Compare-N-Save 75346, 75333, 75334 User Manual

SAFETY DATA SHEET Compare-N-Save® Systemic
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
2. HAZARDS IDENTIFICATION
Tree & Shrub Insect Drench
Product Name: Compare-N-Save® Systemic Tree & Shrub Insect Drench EPA Reg. No.: 228-525-84009 Product Type: Insecticide
Company Name: Ragan and Massey, Inc.
101 Ponchatoula Parkway Ponchatoula, LA 70454 1-800-264-5281
Telephone Numbers: For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300
For Medical Emergencies Only, Call 1-877-325-1840
This product is an EPA FIFRA registered pesticide. Some classifications on this SDS are not the same as the FIFRA label. Certain sections of this SDS are superseded by federal law governed by EPA for a registered pesticide. Please see Section 15. REGULATORY INFORMATION for explanation.
HEALTH HAZARDS: Acute toxicity, inhalation Category 4
Skin irritation Category 2 Specific target organ toxicity - Repeated exposure Category 2
ENVIRONMENTAL HAZARDS
Hazardous to the aquatic environment, acute Category 1
SIGNAL WORD: WARNING
HAZARD STATEMENTS
Harmful if inhaled. Causes skin irritation. May cause damage to organs (heart, liver, blood chemistry, and thyroid) through prolonged or repeated exposure. Very toxic to aquatic life.
PRECAUTIONARY STATEMENTS
Avoid breathing mist/vapors/spray. Use only outdoors or in a well-ventilated area. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. See product label and Section 4 First Aid for medical advice.
Wash hands and exposed skin thoroughly after handing. Wear protective gloves/protective clothing/eye protection/face protection. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Avoid release to the environment. Collect spillage. Dispose of contents/container in accordance with local/regional/national/international regulations.
May 5, 2015 Page 1 of 7
SAFETY DATA SHEET Compare-N-Save® Systemic
3. COMPOSITION / INFORMATION ON INGREDIENTS
4. FIRST AID MEASURES
5. FIRE FIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
Tree & Shrub Insect Drench
COMPONENT CAS NO. % BY WEIGHT
Imidacloprid 138261-41-3 6.5 – 7.2 Propylene Glycol 57-55-6 0.68 – 0.72 Other Ingredients Trade Secret Trade Secret
Synonyms: 1-[(6-chloro-3-pyridinyl)methyl]-N-nitro-2-imidazolidinimine Ingredients not precisely identified are proprietary or non-hazardous. Values are not product’s specifications.
If Swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person.
If in Eyes: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Most Important symptoms/effects/acute and delayed: Changes in blood chemistry. Damage to organs (heart, liver, blood chemistry, and thyroid) through prolonged or repeated exposure.
Indication of immediate medical attention and special treatment if needed: Respiratory or skin irritation.
Extinguishing Media: Water, carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus
and full fire-fighting turn out gear. Dike area to prevent runoff and contamination of water sources. Dispose of fire control water later.
Unusual Fire and Explosion Hazards: If water is used to fight fire, contain runoff, using dikes to prevent contamination of water supplies. Dispose of fire control water later.
Hazardous Decomposition Materials (Under Fire Conditions): May produce gases such as hydrogen chloride, hydrogen cyanide, and oxides of carbon and nitrogen.
Personal Precautions: Wear appropriate protective gear for the situation. See Personal Protection information in Section 8. Environmental Precautions: Prevent material from entering public sewer systems or any waterways. Do not flush to
drain. Large spills to soil or similar surfaces may necessitate removal of topsoil. The affected area should be removed and placed in an appropriate container for disposal.
Methods for Containment: Dike spill using absorbent or impervious materials such as earth, sand or clay. Collect and contaminated absorbent and dike material for disposal.
Methods for Cleanup and Disposal: Pump any free liquid into an appropriate closed container. Absorb and place into container for disposal. Decontaminate tools and equipment following cleanup. See Section 13: DISPOSAL CONSIDERATIONS for more information.
Other Information: Large spills may be reportable to the National Response Center (800-424-8802) and to state and/or local agencies.
May 5, 2015 Page 2 of 7
SAFETY DATA SHEET Compare-N-Save® Systemic
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA
ACGIH
WEEL Component
TWA
STEL
TWA
STEL
TWA
Unit
Imidacloprid
NE
NE
10*
NE
NE
NE
Propylene Glycol
NE
NE
NE
NE
10
mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
Tree & Shrub Insect Drench
HANDLING:
Causes moderate eye irritation. Avoid contact with eyes or clothing. Users should wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove Personal Protective Equipment (PPE) immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.
STORAGE:
Keep out of reach of children and animals. Store in original container only. Store in a cool, dry place and avoid excess heat.
Engineering Controls:
Where engineering controls are indicated by specific use conditions or a potential for excessive exposure, use local exhaust ventilation at the point of generation.
Personal Protective Equipment: Eye/Face Protection: Not normally required. To avoid contact with eyes, wear chemical goggles or shielded safety
glasses. An emergency eyewash or water supply should be readily accessible to the work area. Skin Protection: To avoid contact with skin, wear long pants, long-sleeved shirt, shoes and socks. An emergency shower or water supply should be readily accessible to the work area. Respiratory Protection: Not normally required. If vapors or mists exceed acceptable levels, wear NIOSH approved air­purifying respirator with cartridges/canisters approved for use against pesticides. General Hygiene Considerations: Personal hygiene is an important work practice exposure control measure and the following general measures should be taken when working with or handling this material: 1) do not store, use and/or consume foods, beverages, tobacco products, or cosmetics in areas where this material is stored; 2) wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics or using the toilet.
Exposure Guidelines:
NE = Not Established WEEL = AIHA Workplace Environmental Exposure Levels
Appearance: White colored liquid Odor: Pungent odor Odor threshold: No data available pH: 5.90 ± 0.01 Melting point/freezing point: No data available Initial boiling point and boiling range: No data available Flash point: >100º C Evaporation rate: No data available Flammability (solid, gas): No data available Upper/lower flammability or explosive limits: No data available Vapor Pressure: No data available Vapor Density: 1.006 g/ml
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