SAFETY DATA SHEET
Issuing Date: 12-Feb-2015
Product Name
Product Code(s)
Product ID:
Product Type:
Recommended Use
Restrictions on Use
Manufacturer
Revision Date: 07-Apr-2015
Version 2
1. IDENTIFICATION
CometÒ Disinfecting Sanitizing Bathroom Cleaner
3-20
15154320_PROF_NG
Finished Product - Professional Use Only
Disinfectant
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
Procter & Gamble Professional
2 P&G Plaza
Cincinnati, Ohio 45202
Procter & Gamble Inc.
P.O. Box 355, Station A
Toronto, ON M5W 1C5
1-800-332-7787
E-mail Address
Emergency Telephone
pgsds.im@pg.com
Transportation (24 HR)
CHEMTREC - 1-800-424-9300
(U.S./ Canada) or 1-703-527-3887
Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Hazard Category
Acute toxicity - Oral
Eye Damage / Irritation
Corrosive to metals
Signal Word
Hazard Statements
Hazard pictograms
Category 4
Category 2B
Category 1
WARNING
Causes eye irritation
Harmful if swallowed
May be corrosive to metals
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Precautionary Statements Prevention
Precautionary Statements Response
Precautionary Statements Storage
Precautionary Statements Disposal
Hazards not otherwise classified
(HNOC)
Wash hands thoroughly after handling
Do not eat, drink or smoke when using this product
Keep only in original container
Do not mix with other cleaning products or chemicals as irritating fumes may be formed
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF SWALLOWED:
Rinse with plenty of water
Drink 1 or 2 glasses of water
Call a POISON CENTER or doctor/physician if you feel unwell
Absorb spillage to prevent material damage
Store in corrosive resistant container
Dispose of contents/container in accordance with local regulation
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
Chemical Name Synonyms Trade Secret CAS-No Weight %
Dipropylene Glycol Butoxy Ether
Citric acid - No 77-92-9 1 - 5
1-Propanaminium,
N-(3-aminopropyl)-2-hydroxy-N,N-dim
ethyl-3-sulfo-, N-coco acyl derivs.,
inner salts
Benzenesulfonic acid,
(1-methylethyl)-, sodium salt (1:1)
Alcohols, C9-11, ethoxylated - No 68439-46-3 1 - 5
- No 29911-28-2 5 - 10
- No 68139-30-0 1 - 5
- No 28348-53-0 1 - 5
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact
Skin contact
Ingestion
Inhalation
Rinse with plenty of water. Get medical attention immediately if irritation persists.
Rinse with plenty of water. Get medical attention if irritation develops and persists.
Rinse mouth. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention
immediately if symptoms occur.
Move to fresh air. If symptoms persist, call a physician.
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Most important symptoms/effects,
acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician
None under normal use conditions.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Unsuitable Extinguishing Media
Special hazard
Special protective equipment for
fire-fighters
Specific hazards arising from the
chemical
Personal precautions, protective equipment and emergency procedures
Dry chemical, CO 2, alcohol-resistant foam or water spray.
None.
None known.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Advice for emergency responders
Methods and materials for containment and cleaning up
Methods for containment
Methods for cleaning up
Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Use personal protective equipment as required.
Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal.
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible products
Use personal protective equipment as required. Keep container closed when not in use.
Never return spills in original containers for re-use. Keep out of the reach of children.
Keep containers tightly closed in a dry, cool and well-ventilated place. Store in corrosive
resistant container.
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
No exposure limits noted for ingredient(s).
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Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:
Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction
Personal Protective Equipment
Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Revision Date: 07-Apr-2015
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C
Appearance
Odor
Odor threshold
Property
pH value
Melting/freezing point
Boiling point/boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower Flammability Limit
Vapor pressure
Vapor density
Relative density
liquid
clear
Scented
No information available
Values
3
No information available
No information available
> 93.3 °C / > 200 °F
No information available
No information available
No information available
No information available
No information available
No information available
1.042
Note
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Revision Date: 07-Apr-2015
Water solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Viscosity of Product
VOC Content (%)
Reactivity
Stability
Hazardous polymerization
Hazardous Reactions
Conditions to Avoid
Materials to avoid
Hazardous Decomposition Products
100%
No information available
No information available
No information available .
No information available .
<10 cps
Products comply with US state and federal regulations for VOC content in consumer
products.
10. STABILITY AND REACTIVITY
None under normal use conditions.
Stable under normal conditions.
Hazardous polymerization does not occur.
None under normal processing.
None under normal processing.
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
No known effect.
No known effect.
May be harmful if swallowed.
Irritating to eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Respiratory sensitization
Germ cell mutagenicity
Neurological Effects
Reproductive toxicity
Developmental toxicity
Teratogenicity
STOT - single exposure
STOT - repeated exposure
Target Organ Effects
Aspiration hazard
Carcinogenicity
May be harmful if swallowed.
No known effect.
Irritating to eyes.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
Component Information
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation
Dipropylene Glycol Butoxy Ether 29911-28-2 2610 mg/kg bw (Similar to
OECD 401; standard acute
method; rat)
Citric acid 77-92-9 5400 mg/kg bw (Similar to
OECD 401; standard acute
method; mouse)
> 2000 mg/kg bw (OECD
402; standard acute
method; rat)
> 2000 mg/kg bw (OECD
402, standard acute
method; rat)
> 2.04 mg/L air (OECD
403; standard acute
method; rat)
-
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Benzenesulfonic acid,
(1-methylethyl)-, sodium salt (1:1)
Alcohols, C9-11, ethoxylated 68439-46-3 1600.00 mg/kg (rat) - -
28348-53-0 5160.00 mg/kg (rat) - -
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability
Bioaccumulative potential
Mobility
Other adverse effects
No information available.
No information available.
No information available.
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment
Waste from Residues / Unused
Products
Contaminated packaging
Products covered by this MSDS, in their original form, when disposed as waste, are
corrosive hazardous waste, D002, according to Federal RCRA regulations (40 CFR 261).
Disposal should be in accordance with local, state and federal regulations.
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
California Hazardous Waste Codes
(non-household setting)
DOT
UN no
UN Proper shipping name
Description
Hazard Class
Packing Group
IMDG
UN Number
UN Proper shipping name
Description
Transport hazard class(es)
Packing Group
IATA
UN no
UN Proper shipping name
Description
Hazard Class
Packing Group
331
14. TRANSPORT INFORMATION
UN1760
Corrosive liquids, n.o.s.
UN1760, Corrosive liquid, n.o.s , (citric acid), 8, III , Ltd. Qty.
8
III
UN1760
Corrosive liquid, n.o.s.
UN1760, Corrosive liquid, n.o.s , (citric acid), 8, III , Ltd. Qty.
8
III
UN1760
Corrosive liquid, n.o.s.
UN1760, Corrosive liquid, n.o.s, (citric acid), 8, III , Ltd. Qty.
8
III
U.S. Federal Regulations
SARA 313
15. REGULATORY INFORMATION
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Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
This product does not contain any substances regulated by state right-to-know regulations
Revision Date: 07-Apr-2015
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Canada
This product is in compliance with CEPA for import by P&G.
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
CEPA - Canadian Environmental Protection Act
FIFRA
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain
labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information
required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the
pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
EPA Registration number: 3573-54
CAUTION
May be harmful if swallowed
Causes eye irritation
16. OTHER INFORMATION
HMIS Ratings
Health hazard
Flammability
Physical hazard
3
1
0
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Revision Date: 07-Apr-2015
Health hazard
Flammability
Instability
Issuing Date:
Revision Date:
3
1
0
12-Feb-2015
07-Apr-2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text
End of SDS
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