-83-22,2-Dimethylbutane
40 - 50
30 - 40
10 - 20
3 - 5
1 - 3
< 0.2
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Rinse with water. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.
None known.
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
SDS US
2 / 9
Specific hazards arising from
without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
waterways, sewer, basements or confined areas.
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up.
Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is
remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination.
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label.
Level 3 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
PEL 1800 mg/m3n-Hexane (CAS 110-54-3)
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
ValueComponents Type
SDS US
3 / 9
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
75-83-2)
US. NIOSH: Pocket Guide to Chemical Hazards
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
ACGIH Biological Exposure Indices
wash facilities and emergency shower must be available when handling this product.
107-83-5)
75-83-2)
107-83-5)
ValueComponents Type
500 ppm
ValueComponents Type
STEL 1000 ppm2,2-Dimethylbutane (CAS
TWA 500 ppm STEL 1000 ppm2-Methylpentane (CAS
TWA 500 ppm TWA 50 ppmn-Hexane (CAS 110-54-3)
ValueComponents Type
Ceiling 1800 mg/m32,2-Dimethylbutane (CAS
510 ppm
TWA 350 mg/m3
100 ppm
Ceiling 1800 mg/m32-Methylpentane (CAS
510 ppm
TWA 350 mg/m3
100 ppm
TWA 180 mg/m3n-Hexane (CAS 110-54-3)
50 ppm
TWA 2700 mg/m31,1-Difluoroethane (CAS
75-37-6)
Biological limit values
ValueComponents Determinant Specimen Sampling Time
n-Hexane (CAS 110-54-3)
0.4 mg/l 2,5-Hexanedio n,
without
hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Urine
ValueComponents Type
1000 ppm
*
Skin protection
Hand protection
Other
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton®.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
SDS US
4 / 9
Respiratory protection
wash work clothing and protective equipment to remove contaminants.
Thermal hazards
General hygiene considerations
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Clear water-white.
Mild solvent.
Not available.
Not available.
-244.7 °F (-153.7 °C) estimated
118.4 °F (48 °C) estimated
< 0 °F (< -17.8 °C) Tag Closed Cup
Fast.
Not available.
1 % estimated
8 % estimated
3083.3 hPa estimated
> 1 (air = 1)
0.76 estimated
Negligible.
Not available.
437 °F (225 °C) estimated
Not available.
Not available.
97 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides.
11. Toxicological information
Information on likely routes of exposure
Ingestion
Inhalation
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.
SDS US
5 / 9
Skin contact
Causes skin irritation.
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Partition coefficient n-octanol / water (log Kow)
Direct contact with eyes may cause temporary irritation.
Symptoms related to the physical, chemical and
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain.
toxicological characteristics
Information on toxicological effects
May be fatal if swallowed and enters airways. Narcotic effects.
Extreme Duty Silicone
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
Suspected of damaging fertility.
May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity -
May cause damage to organs through prolonged or repeated exposure.
repeated exposure
Aspiration hazard
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death.
Chronic effects
Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure.
Test ResultsProduct Species
4176.125 mg/kg estimated
66693.3438 ppm, 4 hours estimated
62.4636 mg/l, 4 hours estimated
5884.707 mg/kg estimated
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
Extreme Duty Silicone
Aquatic
Components Test ResultsSpecies
n-Hexane (CAS 110-54-3)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
1,1-Difluoroethane 0.75 2,2-Dimethylbutane 3.82
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
Toxic to aquatic life with long lasting effects.
LC50Fish 2398.897 mg/l, 96 hours estimatedFish
LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product.
No data available.
SDS US
6 / 9
Partition coefficient n-octanol / water (log Kow)
2-Methylpentane 3.74
with all applicable regulations.
n-Hexane 3.9
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user Other information
Passenger and cargo
aircraft
Cargo aircraft only
IMDG
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards
Marine pollutant EmS Special precautions for user
D001: Waste Flammable material with a flash point <140 F
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
UN1950 Aerosols, flammable, Limited Quantity
2.1
-
2.1 Not applicable. Read safety instructions, SDS and emergency procedures before handling. N82 306 None None
UN1950 Aerosols, flammable, Limited Quantity
2.1
­Not applicable. No. 10L Read safety instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
UN1950 AEROSOLS, LIMITED QUANTITY
2
­Not applicable.
No. F-D, S-U Read safety instructions, SDS and emergency procedures before handling.
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
SDS US
7 / 9
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
n-Hexane (CAS 110-54-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
n-Hexane (CAS 110-54-3)
CERCLA Hazardous Substances: Reportable quantity
n-Hexane (CAS 110-54-3) 5000 LBS
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
n-Hexane (CAS 110-54-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
1,1-Difluoroethane (CAS 75-37-6)
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. New Jersey Worker and Community Right-to-Know Act
2,2-Dimethylbutane (CAS 75-83-2)
2-Methylpentane (CAS 107-83-5)
1,1-Difluoroethane (CAS 75-37-6)
n-Hexane (CAS 110-54-3)
US. Massachusetts RTK - Substance List
1,1-Difluoroethane (CAS 75-37-6)
2-Methylpentane (CAS 107-83-5)
n-Hexane (CAS 110-54-3)
US. Pennsylvania Worker and Community Right-to-Know Law
2,2-Dimethylbutane (CAS 75-83-2)
2-Methylpentane (CAS 107-83-5)
n-Hexane (CAS 110-54-3)
US. Rhode Island RTK
1,1-Difluoroethane (CAS 75-37-6)
n-Hexane (CAS 110-54-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
Not regulated.
Not regulated.
Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
No
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
SDS US
8 / 9
Volatile organic compounds (VOC) regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
EPA
VOC content (40 CFR
60 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Silicone Based Multi-Purpose Lubricant. This product is compliant for use in all 50 states.
VOC content (CA)
VOC content (OTC)
60 %
60 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
NFPA ratings
Disclaimer
01-08-2015
Allison Cho
01
Not available.
Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B
Health: 2 Flammability: 4 Instability: 0
4
02
CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Material name: Extreme Duty Silicone
03030 Version #: 01 Issue date: 01-08-2015
SDS US
9 / 9
Loading...