CRC 03006, 03009 User Manual

SAFETY DATA SHEET
www.crcindustries.com
workplace. Wear protective gloves/eye protection/face protection. Wash thoroughly after
with plenty of water. If skin irritation or rash occurs: Get medical attention. Wash contaminated
1. Identification
3-36® Multi-Purpose Lubricant & Corrosion InhibitorProduct identifier
Other means of identification
Product code
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name
Address
Telephone
General Information
Technical Assistance Customer Service
24-Hour Emergency
(CHEMTREC)
Website
03006
Multi-purpose lubricant
CRC Industries, Inc.
885 Louis Dr.
Warminster, PA 18974 US
215-674-4300
800-521-3168
800-272-4620
800-424-9300 (US)
703-527-3887 (International)
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Category 4Flammable liquids
Category 1Sensitization, skin
Category 1Aspiration hazard
Category 3Hazardous to the aquatic environment, acute
hazard
Not classified.
Danger
Combustible liquid. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Harmful to aquatic life.
Keep away from flames and hot surfaces-No smoking. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing gas, mist or vapor. Contaminated work clothing must not be allowed out of the
handling. Avoid release to the environment.
If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
clothing before reuse. In case of fire: Do not use water jet as an extinguisher, as this will spread the fire.
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national regulations.
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3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
Distillates (petroleum), hydrotreated light
Paraffin oils (petroleum), catalytic dewaxed heavy
dipropylene glycol monomethyl ether acetate
Paraffin oils (petroleum), catalytic dewaxed light
n-Butyl stearate
Petrolatum
Fatty Acids, C18-unsatd., Dimers
d-Limonene
Terpinolene
Specific chemical identity and/or percentage of composition has been withheld as a trade secret.
64742-47-8
64742-70-7
88917-22-0
64742-71-8
123-95-5
8009-03-8
61788-89-4
5989-27-5
586-62-9
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions.
Rinse with water. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Aspiration may cause pulmonary edema and pneumonitis. May cause an allergic skin reaction. Dermatitis. Rash.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.
60 - 70
10 - 20
5 - 10
5 - 10
3 - 5
1 - 3
< 1
< 0.2
< 0.2
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
General fire hazards
Water fog. Alcohol resistant foam. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved.
Combustible liquid.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
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Methods and materials for
U.S. - OSHA
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ACGIH
US. ACGIH Threshold Limit Values
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Use water spray to reduce vapors or divert vapor cloud drift. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.
Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke. Avoid breathing gas. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label.
Keep away from heat and sources of ignition. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
Type
TWA 5 mg/m3 RespirableFatty Acids, C18-unsatd.,
Dimers (CAS 61788-89-4)
Type
PEL 5 mg/m3 Mist.Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7)
PEL 5 mg/m3 Mist.Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
PEL 5 mg/m3 Mist.Petrolatum (CAS 8009-03-8)
Type
STEL 10 mg/m3 RespirableFatty Acids, C18-unsatd., Dimers (CAS 61788-89-4)
TWA 5 mg/m3 Respirable
Type
TWA 10 mg/m3n-Butyl stearate (CAS 123-95-5)
TWA 5 mg/m3 Inhalable fraction.Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7)
TWA 5 mg/m3 Inhalable fraction.Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
TWA 5 mg/m3 Inhalable fraction.Petrolatum (CAS 8009-03-8)
ValueComponents
ValueComponents
ValueComponents
ValueComponents
Form
Form
Form
Form
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
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US. NIOSH: Pocket Guide to Chemical Hazards
Type
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
TWA 100 mg/m3Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
STEL 10 mg/m3 Mist.Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7)
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
TWA 5 mg/m3 Mist.
STEL 10 mg/m3 Mist.Petrolatum (CAS 8009-03-8)
TWA 5 mg/m3 Mist.
TWA 165.5 mg/m3d-Limonene (CAS 5989-27-5)
Biological limit values
Appropriate engineering controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
ValueComponents
ValueComponents Type
30 ppm
Form
Skin protection
Hand protection
Other
Respiratory protection
Wear protective gloves such as: Nitrile. Neoprene.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels.
Thermal hazards
General hygiene considerations
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Liquid.
Liquid.
Blue green
Pleasant.
Not available.
Not available.
-56.2 °F (-49 °C) estimated
380 °F (193.3 °C) estimated
192 °F (88.9 °C) Tag Closed Cup
Slow.
Not available.
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
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Upper/lower flammability or explosive limits
Inhalation
Skin contact
Eye contact
Acute toxicity
Respiratory sensitization
Flammability limit - lower
0.6 % estimated
(%)
Flammability limit - upper
5.5 % estimated
(%)
Vapor pressure
Vapor density
Relative density
Solubility (water)
Partition coefficient
0.3 hPa estimated
> 1 (air = 1)
0.83
Not available.
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity (kinematic)
Percent volatile
428 °F (220 °C) estimated
Not available.
Not available.
77.5 % estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
Carbon oxides. Sulfur oxides. Hydrocarbons.
11. Toxicological information
Information on likely routes of exposure
Prolonged inhalation may be harmful.
May cause an allergic skin reaction.
Direct contact with eyes may cause temporary irritation.
Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
Acute
Dermal
LD50 Rabbit 2089 mg/kg estimated
Oral
LD50 Rat 4734 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.
Aspiration may cause pulmonary edema and pneumonitis. Headache. Nausea, vomiting. Diarrhea. May cause an allergic skin reaction. Dermatitis. Rash.
May be fatal if swallowed and enters airways. May cause an allergic skin reaction.
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
Not a respiratory sensitizer.
May cause an allergic skin reaction.
Test ResultsProduct Species
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
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Germ cell mutagenicity
Carcinogenicity
Chronic effects
Acute
Acute
Partition coefficient n-octanol / water (log Kow)
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. Paraffin oils (petroleum), catalytic dewaxed light (CAS
3 Not classifiable as to carcinogenicity to humans.
64742-71-8)
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death.
Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
dipropylene glycol monomethyl ether acetate (CAS 88917-22-0)
Aquatic
Harmful to aquatic life.
LC50Crustacea 2701 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 151 mg/l, 96 hoursFathead minnow (Pimephales promelas)
(Oncorhynchus mykiss)
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
Aquatic
LC50Fish 2.2 mg/l, 96 hoursBluegill (Lepomis macrochirus)
d-Limonene (CAS 5989-27-5)
Aquatic
EC50Crustacea 69.6 mg/l, 48 hoursWater flea (Daphnia pulex)
LC50Fish 0.619 - 0.796 mg/l, 96 hoursFathead minnow (Pimephales promelas)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
No data is available on the degradability of this product.
No data available.
dipropylene glycol monomethyl ether acetate 0.61 OECD 107 d-Limonene 4.232 Fatty Acids, C18-unsatd., Dimers 1 - 2.5, logKow Terpinolene 4.23
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
111 mg/l, 96 hoursRainbow trout,donaldson trout
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
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13. Disposal considerations
Disposal of waste from residues / unused products
Hazardous waste code
Contaminated packaging
This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations.
Not regulated.
Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Food and Drug Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Hazard categories
SARA 302 Extremely hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a))
Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Not regulated.
Not regulated.
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No
No
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Petrolatum (CAS 8009-03-8)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
US. New Jersey Worker and Community Right-to-Know Act
Distillates (petroleum), hydrotreated light (CAS 64742-47-8)
US. Rhode Island RTK
None.
US. Pennsylvania Worker and Community Right-to-Know Law
Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Paraffin oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) Paraffin oils (petroleum), catalytic dewaxed light (CAS 64742-71-8)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR
100 %
51.100(s))
Consumer products
Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products
This product is regulated as a Multi-Purpose Lubricant. This product is compliant for use in all 50 states.
VOC content (CA)
VOC content (OTC)
0 %
0 %
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustralia Australian Inventory of Chemical Substances (AICS)
NoCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Prepared by
Version #
Further information
HMIS® ratings
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
10-31-2013
04-14-2016
Allison Cho
03
CRC # 510F
Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: B
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NFPA ratings
NFPA ratings
Health: 1 Flammability: 2 Instability: 0
2
01
Disclaimer
Revision Information
The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries.
Product and Company Identification: Product and Company Identification Hazard(s) identification: Hazard statement Hazard(s) identification: Response Hazard(s) identification: Storage Hazard(s) identification: Supplemental label information Composition / Information on Ingredients: Disclosure Overrides Toxicological Information: Toxicological Data
Material name: 3-36® Multi-Purpose Lubricant & Corrosion Inhibitor
03006 Version #: 03 Revision date: 04-14-2016 Issue date: 10-31-2013
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