Comstar B2201333 User Manual

Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
1. Identification
Product identifier
Super Grease Cutter
Other means of identification
Part Number
55-121/122/123/124
Recommended use
A solvent degreasing agent designed for removing tar, adhesives, grease, oil and other residues from metal and other hard surfaces.
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name
ComStar International Inc.
20-45 128th Street,
College Point, NY 11356
Telephone
718-445-7900
800-328-0142
Fax: 718-353-5998
2. Hazard(s) identification
H314 Contains gas under pressure, may explode if heated
Physical hazards
H223 Flammable aerosols
Health hazards
H315 Skin May cause skin irritation
H319 May cause Serious eye irritation
Environmental hazards
Not classified.
OSHA defined hazards
Not classified.
Label elements
Signal word
WARNING
Hazard statement
Flammable aerosol. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Precautionary statement
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Wear eye/face protection.
Response
If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see this label). If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
None known.
classified (HNOC)
Supplemental information
Not applicable.
3. Composition/information on ingredients
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Mixtures
Chemical name
Common name and synonyms
CAS number
%
Distillates petroleum hydrotreated light – aliphatic
64742-88-7
60 - < 70
Dipropylene glycol monomethyl ether (dpm)
034590-94-8
10 - <20 D-limonene
5989-27-5
10 - <20
Carbon dioxideaerosol only
124-38-9
1 - <3
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention if irritation develops and persists.
Ingestion
Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important symptoms/effects, acute and delayed
Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Defatting of the skin. Rash. Symptoms of overexposure can include shortness of breath. drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, and are reversible if exposure is stopped.
Indication of immediate medical attention and special treatment needed
Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim under observation. Symptoms may be delayed.
General information
In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from the chemical
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Special protective equipment and precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in endosed spaces. SCBA. Structural firefighters protective clothing will only provide limited protection.
Fire-fighting equipment/instructions
In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Water runoff can cause environmental damage.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. In the event of fire and/or explosion do not breathe fumes.
General fire hazards
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS.
Containment and Cleaning up
precautionary measures against static discharge. Use only non-sparking tools. Keep combustible (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never retum spills in original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not smoke. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Avoid release to the environment. Do not empty into drains.
Conditions for safe storage, including any incompatibilities
Level 3 Aerosol.
Contents under pressure. Keep away from heat, sparks and open flame. Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Keep in an area equipped with sprinklers.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Carbon Dioxide CAS 124-38-9
PEL & TWA
9000 mg/m3
STEL
30,000 ppm
Dipropylene glycol monomethyl ether Cas# 034590-94-8
Pel & tlv
1000 ppm
Aliphatic Distillates CAS 64742-88-7
PEL & TLV
2000 PPM
d-Limonene CAS 124-38-9
TWA
8 HR = 30 ppm (AIHA Std)
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering Controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation. or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.
Skin protection
Hand protection
Chemical resistant gloves are recommended.
Other
Avoid contact with clothing. Wear suitable protective clothing. Chemical resistant gloves.
Respiratory protection
No personal respiratory protective equipment normally required. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection.
General hygiene considerations
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
lLiquid.
Form
Aerosol.
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Color
Clear, Off-white.
Odor
Orange
Odor threshold
Not established
PH
Not applicable
Melting point/freezing point
Not established
Initial boiling point and boiling
> 302 °F (> 150 °C)
range
Flash point
104.0 °F (40.0 X) Tag Closed Cup
Evaporation rate
> 0.1 BuAc
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
0.7 %
(%) Flammability limit - upper
6%
(%) Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
< 5 mm Hg @ 20°C
Vapor density
> 1 (air=1)
Relative density
Not available.
Solubility(ies)
Solubility (water)
< 15%
Partition coefficient
Not established
(n-octanol/water)
Auto-ignition temperature
> 392 °F (> 200 °C)
Decomposition temperature
Not established
Viscosity
< 3 cSt @ 25°C
Other information
Heat of combustion
> 30 kJ/g
Percent volatile
100%
Specific gravity
0.82 - 0.86 @ 20°C
VOC (Weight %)
97.2 % per U.S. State and Federal Consumer Product Regulations
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous reactions
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks. Avoid temperatures exceeding the flash point.
Incompatible materials
Strong oxidizing agents.
Hazardous decomposition products
Carbon oxides.
11. Toxicological information
Information on likely routes of exposure
Ingestion
May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure.
Inhalation
May cause irritation to the respiratory system.
Eye contact
Causes eye irritatlon.
Symptoms related to the physical, chemical and toxicological characteristics
Irritant effects. Symptoms may Include stinging, tearing, redness, swelling, and blurred vision. Defatting of the skin. Symptoms of overexposure may be headache, dizziness,
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
tiredness, nausea and vomiting.
Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
Components
Species
Test Results
Distillates Petroleum Hydrotreated Light (CAS 64742-47-8)
Acute
Dermal
LD50
Rabbit
> 2000 mg/kg
Inhalation
LC50
Cat
> 6.4 mg/l
Rat
> 0.1 mg/l
Oral
LD50
Rat
> 5000 mg/kg
d-limonene (CAS 5989-27-5)
Acute
Dermal
LD50
Rabbit
> 5000 mg/kg
Oral
LD50
Mouse
5600 - 6600 mg/kg
Rat
> 2000 mg/kg
Other
LD50
Mouse
1.3 g/kg
Dipropylene glycol monomethyl ether - N/A
Rat
0.11 g/kg * Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation.
Causes skin irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitization
Based on available data, the classification criteria are not met.
Skin sensitization
May cause sensitization by skin contact.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Carcinogenicity
Based on available data, the classification criteria are not met.
IARC Monographs. Overall Evaluation of Carcinogenicity
d-limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Based on available data, the classification criteria are not met.
Specific target organ toxicity - single exposure
Based on available data, the classification criteria are not met.
Specific target organ toxicity ­repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Not likely, due to the form of the product.
Chronic effects
Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Components
Species
Test Results
Distillates Petroleum Hydrotreated Light (CAS 64742-47-8)
Aquatic
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Fish
LC50
Rainbow trout,donaldson trout (Oncorhynchus mykiss)
2.9 mg/l, 96 hours
d-Limonene (CAS 5989-27-5)
Aquatic
Crustacea EC50
Water flea (Daphnia pulex)
69.6 mg/l, 48 hours
Fish LC50
Fathead minnow (Pimephales promelas)
0.619 - 0.796 mg/l. 96 hours
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Not inherently biodegradable.
Bioaccumulative potential
No data available.
Partition coefficient n-octanol / water (log Kow)
d-limonene
4.232
Mobility in soil
Readily absorbed into soil.
Other adverse effects
Not available.
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazardous waste code
D001: Waste Flammable material with a flash point <140 F
D003: Waste Reactive material
Waste from residues / unused products
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
For: AEROSOLS
For: NON- AEROSOLS
UN number
UN1950
UN1993
UN proper shipping name
Aerosols, flammable
Flammable Liquid, N.O.S.
Transport hazard class(es)
Class
2.1
2.1
Subsidiary risk
-
Label(s)
2.1 ORM - D
2.1
Packing group
Not applicable
Environmental hazards
Marine pollutant
No
No
Special precautions for user
Not available.
Not available.
Special provisions
N82 - Packaging exceptions
306
-
Packaging non bulk
None
-
Packaging bulk
None
-
IATA
UN number
UN1950
UN1993
UN proper shipping name
Aerosols, flammable
Flammable Liquid, N.O.S.
Transport hazard class(es)
Class
2.1
2.1
Subsidiary risk
-
-
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Label(s)
2.1
2.1
Packing group
Not applicable.
Not applicable.
Environmental hazards
No.
No.
Special precautions for user
Not available.
Not available.
Other information
Passenger and cargo
Allowed.
Allowed.
aircraft
Cargo aircraft only
Allowed.
Allowed.
IMDG
UN1950
UN1993
UN number
Aerosols, flammable, MARINE POLLUTANT
Flammable Liquid, N.O.S.
UN proper shipping name
Transport hazard class(es)
Class
2.1
2.1
Subsidiary risk
-
Label(s)
2.1
2.1
Packing group
Not applicable.
Not applicable.
Environmental hazards
Marine pollutant
Yes
Yes
EmS
F-D, S-U
-
Special precautions for user
Not available.
Not available.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not available.
Not available. DOT
DOT
lATA; IMDG
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR
1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely
No
hazardous substance
Chemical
SARA 313(TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Carbon Dioxide (CAS 124-38-9)
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Carbon Dioxide (CAS 124-38-9)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region
Inventory name
On inventory (yes/no)*
Australia
Australian Inventory of Chemical Substances (AICS)
Yes
Canada
Domestic Substances List (DSL)
Yes
Canada
Non-Domestic Substances List (NDSL)
No
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical Substances (EINECS)
Yes Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Yes
Safety Data Sheet
Super Grease Cutter
SDS Revision Date:
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
*A "Yes" Indicates that all components of this product comply with the inventory requirements administered by the governing
country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).
16. Other information, including date of preparation or last revision
Issue date
10-21-2013
Version #
01
HMIS® ratings
Health: 2
Flammability: 4
Physical hazard: 2
NFPA ratings
Health: 2
Flammability: 2
Instability: 0
Disclaimer
The infomnation provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use. processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or In any process, unless specified in the text.
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