Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters
airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs
through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
Do not puncture or incinerate container. Do not expose to heat or store at temperatures above
49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to
ensure a fresh air supply during use and while product is drying. If you experience any symptoms
listed on this label, increase ventilation or leave the area. Do not breathe gas, mist or vapor. Wear
protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing
must not be allowed out of the workplace. Wash hands thoroughly after handling. Avoid release to
the environment.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
1 / 10
Response
with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
90.18% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
Store locked up. Protect from sunlight. Store in a well-ventilated place. Exposure to high
temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
CAS number%Chemical nameCommon name and synonyms
64742-46-7Distillates (petroleum), hydrotreated
middle
88917-22-0Dipropylene glycol monomethyl
ether acetate
29911-27-1Dipropylene glycol monopropyl
ether (dpmp)
8006-64-2Turpentine, oil
108-83-82,6-Dimethyl-4-heptanone
ProprietaryFatty ester
8052-41-3Stoddard Solvent
124-38-9Carbon dioxide
8002-09-3Pine oil
94266-48-5Pinus sylvestris extract
40 - 50
5 - 10
5 - 10
5 - 10
3 - 5
3 - 5
3 - 5
1 - 3
1 - 3
1 - 3
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing immediately and wash skin with soap and water. If skin irritation or
rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may
cause pulmonary edema and pneumonitis.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an
allergic skin reaction. Dermatitis. Rash. May cause redness and pain. Prolonged exposure may
cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Wash contaminated
clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Water.
None known.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
2 / 10
Specific hazards arising from
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all
directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay
away from tanks engulfed in flame. Move containers from fire area if you can do so without risk.
Containers should be cooled with water to prevent vapor pressure build up. For massive fire in
cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire
burn out.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Do not
breathe mist or vapor. Do not breathe gas. Ensure adequate ventilation. Local authorities should
be advised if significant spillages cannot be contained. For personal protection, see section 8 of
the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if
the leak is irreparable. Isolate area until gas has dispersed. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Scoop up used absorbent into drums or other appropriate container.
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery,
flush area with water.
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray
button is missing or defective. Do not spray on a naked flame or any other incandescent material.
Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,
grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around
energized equipment. The metal container will conduct electricity if it contacts a live source. This
may result in injury to the user from electrical shock and/or flash fire. Do not re-use empty
containers. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin. Avoid
contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do
not empty into drains. For product usage instructions, please see the product label.
Level 1 Aerosol.
Store in a well-ventilated place. Contents under pressure. Do not expose to heat or store at
temperatures above 120°F/49°C as can may burst. Do not puncture, incinerate or crush. Do not
handle or store near an open flame, heat or other sources of ignition. Store away from
incompatible materials (see Section 10 of the SDS). Keep out of the reach of children.
8. Exposure controls/personal protection
Occupational exposure limits
Type
PEL290 mg/m32,6-Dimethyl-4-heptanone
(CAS 108-83-8)
PEL9000 mg/m3Carbon dioxide (CAS
124-38-9)
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
ValueComponents
50 ppm
Form
SDS US
3 / 10
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
hydrotreated middle (CAS
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
wash facilities and emergency shower must be available when handling this product.
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
ValueComponents
25 ppm
30000 ppm
5000 ppm
100 ppm
Form
Skin protection
Hand protection
Other
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
Wear protective gloves such as: Nitrile. Rubber.
Wear appropriate chemical resistant clothing.
SDS US
4 / 10
Respiratory protection
wash work clothing and protective equipment to remove contaminants. Contaminated work
Ingestion
Thermal hazards
General hygiene
considerations
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
clothing should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
Liquid.
Aerosol.
Red.
Pleasant pine.
Not available.
Not available.
-121 °F (-85 °C) estimated
311 °F (155 °C) estimated
147 °F (63.9 °C) Tag Closed Cup
Moderate
Not available.
0.7 % estimated
7.1 % estimated
1958.7 hPa estimated
> 1 (air = 1)
0.86
Negligible.
Not available.
401 °F (205 °C) estimated
Not available.
Not available.
98.4 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Strong oxidizing agents. Chlorine.
Carbon monoxide. Irritating and/or toxic fumes and gases may be emitted upon the products
decomposition.
11. Toxicological information
Information on likely routes of exposure
May be fatal if swallowed and enters airways.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
5 / 10
Inhalation
Skin contact
Eye contact
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Acute
Prolonged inhalation may be harmful. May cause damage to organs by inhalation. May cause
irritation to the respiratory system.
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
Symptoms related to the
physical, chemical and
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an
allergic skin reaction. Skin irritation. May cause redness and pain. Dermatitis. Rash.
toxicological characteristics
Information on toxicological effects
Acute toxicity
May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause
respiratory irritation.
Knock'er Loose® Penetrating Solvent
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
ACGIH sensitization
Turpentine, oil (CAS 8006-64-2)Sensitizer.
Not available.
Skin sensitization
Germ cell mutagenicity
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Respiratory tract irritation.
single exposure
Specific target organ toxicity -
May cause damage to organs through prolonged or repeated exposure.
repeated exposure
May be fatal if swallowed and enters airways.
Chronic effects
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause
damage to organs through prolonged or repeated exposure.
Test ResultsProductSpecies
9017.0938 mg/kg
117.794 mg/l, 4 hours estimated
4127.4175 mg/kg estimated
12. Ecological information
Ecotoxicity
ProductTest ResultsSpecies
Knock'er Loose® Penetrating Solvent
Aquatic
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
111 mg/l, 96 hoursRainbow trout,donaldson trout
13. Disposal considerations
Disposal of waste from
residues / unused products
Hazardous waste code
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33).
Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush.
Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds,
accordance with local/regional/national regulations.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
UN1950
Aerosols, non-flammable, limited quantity
2.2
-
2.2
Not applicable.
Read safety instructions, SDS and emergency procedures before handling.
Not available.
306
None
None
UN1950
Aerosols, non-flammable, limited quantity
2.2
Not applicable.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
7 / 10
Environmental hazards
ERG Code
Special precautions for user
No.
2L
Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo
Allowed.
aircraft
Cargo aircraft only
Allowed.
IMDG
UN number
UN proper shipping name
UN1950
AEROSOLS, LIMITED QUANTITY
Transport hazard class(es)
Class
Subsidiary risk
Packing group
2
Not applicable.
Environmental hazards
Marine pollutant
EmS
Special precautions for user
No.
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312
Hazard categories
SARA 302 Extremely
hazardous substance
US state regulations
US. New Jersey Worker and Community Right-to-Know Act
2,6-Dimethyl-4-heptanone (CAS 108-83-8)
Carbon dioxide (CAS 124-38-9)
Pine oil (CAS 8002-09-3)
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Not regulated.
Not regulated.
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
No
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
8 / 10
Stoddard Solvent (CAS 8052-41-3)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Turpentine, oil (CAS 8006-64-2)
US. Massachusetts RTK - Substance List
2,6-Dimethyl-4-heptanone (CAS 108-83-8)
Carbon dioxide (CAS 124-38-9)
Stoddard Solvent (CAS 8052-41-3)
Turpentine, oil (CAS 8006-64-2)
US. Pennsylvania Worker and Community Right-to-Know Law
2,6-Dimethyl-4-heptanone (CAS 108-83-8)
Carbon dioxide (CAS 124-38-9)
Stoddard Solvent (CAS 8052-41-3)
US. Rhode Island RTK
None.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
98.4 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
VOC content (CA)
VOC content (OTC)
This product is regulated as a Penetrant. This product is compliant for use in all 50 states.
23.6 %
23.6 %
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustraliaAustralian Inventory of Chemical Substances (AICS)
YesCanadaDomestic Substances List (DSL)
NoCanadaNon-Domestic Substances List (NDSL)
NoChinaInventory of Existing Chemical Substances in China (IECSC)
NoEuropeEuropean Inventory of Existing Commercial Chemical
NoEuropeEuropean List of Notified Chemical Substances (ELINCS)
NoJapanInventory of Existing and New Chemical Substances (ENCS)
NoKoreaExisting Chemicals List (ECL)
NoNew ZealandNew Zealand Inventory
NoPhilippinesPhilippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
11-19-2013
06-11-2014
Allison Cho
02
CRC # 548A
Health: 1*
Flammability: 1
Physical hazard: 0
Personal protection: B
SDS US
9 / 10
NFPA ratings
NFPA ratings
Health: 1
Flammability: 1
Instability: 0
1
01
Disclaimer
The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
10 / 10
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