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SAFETY DATA SHEET
1. Identification
Product identifier Knock'er Loose® Penetrating Solvent
Other means of identification
Product code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name
Address
Telephone
General Information
Technical
Assistance
Customer Service
24-Hour Emergency
(CHEMTREC)
Website
03016, 03020
Penetrant
None known.
CRC Industries, Inc.
885 Louis Dr.
Warminster, PA 18974 US
215-674-4300
800-521-3168
800-272-4620
800-424-9300 (US)
703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Compressed gasGases under pressure
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 1Sensitization, skin
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 2Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
Danger
Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters
airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs
through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.
Do not puncture or incinerate container. Do not expose to heat or store at temperatures above
49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means to
ensure a fresh air supply during use and while product is drying. If you experience any symptoms
listed on this label, increase ventilation or leave the area. Do not breathe gas, mist or vapor. Wear
protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing
must not be allowed out of the workplace. Wash hands thoroughly after handling. Avoid release to
the environment.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
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Response
with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
90.18% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for
breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
Store locked up. Protect from sunlight. Store in a well-ventilated place. Exposure to high
temperature may cause can to burst.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-46-7Distillates (petroleum), hydrotreated
middle
88917-22-0Dipropylene glycol monomethyl
ether acetate
29911-27-1Dipropylene glycol monopropyl
ether (dpmp)
8006-64-2Turpentine, oil
108-83-82,6-Dimethyl-4-heptanone
ProprietaryFatty ester
8052-41-3Stoddard Solvent
124-38-9Carbon dioxide
8002-09-3Pine oil
94266-48-5Pinus sylvestris extract
40 - 50
5 - 10
5 - 10
5 - 10
3 - 5
3 - 5
3 - 5
1 - 3
1 - 3
1 - 3
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing immediately and wash skin with soap and water. If skin irritation or
rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may
cause pulmonary edema and pneumonitis.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an
allergic skin reaction. Dermatitis. Rash. May cause redness and pain. Prolonged exposure may
cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Wash contaminated
clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Water.
None known.
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
SDS US
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Specific hazards arising from
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all
directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay
away from tanks engulfed in flame. Move containers from fire area if you can do so without risk.
Containers should be cooled with water to prevent vapor pressure build up. For massive fire in
cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire
burn out.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Do not
breathe mist or vapor. Do not breathe gas. Ensure adequate ventilation. Local authorities should
be advised if significant spillages cannot be contained. For personal protection, see section 8 of
the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if
the leak is irreparable. Isolate area until gas has dispersed. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Scoop up used absorbent into drums or other appropriate container.
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery,
flush area with water.
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray
button is missing or defective. Do not spray on a naked flame or any other incandescent material.
Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,
grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around
energized equipment. The metal container will conduct electricity if it contacts a live source. This
may result in injury to the user from electrical shock and/or flash fire. Do not re-use empty
containers. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin. Avoid
contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do
not empty into drains. For product usage instructions, please see the product label.
Level 1 Aerosol.
Store in a well-ventilated place. Contents under pressure. Do not expose to heat or store at
temperatures above 120°F/49°C as can may burst. Do not puncture, incinerate or crush. Do not
handle or store near an open flame, heat or other sources of ignition. Store away from
incompatible materials (see Section 10 of the SDS). Keep out of the reach of children.
8. Exposure controls/personal protection
Occupational exposure limits
Type
PEL 290 mg/m32,6-Dimethyl-4-heptanone
(CAS 108-83-8)
PEL 9000 mg/m3Carbon dioxide (CAS
124-38-9)
Material name: Knock'er Loose® Penetrating Solvent
1727 Version #: 02 Revision date: 06-11-2014 Issue date: 11-19-2013
ValueComponents
50 ppm
Form
SDS US
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