Page 1
Conforms to HazCom 2012/United States
SAFETY DATA SHEET
CS-102
© 2014 Concrete Sealants, Inc. 1/10
Section 1. Identification
GHS product identifier
: CS-102
Other means of
identification
: Not Available
Relevant identified uses of the substance or mixture and uses advised against
Not available
Supplier’s details
: Concrete Sealants, Inc.
9325 St. Rte. 201
Tipp City, Ohio 45371
Tel.: 937-845-8776
Toll-free: 800-332-7325
Fax: 937-845-3587
Email: [email protected]
Website URL: www.conseal.com
Emergency telephone
number (with hours of
operation)
: 937-845-8776 or 800-332-7325
(6am to 5pm EST)
Section 2. Hazards Identification
Since the product is in paste form, the risk of exposure to a carcinogen dust is minimum; this is why the
related hazard statements are not shown in this SDS.
OSHA/HCS status
: While this material is not considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200), this SDS contains valuable
information critical to the safe handling and proper use of the product. This SDS
should be retained and available for employees and other users of this product.
Classification of the
substance or mixture
: Not Classified
GHS label elements
Signal word
: No signal word
Hazard statements
: No known significant effects or critical hazards.
Precautionary statements
General
: Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention
: Not applicable
Response
: Not applicable
Storage
: Not applicable
Disposal
: Not applicable
Hazards not otherwise
classified
: None known
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Other means of
identification
: Not available
CAS number/other identifiers
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CS-102
Section 3. Composition/information on ingredients
CAS number
: Not applicable
Product code
: Not available
Ingredient name
%
CAS number
Crystalline silica, quartz
Kaolin
Palygorskite
Titanium dioxide
Hydrogen sulphide
10 – 30
1 – 5
1 – 5
1 – 5
0 – 0.1
14808-60-7
1332-58-7
12174-11-7
13463-67-7
7783-06-4
Section 4. First aid measures
Description of necessary first aid measures
Eye contact
: Not a likely route of exposure.
Inhalation
: Not a likely route of exposure.
Skin contact
: No first aid should be needed.
Ingestion
: Wash mouth out with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
Protection of first-aiders
Section 5. Firefighting measures
Extinguishing media
Suitable extinguishing
media
: Carbon dioxide, dry chemical, foam and water fog spray.
Unsuitable extinguishing
media
: None known
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
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CS-102
Section 5. Firefighting measures
Specific hazards arising
from the chemical
: No specific fire or explosion hazard.
Hazardous thermal
decomposition products
: Decomposition materials may include the following materials:
carbon dioxide
carbon monoxide
Special protective actions
for firefighters
: No special measures are required.
Special protective
equipment for firefighters
: Firefighters should wear appropriate protective equipment and self- contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training. Put
on appropriate personal protective equipment.
For emergency
responders
: If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in “For non-emergency personnel.”
Environmental
precautions
: None require if used according to recommended conditions.
Methods and materials for contaminant and cleaning up
Spill
: Not applicable
Section 7. Handling and storage
Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8).
Advice on general
occupational hygiene
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and faces before
eating, drinking and smoking. See also Section 8 for additional information on
hygiene measures.
Conditions for safe
storage, including any
incompatibilities
: Store in accordance with local regulations. Store away from direct sunlight in a, cool
and well-ventilated area, away from incompatible materials (see Section 10) and
food and drink. Do not store in unlabeled containers.
Section 8. Exposure Controls / Personal Protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
Crystalline silica, quartz
OSHA PEL Z3 (United States, 2/2013).
TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form: Respirable
TWA: 250 MPPCF / (%SiO2+5) 8 hours. Form: Respirable
ACGIH TLV (United States, 6/2013).
TWA: 0.025 mg/m3 8 hours. Form: Respirable fraction
NIOSH REL (United States, 4/2013).
TWA: 0.05 mg/m3 10 hours. Form: Respirable dust
ACGIH TLV (United States, 3/2012).
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Section 8. Exposure Controls / Personal Protection
Kaolin
TWA: 2 mg/m3 8 hours. Form: Respirable fraction
NIOSH REL (United States, 6/2009).
TWA: 5 mg/m3 10 hours. Form: Respirable fraction
TWA: 10 mg/m3 10 hours. Forms: Total
OSHA PEL (United States, 6/2010).
TWA: 5 mg/m3 8 hours. Forms: Respirable fraction
TWA: 15 mg/m3 8 hours. Form: Total dust
Titanium dioxide
OSHA PEL (United States, 6/2010).
TWA: 15 mg/m3 8 hour. Form: Total dust
OSHA PEL 1989 (United States, 3/1989).
TWA: 10 mg/m3 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2012).
TWA: 10 mg/m3 8 hours.
Hydrogen sulphide
ACGIH TLV (United States, 6/2013).
STEL: 5 ppm 15 minutes.
TWA: 1 ppm 8 hours.
NIOSH REL (United States, 4/2013).
CEIL: 15 mg/m3 10 minutes.
CEIL: 10 ppm 10 minutes.
OSHA PEL Z2 (United States, 2/2013).
AMP: 50 ppm 10 minutes.
CEIL: 20 ppm
Appropriate engineering
controls
: Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.
Individual protection measures
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Eye/face protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gasses or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Skin protection
Hand protection
: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
Body protection
: Not required under normal use.
Other skin protection
: Not required under normal use.
Respiratory protection
: Not required under normal use.
Section 9. Physical and Chemical Properties
Appearance
Physical state
: Solid
Color
: Black
Odor
: Petroleum. [Slight]
Odor threshold
: Not available
pH
: Not available
Melting point
: Not available
Boiling point
: Not available
Flash point
: Open cup: 232.22oC (450oF) [Cleveland.]
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CS-102
Section 9. Physical and Chemical Properties
Burning time
: Not available
Burning rate
: Not available
Evaporation rate
: Not available
Flammability (solid, gas)
: Not available
Lower and upper
explosive (flammable)
limits
: Not available
Vapor pressure
: Not available
Vapor density
: Not available
Relative density
: 1.25
Solubility
: Insoluble in the following material: cold water and hot water.
Solubility in water
: 0 g/l
Partition coefficient noctanol/water
: Not available
Auto-ignition temperature
: Not available
Decomposition
temperature
: Not available
SADT
: Not available
Viscosity
: Not available
Section 10. Stability and Reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Section 11. Toxicological Information
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Hydrogen sulphide
LC50 Inhalation Gas.
LC50 Inhalation Vapor
Rat
Rat
444 ppm
700 mg/m3
4 hours
4 hours
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
Titanium dioxide
Skin – Mild irritant
Human
-
72 hours 300 µg
Intermittent
-
Sensitization
Skin
: There is no data available
Respiratory
: There is no data available
Mutagenicity
There is no data available
Carcinogenicity
Classification
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CS-102
Section 11. Toxicological Information
Product/ingredient name
OSHA
IARC
NTP
Crystalline silica, quartz
Palygorskite
Titanium dioxide
-
-
-
1
2B
2B
Known to be a human carcinogen.
-
-
There is no data available
Reproductive toxicity
There is no data available
Teratogenicity
There is no data available
Specific target organ toxicity (single exposure)
There is no data available
Specific target organ toxicity (repeated exposure)
Name
Category
Route of
exposure
Target organs
Crystalline silica, quartz
Kaolin
Category 1
Category 2
Not determined
Inhalation
Kidneys, respiratory
tract and testes
Not determined
Aspiration hazard
There is no data available
Information on the likely
routes of exposure
: Route of entry anticipated: Oral, Dermal.
Potential acute health effects
Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
: No known significant effects or critical hazards.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: No known significant effects or critical hazards.
Ingestion
: No known significant effects or critical hazards.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
effects
: No known significant effects or critical hazards.
Potential delayed effects
: No known significant effects or critical hazards.
Long term exposure
Potential immediate
effects
: No known significant effects or critical hazards.
Potential delayed effects
: No known significant effects or critical hazards.
Potential chronic health effects
General
: No known significant effects or critical hazards.
Carcinogenicity
: No known significant effects or critical hazards.
Mutagenicity
: No known significant effects or critical hazards.
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Section 11. Toxicological Information
Teratogenicity
: No known significant effects or critical hazards.
Developmental effects
: No known significant effects or critical hazards.
Fertility effects
: No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route
ATE value
Section 12. Ecological Information
Toxicity
Product/ingredient name
Result
Species
Exposure
Titanium dioxide
Acute EC50 5.83 mg/L Fresh water
Acute LC50 3 mg/L Fresh water
Acute LC50 5.5 ppm Fresh water
Acute LC50 1000 mg/L Fresh water
Chronic NOEC 0.984 mg/L Fresh water
Algae- Pseudokirchneriella
subcapitata- Exponential growth
phase
Crustaceans- Ceriodaphnia d ubia
Neonate
Daphnia-Daphnia magna-Juvenile
(Fledgling, Hatchling, Weanling)
Fish- Pimephales promelas
Algae- Pseudokirchneriella
subcapitata
Exponential growth phase
72 hours
48 hours
48 hours
96 hours
72 hours
Hydrogen sulphide
Acute EC50 62 µg/l Fresh water
Acute LC50 2 µg/l Fresh water
Crustaceans- Gammarus
pseudolimnaeus
Fish- Coregonus clupeaformisYolk-sac fry
2 days
96 hours
Persistence and degradability
There is no data available
Bioaccumulative potential
Product/ingredient name
LogPOW
BCF
Potential
Titanium dioxide
-
352
low
Mobility in soil
Soil/water partition
coefficient (KOC)
: Not available
Other adverse effects
: No known significant effects or critical hazards.
Section 13. Disposal Considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Waste should not be disposed of untreated to the
sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible.
Section 14. Transport Information
DOT Classification
IMDG
IATA
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CS-102
Section 14. Transport Information
UN number
Not regulated
Not regulated
Not regulated
UN proper
shipping name
- - -
Transport
hazard
class(es)
- - -
Packing group
- - -
Environmental
hazards
No.
No.
No.
Additional
information
- - -
Special precautions for
user
: Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do
in the event of an accident or spillage.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
: Not available
Section 15. Regulatory Information
U.S. Federal regulations
: TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempt.
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Not Listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
SARA 302/304
Composition/information on ingredients
Name
%
EHS
SARA 302 TPQ
SARA 304 RQ
(lbs)
(gallons)
(lbs)
(gallons)
Hydrogen sulphide
0 – 0.1
Yes.
500 - 100 -
No products were found
SARA 304 RQ
: 1394700.1 lbs /633193.9 kg
SARA 311/312
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CS-102
Classification
: Not applicable
Composition/information on ingredients
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Crystalline silica, quartz
Kaolin
Palygorskite
Titanium dioxide
Hydrogen sulphide
10-30
1-5
1-5
1-5
0-0.1
No.
No.
No.
No.
Yes.
No.
No.
No.
No.
Yes.
No.
No.
No.
No.
No.
No.
No.
No.
No.
Yes.
Yes.
Yes.
Yes.
Yes.
No.
SARA 313
Product name
CAS number
%
Form R – Reporting
requirements
Supplier notification
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts
: The following components are listed: Crystalline silica, quartz; Titanium dioxide;
Cellulose; Petroleum asphalt.
New York
: None of the components are listed.
New Jersey
: The following components are listed: Crystalline silica, quartz; Titanium dioxide;
Cellulose; Petroleum asphalt; Kaolin.
Pennsylvania
: The following components are listed: Crystalline silica, quartz; Titanium dioxide;
Cellulose; Petroleum asphalt; Kaolin.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
Crystalline silica, quartz
Palygorskite
Titanium dioxide
Yes.
Yes.
Yes.
No.
No.
No.
No.
No.
No.
No.
No.
No.
International regulations
International lists
: Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory: Not determined.
Korea inventory: Not determined.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan inventory (CSNN): Not determined.
Chemical Weapons
Convention List Schedule
I Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
: Not listed
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CS-102
Chemical Weapons
Convention List Schedule
III Chemicals
: Not listed
Section 16. Other Information
History
Date of issue mm/dd/yyyy
: 08/04/2016
Version
: 2
Revised sections
: Section 13
Prepared by
: Concrete Sealant Inc.
Key to abbreviations
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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