CRC 03011 User Manual

SAFETY DATA SHEET
www.crcindustries.com
with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated
1. Identification
Product identifier 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
Other means of identification
Product code
Recommended use
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name Address
Telephone
General Information Technical Assistance Customer Service 24-Hour Emergency (CHEMTREC)
Website
03006, 03007, 03009, 03011
Multi-purpose lubricant
None known.
CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US
215-674-4300 800-521-3168
800-272-4620 800-424-9300 (US) 703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Category 4Flammable liquids
Category 2Skin corrosion/irritation
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment, acute
hazard
Not classified.
Danger
Combustible liquid. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. In case of fire: Do not use water jet as an extinguisher, as this will spread the fire.
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
33.67% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment.
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national regulations.
None known.
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3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
64742-47-8Distillates (petroleum),
Hydrotreated Light
64741-88-4Distillates (petroleum),
Solvent-refined Heavy Paraffinic
123-95-5n-Butyl stearate
61788-89-4Fatty Acids, C18-unsatd., Dimers
8009-03-8Petrolatum
5989-27-5d-Limonene
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Rinse with water. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis.
Direct contact with eyes may cause temporary irritation. Skin irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
60 - 70
10 - 20
3 - 5
1 - 3
1 - 3
< 0.2
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Alcohol resistant foam. Water spray. Water fog. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2).
Water. Do not use water jet as an extinguisher, as this will spread the fire.
The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved.
Combustible liquid.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
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Methods and materials for
water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
U.S. - OSHA
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ACGIH
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
containment and cleaning up
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Avoid contact with clothing. Use only in
after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label.
Keep away from heat and sources of ignition. Store in original tightly closed container. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep in an area equipped with sprinklers.
8. Exposure controls/personal protection
Occupational exposure limits
Type
TWA 5 mg/m3 RespirableFatty Acids, C18-unsatd.,
Dimers (CAS 61788-89-4)
Type
PEL 5 mg/m3 Mist.Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4)
PEL 5 mg/m3 Mist.Petrolatum (CAS 8009-03-8)
Type
STEL 10 mg/m3 RespirableFatty Acids, C18-unsatd., Dimers (CAS 61788-89-4)
TWA 5 mg/m3 Respirable
Type
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4)
TWA 10 mg/m3n-Butyl stearate (CAS 123-95-5)
TWA 5 mg/m3 Inhalable fraction.Petrolatum (CAS 8009-03-8)
ValueComponents
ValueComponents
2000 mg/m3 500 ppm
ValueComponents
ValueComponents
Form
Form
Form
Form
Type
TWA 100 mg/m3Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
ValueComponents
Form
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US. NIOSH: Pocket Guide to Chemical Hazards
Type
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
wash facilities and emergency shower must be available when handling this product.
wash work clothing and protective equipment to remove contaminants.
STEL 10 mg/m3 Mist.Distillates (petroleum), Solvent-refined Heavy Paraffinic (CAS 64741-88-4)
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.Petrolatum (CAS 8009-03-8)
TWA 5 mg/m3 Mist.
TWA 165.5 mg/m3d-Limonene (CAS 5989-27-5)
Biological limit values
Appropriate engineering controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as neoprene or nitrile.
Wear appropriate chemical resistant clothing.
If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Wear positive pressure self-contained breathing apparatus (SCBA). Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely
ValueComponents
ValueComponents Type
30 ppm
Form
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Liquid.
Liquid.
Blue green.
Pleasant.
Not available.
Not available.
-72.4 °F (-58 °C) estimated
380 °F (193.3 °C) estimated
192 °F (88.9 °C) Tag Closed Cup
Slow
Not available.
0.6 % estimated
5.5 % estimated
0.2 hPa estimated
> 1 (air = 1)
0.83
Not available.
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
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Partition coefficient
Ingestion
Skin contact
Eye contact
Respiratory sensitization
Carcinogenicity
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
456.8 °F (236 °C) estimated
Not available.
Not available.
90.8 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides. Sulfur oxides.
11. Toxicological information
Information on likely routes of exposure
May be fatal if swallowed and enters airways.
Inhalation
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Acute toxicity
3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Subchronic
Oral
LD50 Rat
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful.
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
Skin irritation. May cause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
May be fatal if swallowed and enters airways. Narcotic effects. Expected to be a low hazard for usual industrial or commercial handling by trained personnel.
Test ResultsProduct Species
2730.2576 mg/kg estimated
113.9506 mg/l estimated
6571.6235 mg/kg estimated
757.9653 g/kg, 14 days estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Germ cell mutagenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Specific target organ toxicity ­single exposure
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
Causes skin irritation.
Direct contact with eyes may cause temporary irritation.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects.
Narcotic effects.
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Specific target organ toxicity -
Aspiration hazard
Acute
Acute
Acute
Partition coefficient n-octanol / water (log Kow)
repeated exposure
Chronic effects
Not classified.
May be fatal if swallowed and enters airways.
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Product Test ResultsSpecies
3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
Components Test ResultsSpecies
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
Aquatic
d-Limonene (CAS 5989-27-5)
Aquatic
Fatty Acids, C18-unsatd., Dimers (CAS 61788-89-4)
Toxic to aquatic life.
LC50Fish 4797.0479 ppm, 96 hours estimatedFish
LC50Fish 2.2 mg/l, 96 hoursBluegill (Lepomis macrochirus)
EC50Crustacea 69.6 mg/l, 48 hoursWater flea (Daphnia pulex)
LC50Fish 0.619 - 0.796 mg/l, 96 hoursFathead minnow (Pimephales promelas)
NOELCrustacea 1000 mg/l, 48 hours loading rate WAFDaphnia
NOELFish 1000 mg/l, 96 hours loading rate WAFFish
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
d-Limonene 4.232 Fatty Acids, C18-unsatd., Dimers 1 - 2.5, logKow
Mobility in soil
Other adverse effects
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container.
Not regulated.
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
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US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
Food and Drug
Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Hazard categories
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
US state regulations
US. New Jersey RTK - Substances: Listed substance
None.
US. Massachusetts RTK - Substance List
None.
US. Pennsylvania RTK - Hazardous Substances
Distillates (petroleum), Hydrotreated Light (CAS 64742-47-8)
US. Rhode Island RTK
None.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
100 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Multi-Purpose Lubricant. This product is compliant for use in all 50 states.
VOC content (CA)
VOC content (OTC)
0 %
0 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
NoAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
NoChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
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Country(s) or region Inventory name On inventory (yes/no)*
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
country(s).
16. Other information, including date of preparation or last revision
Issue date
Prepared by
Version #
Further information
HMIS® ratings
NFPA ratings
Disclaimer
10-31-2013
Allison Cho
01
CRC # 510F
Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: B
Health: 1 Flammability: 2 Instability: 0
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
1310 Version #: 01 Issue date: 10-31-2013
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