Safety Data Sheet
CF - 40
SDS Revision Date:
04/01/2015
1. Identification
1.1. Product identifier
Product Identity
CF - 40
Alternate Names
90-503,90-504, 90-505, Blended Formula
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use
See Technical Data Sheet.
Application Method
See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Company Name
ComStar International Inc.
20-45 128th Street,
College Point, NY 11356
Telephone No.
718-445-7900
800-328-0142
Fax: 718-353-5998
2. Hazard(s) identification
2.1. Classification of the substance or mixture
Skin Irrit. 2;H315
Causes skin irritation.
Eye Irrit. 2;H319
Causes serious eye irritation.
Muta. 2;H341
Suspected of causing genetic defects
Carc. 1 B;H350
May cause cancer
STOT SE 3;H336
May cause drowsiness or dizziness
Aquatic Chronic 2;H411
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Danger
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Safety Data Sheet
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SDS Revision Date:
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H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H411 Toxic to aquatic life with long lasting effects.
[Prevention]:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
[Response]:
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present
and easy to do - continue rinsing.
P308+313 IF exposed or concerned: Get medical advice / attention.
P321 Specific treatment (see information on this label).
P331 Do NOT induce vomiting.
P332+313 If skin irritation occurs: Get medical advice / attention.
P337+313 If eye irritation persists: Get medical advice / attention.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 Protect from sunlight.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
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Safety Data Sheet
CF - 40
SDS Revision Date:
04/01/2015
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and
Federal Hazardous Substances regulations.
Ingredient/Chemical Designations
Weight %
GHS Classification
Notes
TRICHLOROETHYLENE
CAS#: 79-01-6
>80
Carc. 1B;H350
Muta. 2;H341
Eye Irrit. 2;H319
Skin Irrit. 2;H315
STOT SE 3;H336
Aquatic Chronic 3;H412
[1][2]
1, 2 – BUTYLENE OXIDE
STABILIZERS
CAS#: 106-88-7
<20
Carc. 2
Muta. Not classified
Eye Irrit. 1
Skin Irrit. 2
Aquatic Chronic Not classified
[1][2]
In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures
General
In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give
artificial respiration. If unconscious place in the recovery position and obtain immediate
medical attention. Give nothing by mouth.
Eyes
Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and
seek medical attention.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a
recognized skin cleanser.
Ingestion
If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Overview
No specific symptom data available.
Reproductive or genetic defect hazard. See section 2 for further details.
Inhalation
May cause drowsiness or dizziness.
Eyes
Causes serious eye irritation.
Skin
Causes skin irritation.
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Safety Data Sheet
CF - 40
SDS Revision Date:
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5.1. Extinguishing media
Use dry chemical, COL or foam to extinguish fire.
Cool fire exposed container with water.
Water may be ineffective as an extinguishing agent.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: No hazardous decomposition data available.
Avoid breathing dust / fume / gas / mist / vapors / spray.
Do not get in eyes, on skin, or on clothing.
5.3. Advice for fire-fighters
Wear self-contained breathing apparatus and protective clothing.
6.1. Personal precautions, protective equipment and emergency procedures
Put on appropriate personal protective equipment (see section 8).
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove
soiled clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.
For Large Spills: Flush spill area with water spray. Prevent run-off from entering drains, sewers, or streams, collect
run-off.
7.1. Precautions for safe handling
Avoid contact with eyes and skin. Wash thoroughly after handling. Do not breathe vapors or fumes.
Preventation of Fire and Explosion: Keep from contact with oxidizing materials, alkalis and acids. Store away from
heat, sunlight and moisture.
See section 2 for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Handle containers carefully to prevent damage and spillage.
5. Fire-fighting measures
6. Accidental release measures
7. Handling and storage
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Safety Data Sheet
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SDS Revision Date:
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Incompatible materials: Oxidizing agents, alkali metals
See section 2 for further details. - [Storage]:
7.3. Specific end use(s)
No data available.
8. Exposure controls and personal protection
8.1. Control parameters
Exposure
CAS No.
Ingredient
Source
Value
79-01-6
TRICHLOROETHYLENE
OSHA
50 ppm
ACGIH
50 ppm
NIOSH
25 ppm
Supplier
No Established Limit
106-88-7
1, 2 – BUTYLENE OXIDE STABILIZERS
OSHA
No Established Limit
ACGIH
No Established Limit
NIOSH
No Established Limit
Supplier
TWA 40 ppm
Carcinogen Data
CAS No.
Ingredient
Source
Value
79-01-6
Trichloroethylene
OSHA
Select Carcinogen: No
NTP
Known: No; Suspected: Yes
IARC
Group 1: Yes; Group 2a: No; Group 2b: No; Group 3: No; Group
4: No;
106-88-7
1, 2 – BUTYLENE OXIDE STABILIZERS
OSHA
Select Carcinogen: No
NTP
Known: No; Suspected: Yes
IARC
Group 1: Yes; Group 2a: No; Group 2b: No; Group 3: No; Group
4: No;
8.2. Exposure controls
Respiratory
If engineering controls do not maintain airborne concentrations to an acceptable level,
a
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Safety Data Sheet
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SDS Revision Date:
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NIOSH approved respirator must be worn.
Respirator Type: Organic vapor. If respirators are used, a program should be
instituted to assure Compliance with OSHA Standard 29 CFR 1910.134.
Eyes
Safety glasses with side shields, goggles or face shield are recommended.
Skin
Wear overalls to keep skin contact to a minimum.
Engineering Controls
Good general ventilation (typically 10 air changes per hour) should be used.
Ventilation rates should be matched to conditions. Supplementary local exhaust
ventilation, closed systems, or respiratory protection may be needed in special
circumstances such as poorly ventilated spaces, evaporation from large
surfaces, spraying, heating, etc. Recommended Decontamination Facilities:
Eye bath, washing facilities.
Other Work Practices
Use good personal hygiene practices. Wash hands before eating, drinking,
smoking or using toilet. Promptly remove soiled clothing and wash thoroughly
before reuse.
See section 2 for further details. - [Prevention]:
9. Physical and chemical properties
Appearance
Clear Liquid
Odor
Mild perfumed
Odor threshold
Not Measured
pH
Not Measured
Melting point / freezing point
Not Measured
Initial boiling point and boiling range
160 F (71 C)
Flash Point
None, TOC
Evaporation rate (Ether = 1)
Not Measured
Flammability (solid, gas)
Not Applicable
Upper/lower flammability or explosive limits
Lower Explosive Limit: 135C(275F): NA
Upper Explosive Limit: 199C(390F): NA
Vapor pressure (Pa)
95 psig (at 70 F)
Vapor Density
> 1 (Air = 1)
Specific Gravity
Not Measured
Solubility in Water
Negligible
Partition coefficient n-octanol/water (Log Kow)
Not Measured
Auto-ignition temperature
(ASTM D 2155): NA
Decomposition temperature
Not Measured
Viscosity (cSt)
at 25C/77F: NA
Volatiles (% by weight)
NA
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Safety Data Sheet
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SDS Revision Date:
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Octanol/Water Partition Coefficient
NA
9.2. Other information
No other relevant information.
10. Stability and reactivity
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
Avoid heat, sparks, flames and other sources of ignition
10.4. Conditions to avoid
Avoid heat, sparks, flames and other sources of ignition
10.5. Incompatible materials
Oxidizing agents, alkali metals
10.6. Hazardous decomposition products
No hazardous decomposition data available.
11. Toxicological information
Acute toxicity
Ingredient
Oral LD50,
mg/kg
Skin LD50,
mg/kg
Inhalation
Vapor LC50,
mg/L/4hr
Inhalation
Dust/Mist LC50,
mg/L/4hr
Inhalation
Gas LC50,
ppm
Trichloroethylene (79-01-6)
4,920.00, Rat
Category: 5
20,000.00,
Rabbit -
Category: NA
Rat
12,500 ppm
No data
available
No data
available
1, 2 – BUTYLENE OXIDE STABILIZERS (106-88-7)
No data
available
1,500 - < 2,95,
Rabbit
No data
available
No data
available
No data
available
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate
was used in the calculation of the product's ATE (Acute Toxicity Estimate).
Classification
Category
Hazard Description
Acute toxicity (oral)
---
Not Applicable
Acute toxicity (dermal)
---
Not Applicable
Acute toxicity (inhalation)
---
Not Applicable
Skin corrosion/irritation
2
Causes skin irritation.
Serious eye damage/irritation
2
Causes serious eye irritation.
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Safety Data Sheet
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SDS Revision Date:
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Respiratory sensitization
---
Not Applicable
Skin sensitization
---
Not Applicable
Germ cell mutagenicity
2
Suspected of causing genetic defects.
Carcinogenicity
1B
May cause cancer.
Reproductive toxicity
---
Not Applicable
STOT-single exposure
3
May cause drowsiness or dizziness.
STOT-repeated exposure
---
Not Applicable
Aspiration hazard
---
Not Applicable
12. Ecological information
12.1. Toxicity
This product is not expected to be toxic to aquatic organishes
Harmful to aquatic life.
Aquatic Ecotoxicity
Ingredient
96 hr LC50 fish,
mg/l
48 hr EC50 crustacea,
mg/l
ErC50 algae,
mg/l
Trichloroethylene (79-01-6)
21.90, Pimephales
promelas
18.00, Daphnia magna
36.50 (72 hr),
Chlamydomonas reinhardtii
1, 2 – BUTYLENE OXIDE STABILIZERS (10688-7)
100 mg/l
70 mg/l
> 500 mg/l
12.2. Persistence and degradability
There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.
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Safety Data Sheet
CF - 40
SDS Revision Date:
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13. Disposal considerations
13.1. Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.
14. Transport information
DOT (Domestic Surface
Transportation)
IMO / IMDG (Ocean
Transportation)
ICAO/IATA
14.1. UN number
UN1897
UN1897
UN1897
14.2. UN proper shipping
name
UN1897
Tetrachloroethylene
UN1897
Tetrachloroethylene
UN1897
Tetrachloroethylene
14.3. Transport hazard
class(es)
DOT Hazard Class: 6.1
IMDG: 6.1
Sub Class: Not Applicable
Air Class: 6.1
14.4. Packing group
III
III
III
14.5. Environmental hazards
IMDG
14.6. Special precautions for user
No further information
15. Regulatory information
Regulatory Overview
The regulatory data in Section 15 is not intended to be all-inclusive, only selected
regulations are represented.
Toxic Substance
Control Act ( TSCA)
All components of this material are either listed or exempt from listing on the TSCA
Inventory.
WHMIS Classification
D2A
US EPA Tier II Hazards
Fire:
No
Sudden Release of Pressure:
No
Reactive:
No
Immediate (Acute):
Yes
Delayed (Chronic):
Yes
EPCRA 311/312 Chemicals and RQs (Ibs):
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Safety Data Sheet
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SDS Revision Date:
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Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
EPCRA 302 Extremely Hazardous:
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
EPCRA 313 Extremely Hazardous:
Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
Proposition 65 - Carcinogens (>0.0%):
Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
Proposition 65 - Developmental Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Female Repro Toxins (>0.0%):
To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
Proposition 65 - Male Repro Toxins (>0.0%):
Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
New Jersey RTK Substances (>1%):
Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
Pennsylvania RTK Substances (>1%):
Trichloroethylene
1, 2 – BUTYLENE OXIDE STABILIZERS
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.
We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our
products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and
orders.
The full text of the phrases appearing in section 3 is:
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
H341 Suspected of causing genetic defects.
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Safety Data Sheet
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SDS Revision Date:
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H350 May cause cancer.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats
are not applicable.
The opinions expressed are those of qualified experts within ComStar International Inc. We believe that the
information contained is current as of the date of the Material Safety Data Sheet. Since the use of this information and
of these opinions and the conditions of the use of the product are not within the control of ComStar International Inc.,
it is the user’s obligation to determine the conditions of safe use of the product.
End of Document
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