AFTER 5 PM AND ON WEEKENDS: (203) 272-3221
ORIGINATOR: H.F.
TRADE NAMES & SYNONYMS:
CHEMICAL FAMILY: ASPHALT
EFFECTIVE DATE: 06/06/2014
DATE SUPERSEDED: 06/16/2010
Section II – Hazards Information on
Emergency Overivew: Signal Word: Warning
HCS Pictogram:
ROUTES OF ENTRY: Inhalation, skin, ingestion (rare)
EFFECTS OF OVEREXPOSURE / ACUTE OVEREXPOSURE:
Inhalation: Vapors may be irritating to eyes, nose and throat. May cause headaches, dizziness and nausea.
Skin: Hot product may cause minor to severe burns if contact is made with the skin.
Ingestion: May result in vomiting. Have the patient drink large amounts of water; contact a physician.
UNUSUAL CHRONIC TOXICITY:
Respiratory problems may be aggravated by petroleum fumes.
CARCINOGENIC: N/A
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Section III – Composition on
Asphalt Cement,
CAS #8052-42-4
Listed in SARA Title III, Section 313: No
ACGIH TLV: 5 mg/m3 (volatiles)
Ingredients total weight % are below 100% only if all others unlisted are not considered hazardous by any federal (OSHA, WHMIS,
SARA), any state or province, or local Right-To-Know regulations.
Section IV – First-Aid Measures on
EMERGENCY AND FIRST-AID PROCEDURES:
Eyes: Hot materials may cause burns. Immediately flush with clean water for 15 minutes while holding eyelids open, consult a
physician.
Inhalation: If overcome by mist or vapor, remove from exposure immediately; call a physician. If breathing is stopped or irregular,
start resuscitation, administer oxygen.
Skin: Remove any contaminated clothing and wash skin with soap and warm water. Vegetable or mineral oil can remove dry
material. Get medical help for severe burns.
Ingestion: INDUCE VOMITING! Prevent aspiration of liquid into lungs Get immediate medical attention.
Section V – Fire-Fighting Measures on
FLAMMABILITY CLASSIFICATION: Not Regulated
FLASH POINT: Greater than 425° F.
AUTO IGNITION TEMP.: N/A
LOWER EXPLOSIVE LIMIT (LEL): N/A
UPPER EXPLOSIVE LIMIT (UEL): N/A
EXTINGUISHING MEDIA:
Class B fire extinguishing media such as, but not limited to: Halon, CO2, or dry chemical
SPECIAL FIRE FIGHTING PROCEDURES:
Fire fighters should wear self-contained breathing equipment in addition to full body protective gear (face shield, trench coats,
gloves, and rubber boots). Concentrated vapors from combustion should not be breathed. Do not allow run off from fire fighting
procedures to enter public waterways. Avoid using solid water streams. Water spray and foam must be applied carefully to avoid
frothing. Use water to cool surfaces
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Material will not burn unless preheated. Hot materials may ignite flammable materials on contact. Use adequate ventilation with
clean-up procedures.
UN/NA/PIN#: N/A
IMPACT SENSITIVE: No
STATIC SENSITIVE: No
EXPLOSIVE POWER: N/A
BURNING RATE: N/A
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Section VI – Accidental Release Measures on
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Remove all ignition sources. Wear suitable protective clothing, gloves & eye/face protection. Allow material to cool to a solid and put in
an approved container. Scoop up for reuse or disposal. Dispose of in accordance with federal, state and local regulations.
Section VII – Handling and Storage on
Handling: For hot material, avoid eye contact, repeated or prolonged skin contact or inhalation of vapors. Wash thoroughly after
handling. Use in well ventilated areas.
Storage: Keep container closed when not in use. Do not store in open, unlabeled or mislabeled containers. Unheated material presents
no known hazards. Store in areas where sources of ignition have been eliminated from vicinity of stored products.
Section VIII – Exposure Controls / Personal Protection on
Personal protective equipment pictograms:
VENTILATION:
Local Exhaust: Required
Mechanical (general): Required
Special: N/A
Other: N/A
RESPIRATORY PROTECTION:
Use only with adequate ventilation. If ventilation is inadequate, wear approved respiratory equipment.
PROTECTIVE GLOVES: Wear heat gloves to protect hands and arms from hot material.
EYE PROTECTION: Wear safety glasses, goggles, or face shield.
OTHER PROTECTIVE EQUIPMENT: Wear suitable protective clothing
Section IX – Physical and Chemical Properties on
APPEARANCE & ODOR: Black semi-solid PHYSICAL STATE: semi-solid
BOILING POINT: 750° F FREEZING POINT: N/A
VAPOR PRESSURE: N/A %VOLATILE (by Wt.): N/A
SPECIFIC GRAVITY: 1.05 - 1.25 THRESHOLD ODOR: N/A
SOLUBILITY IN WATER: Negligible VAPOR DENSITY: N/A
EVAPORATION RATE: N/A
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Component Name
Concentration
CAS
Data
Asphalt Cement
30 – 45 %
8052-42-4
Acute oral toxicity: LD50 rat
Dose: 5,001 mg/kg
Acute dermal toxicity: LD50 rat
Dose: 2,001 mg/kg
Section X – Stability and Reactivity on
STABILITY: Stable
CONDITIONS TO AVOID: DO NOT expose fumes from heated product to sources of ignition
INCOMPATIBILITY (materials to avoid): Strong oxidizing agents.
HAZARDOUS POLYMERIZATION: Will Not Occur
HAZARDOUS DECOMPOSITION PRODUCTS: Combustion may produce oxides of carbon (CO, CO2, etc)
Section XI – Toxicological Information on
Component: Asphalt:
NTP: This component, Asphalt (CAS-No.: 8052-42-4), may contain trace amounts of benzene, a chemical known to cause
cancer.
IARC: Asphalt (Bitumen) (CAS-No.: 8052-42-4) Group 2B possibly carcinogenic to humans.
OSHA: This component, Asphalt (CAS-No.: 8052-42-4), may contain trace amounts of benzene, a chemical known to cause
cancer.
CA Prop 65: WARNING! This product contains a chemical known to the State of California to cause cancer: Asphalt (CAS-No.:
8052-42-4)
Please refer to the individual SDS of the components listed in Section III for additional information.
Section XII – Ecological Information on
Ecological Fate: No data available
Persistence/Degradability No data available
Bioaccumulation Potential: No data available
Mobility in Soil: No data available
Analysis for ecological effects has not been conducted.
Section XIII – Disposal Considerations on
WASTE DISPOSAL METHOD: Dispose in accordance with federal, state and local regulations.
SARA TITLE III:
#302: No #304 CERCLA: No #313: Yes RCRA: No
REPORTABLE QUANTITIES (lbs): N/A TPO (lb): N/A
REGULATIONS: WHMIS, SARA, state and provinceHAZARDOUS WASTE: N/A
Page 4 of 5 CRACK-STIX
Page 5
Component Name
CAS
State Right to Know
MA
NJ
PA
Asphalt Cement
8052-42-4
yes
yes
yes
Section XIV – Transportation Information on
UN Number: N/A
UN Packing Group: N/A
UN Class: N/A
ICAO/IATA Class: N/A
IMDG Class: N/A
Notes: This product is NOT REGULATED for domestic and international transportation when shipped in individual containers of less
than 595 gallons.
U.S. DOT RQ.: None
Section XV – Regulatory Information on
California Prop 65:
WARNING! This product contains a chemical known to the State of California to cause cancer.
Section XVI – Other Information on
Other Precautions:
Keep out of reach of children.
Always read label plus precautions and follow directions carefully.
Avoid contact with eyes, skin and clothing.
Wear suitable protective clothing, gloves and eye/face protection.
Wash thoroughly after using.
Do not breathe vapor or spray mist.
Use only in well ventilated areas.
Keep containers closed when not in use.
Do not take internally
Revision Date: 06/06/2014
Supersedes: 06/16/2010
Prepared by: H. Farr
Disclaimer/Statement of Liability:
THE INFORMATION AND RECOMMENDATIONS PROVIDED HEREIN ARE BELIEVED TO BE ACCURATE AS OF THE
DATE HEREOF. HOWEVER, SUCH INFORMATION AND RECOMMENDATIONS ARE PROVIDED WITHOUT
WARRANTY OF ANY KIND AND THIS CORPORATION DISCLAIMS ANY AND ALL LIABILITY OR LEGAL
RESPONSIBILITY FOR USE OR RELIANCE UPON SAME.
Page 5 of 5 CRACK-STIX
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