Crayola 501402 User Manual

Page 1
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
CRAYOLA LLC 1100 Church Lane Easton, PA 18044 Phone: 1-800-272-9652 Emergency Phone #: Health Emergency - Call local POISON CONTROL E-mail: support@crayola.com
Safety Data Sheet
Section 1 - PRODUCT AND COMPANY IDENTIFICATION
Material Name
CRAYOLA® CHALK
Synonyms
CRAYOLA COLORED CHALK; CRAYOLA DRAWING CHALK; CRAYOLA MOLDED CHALK; CRAYOLA SIDEWALK CHALK/CRAYONS; CRAYOLA GIANT CHALK; CRAYOLA 3-D CHALK; CRAYOLA GLOW CHALK; CRAYOLA GLITTER CHALK; CRAYOLA TIE DYED CHALK; CRAYOLA CHALKBOARD CHALK; CRAYOLA ANTI-DUST LOW DUST CHALK; PRODUCT CODE(S): 03-4984; 03-4985; 03-4986; 03­4987; 03-4988; 03-4989; 03-4490; 03-4990; 03-4991; 04-4992; 03-4994; 03-4995; 03-4996; 03-4997; 03-4998; 03­4999; 03-5037; 03-5039; 03-5053; 03-5044; 03-5061; 03-5063; 03-5064; 03-5066; 03-5067; 03-5068; 03-5071; 03­5072; 03-5073; 03-5078; 03-5079; 03-5080; 03-5081; 03-5090; 03-5091; 03-5092; 03-5093; 03-5094; 03-5101; 03­5102; 03-5103; 03-5104; 03-5105; 03-5106; 03-5107; 03-5108; 03-5111; 03-5200; 03-5201; 03-5202; 03-5203; 03­5204; 03-5205; 03-5206; 03-5207; 03-5208; 03-5209; 03-5210; 03-5211; 03-5212; 03-5213; 03-5214; 03-5215; 03­5216; 03-5217; 03-5218; 03-5220; 03-5224; 03-5225; 03-5226; 03-5228; 03-5229; 03-5230; 03-5231; 03-5232; 03­5233; 03-5234; 03-5235; 03-5301; 03-5302; 03-5303; 03-5304; 03-5350; 03-5398; 03-5399; 03-5401; 03-5800; 03­5801; 03-5802; 03-5803; 03-5804; 03-5805; 03-5806; 03-6100; 03-7603; 04-0145; 04-0294; 04-0295; 04-0296; 04­0413; 04-0530; 04-0555; 04-0456; 04-0586; 04-0608; 04-0640; 04-0945; 04-0944; 04-1907; 04-1950; 04-1951; 04­2542; 04-5033; 04-5350; 04-5355; 04-5358; 04-5718; 04-5719; 04-5727; 04-5873; 04-6010; 04-6874; 04-6887; 50­1402; 51-0012; 51-2004; 51-0200; 51-0312; 51-0320; 51-0320; 51-0400; 51-0403; 51-0404; 51-0816; 51-1015; 51­1020; 51-1200; 51-1202; 51-1205; 51-1206; 51-1216; 51-1503; 51-1515; 51-1524; 51-1650; 51-1660; 51-1661; 51­1662; 51-1663; 51-2010; 51-2012; 51-2016; 51-2024; 51-2024; 51-2036; 51-2048; 51-2049; 51-2050; 51-2064; 51­2065; 51-2515; 51-3505; 51-3515; 51-3523; 51-4005; 51-4008; 51-4102; 51-4103; 51-4104; 51-4105; 51-4107; 51­4108; 51-4109; 51-4110; 51-4111; 51-5298; 51-5299; 51-7000; 51-8015; 51-8020; 51-8052; 51-8064; 55-4403 ; 81­1378
Product Description
Finished product.
Product Use
Arts and Crafts
Restrictions on Use
None known.
Details of the supplier of the safety data sheet
Section 2 - HAZARDS IDENTIFICATION
Classification in accordance with paragraph (d) of 29 CFR 1910.1200.
None needed according to classification criteria.
GHS Label Elements Symbol(s)
None needed according to classification criteria.
Signal Word
None needed according to classification criteria
Hazard Statement(s)
None needed according to classification criteria.
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Page 2
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
CAS
Component Name
Percent
Not available
Product has been certified as nontoxic by the Art & Creative Materials Institute, Inc. and conforms to ASM D 4236 standard practice for labeling art materials for acute and chronic adverse health hazards.
100
Safety Data Sheet
Precautionary Statement(s) Prevention
None needed according to classification criteria.
Response
None needed according to classification criteria.
Storage
None needed according to classification criteria.
Disposal
Dispose in accordance with all applicable federal, state/regional and local laws and regulations.
Other Hazards
None known.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Component Related Regulatory Information
The chemical identity and/or percentage of composition is being withheld as a trade secret.
Section 4 - FIRST AID MEASURES
Inhalation
It is unlikely that emergency treatment will be required. Remove from exposure. Get medical attention, if needed.
Skin
It is unlikely that emergency treatment will be required. If adverse effects occur, wash with soap or mild detergent and large amounts of water. Get medical attention, if needed.
Eyes
It is unlikely that emergency treatment will be required. Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists: Get medical advice/attention.
Ingestion
Call a poison control center or doctor immediately for treatment advice.
Most Important Symptoms/Effects Acute
No information on significant adverse effects.
Delayed
No information on significant adverse effects.
Indication of any immediate medical attention and special treatment needed
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
Extinguishing Media Suitable Extinguishing Media
carbon dioxide, regular dry chemical, regular foam, Water
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Page 3
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
Safety Data Sheet
Unsuitable Extinguishing Media
None known.
Hazardous Combustion Products
Oxides of carbon
Advice for firefighters
Slight fire hazard.
Fire Fighting Measures
Move container from fire area if it can be done without risk. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Special Protective Equipment and Precautions for Firefighters
Wear protective clothing and equipment suitable for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
None.
Methods and Materials for Containment and Cleaning Up
Stop leak if possible without personal risk. Collect spilled material in appropriate container for disposal.
Section 7 - HANDLING AND STORAGE
Precautions for Safe Handling
Wash thoroughly after handling. Use methods to minimize dust.
Conditions for Safe Storage, Including any Incompatibilities
None needed according to classification criteria. Store and handle in accordance with all current regulations and standards. See original container for storage recommendations. Keep separated from incompatible substances.
Incompatible Materials
oxidizing materials
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits.
ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI)
There are no biological limit values for any of this product's components.
Engineering Controls
Based on available information, additional ventilation is not required.
Individual Protection Measures, such as Personal Protective Equipment Eye/face protection
Eye protection not required under normal conditions.
Skin Protection
Protective clothing is not required under normal conditions.
Respiratory Protection
No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Glove Recommendations
Protective gloves are not required under normal conditions.
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Page 4
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
Appearance
various colors
Physical State
solid
Odor
odorless
Color
various colors
Odor Threshold
Not available
pH
Not available
Melting Point
Not available
Boiling Point
Not available
Boiling Point Range
Not available
Freezing point
Not available
Evaporation Rate
Not available
Flammability (solid, gas)
Not available
Autoignition Temperature
Not available
Flash Point
Not available
Lower Explosive Limit
Not available
Decomposition temperature
Not available
Upper Explosive Limit
Not available
Vapor Pressure
Not available
Vapor Density (air=1)
Not available
Specific Gravity (water=1)
Not available
Water Solubility
(Insoluble )
Partition coefficient: n­octanol/water
Not available
Viscosity
Not available
Kinematic viscosity
Not available
Solubility (Other)
Not available
Density
Not available
Physical Form
solid
Molecular Weight
Not available
Safety Data Sheet
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Section 10 - STABILITY AND REACTIVITY
Reactivity
No hazard expected.
Chemical Stability
Stable at normal temperatures and pressure.
Possibility of Hazardous Reactions
Will not polymerize.
Conditions to Avoid
None reported.
Incompatible Materials
oxidizing materials
Hazardous decomposition products
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Page 5
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
Safety Data Sheet
Oxides of carbon.
Thermal decomposition products
Oxides of carbon
Section 11 - TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure Inhalation
No information on significant adverse effects.
Skin Contact
No information on significant adverse effects.
Eye Contact
No information on significant adverse effects.
Ingestion
No information on significant adverse effects.
Acute and Chronic Toxicity Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and no selected endpoints have been identified.
Product Toxicity Data Acute Toxicity Estimate
No data available.
Immediate Effects
No information on significant adverse effects.
Delayed Effects
No information on significant adverse effects.
Irritation/Corrosivity Data
None
Respiratory Sensitization
No information available for the product.
Dermal Sensitization
No information available for the product.
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.
Germ Cell Mutagenicity
No information available for the product.
Tumorigenic Data
No data available
Reproductive Toxicity
No information available for the product.
Specific Target Organ Toxicity - Single Exposure
No target organs identified.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
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Page 6
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
Safety Data Sheet
Aspiration hazard
no data available.
Medical Conditions Aggravated by Exposure
No data available.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity
No information available for the product.
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components.
Persistence and Degradability
No information available for the product.
Bioaccumulative Potential
No information available for the product.
Mobility
No information available for the product.
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
Section 14 - TRANSPORT INFORMATION
US DOT Information: Further information: Not regulated as a hazardous material.
IATA Information: Further information: Not regulated as dangerous goods.
ICAO Information: Further information: Not regulated as dangerous goods.
IMDG Information:
Further information: Not regulated as dangerous goods.
TDG Information: Further information: Not regulated as dangerous goods.
International Bulk Chemical Code
This material does not contain any chemicals required by the IBC Code to be identified as dangerous chemicals in bulk.
Section 15 - REGULATORY INFORMATION
U.S. Federal Regulations
None of this product's components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan.
SARA Section 311/312 (40 CFR 370 Subparts B and C) reporting categories
No hazard categories applicable.
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Page 7
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
US
CA
AU
CN
EU
JP - ENCS
JP - ISHL
KR KECI - Annex 1
KR KECI - Annex 2
No
No
No
No
No
No
No
No
No KR - REACH CCA
MX
NZ
PH
TH-TECI
TW
VN (Draft)
No
No
No
No
No
No
No
Safety Data Sheet
U.S. State Regulations
None of this product's components are listed on the state lists from CA, MA, MN, NJ or PA.
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65)
Not listed under California Proposition 65.
Component Analysis - Inventory
Product has been certified as nontoxic by the Art & Creative Materials Institute, Inc. and conforms to ASM D 4236 standard practice for labeling art materials for acute and chronic adverse health hazards. (Not available)
U.S. Inventory (TSCA)
All of the components of this product are listed on the TSCA Inventory. All components of this product are listed on the DSL.
Section 16 - OTHER INFORMATION
NFPA Ratings
Health: 1 Fire: 1 Instability: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Summary of Changes
04/29/2019 - Update to Section(s) 1.
Revision date
09/13/2018
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CA/MA/MN/NJ/PA ­California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CFR - Code of Federal Regulations (US); CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD
- Dangerous Substance Directive; DSL - Domestic Substances List; EC – European Commission; EEC ­European Economic Community; EIN - European Inventory of (Existing Commercial Chemical Substances); EINECS - European Inventory of Existing Commercial Chemical Substances; ENCS - Japan Existing and New Chemical Substance Inventory; EPA - Environmental Protection Agency; EU - European Union; F ­Fahrenheit; F - Background (for Venezuela Biological Exposure Indices); IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG ­International Maritime Dangerous Goods; ISHL - Japan Industrial Safety and Health Law; IUCLID ­International Uniform Chemical Information Database; JP - Japan; Kow - Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal Dose/ Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK ­Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; MX – Mexico; Ne­Non-specific; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety
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Page 8
Material Name: CRAYOLA® CHALK
SDS ID: CRAY-028
Issue date: 2019-10-08 Revision 9.0
Print date: 2019-10-08
Safety Data Sheet
and Health; NJTSR - New Jersey Trade Secret Registry; Nq - Non-quantitative; NSL – Non-Domestic Substance List (Canada); NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; Sc ­Semi-quantitative; STEL - Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG ­Transportation of Dangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act; TW – Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations /North American; US - United States; VLE - Exposure Limit Value (Mexico); VN (Draft) - Vietnam (Draft); WHMIS - Workplace Hazardous Materials Information System (Canada).
Other Information Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights.
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