Page 1
Revision Number: 001.1
Issue date: 03/16/2017
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
Product identifier used on the label:
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
Recommended use of the chemical and restrictions on use:
Crawling insects, Use biocides safety. Always read the label and
product information before use.
Name, address and telephone number of the chemical manufacturer:
Combat Insect Control Systems
7201 E. Henkel Way
Scottsdale, AZ 85255
Emergency telephone number:
Medical Emergencies:
2. HAZARDS IDENTIFICATION
The hazards described in this OSHA Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and
does not address consumer use of the product. For information regarding consumer applications of this product, refer to the
product label.
Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200
HAZARD CLASS
HAZARD CATEGORY
SKIN SENSITIZATION
1
Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200
Signal word:
WARNING
Hazard Statement(s):
May cause an allergic skin reaction.
Symbol(s):
Precautionary Statements:
Prevention:
Avoid breathing vapors, mist, or spray.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves.
Response:
IF ON SKIN: Wash with plenty of water.
If skin irritation or rash occurs: Get medical attention.
Wash contaminated clothing before reuse.
Storage:
Not prescribed
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local governmental
regulations.
Hazards not otherwise
classified:
None known
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Safety Data Sheet
Page 1 of 7
Page 2
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.
Chemical Name*
CAS Number (Unique
Identifier)
Concentration
Gelling agent
Proprietary
1 - 5 %
Preservative
Proprietary
0.1 - 1 %
Fipronil
120068-37-3
103.000 PPM
*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in accordance with paragraph (i) of
§1910.1200.
4. FIRST AID MEASURES
Description of necessary measures
Inhalation:
Remove from exposure area to fresh air. Treat symptomatically and supportively.
Skin contact:
Rinse affected area with mild soap and water until no evidence of product remains. Get medical
attention if irritation persists.
Eye contact:
Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no
evidence of product remains. Get medical attention if pain or irritation develops.
Ingestion:
Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. Contact
physician or local poison control center.
Most important symptoms and effects, both acute and delayed
After eye contact: May cause mild transient irritation After skin contact: Repeated or prolonged excessive exposure may cause
irritation or dermatitis. After ingestion: May be fatal if swallowed and enters airways. Nausea and possible vomiting may occur. After
inhalation: Unlikely to occur due to the physical properties of the product.
Indication of any immediate medical attention and special treatment needed
After eye contact: Rinse eyes with plenty of water until no evidence of product remains. After skin contact: Rinse affected area with
mild soap and water until no evidence of product remains. After ingestion: May be fatal if swallowed and enters airways. Dilution by
rinsing the mouth and giving a glass of water to drink is generally recommended. After inhalation: Remove from exposure area to
fresh air.
5. FIRE FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media
Suitable extinguishing media:
Dry chemical, carbon dioxide, water spray or regular foam.
Unsuitable extinguishing media:
None known
Specific hazards arising from the chemical
Irritating smoke, carbon monoxide, and carbon dioxide.
Special protective equipment and precautions for fire-fighters
In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Shut off all ignition sources
Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Isolate area. Keep unnecessary
personnel away. Avoid breathing vapors, keep upwind.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear skin, eye and respiratory protection as recommended in Section 8. Ventilate spill area if possible. Do not touch spilled
material. Spills present a slipping hazard. Keep unnecessary personnel away. Make sure area is slip-free before re-opening to
traffic.
Environmental precautions
Do not discharge into surface water/ground water.
Methods and materials for containment and cleaning up
SMALL SPILLS: Sweep or scoop up and place into containers for later disposal. Wash site of spillage thoroughly with water.
LARGE SPILLS: Ventilate closed spaces before entering. Sweep or scoop up. Dispose in suitable waste container. Keep
unnecessary people away from spill.
Page 2 of 7
Page 3
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
7. HANDLING AND STORAGE
Precautions for safe handling
Do not get in eyes, on skin, on clothing Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists.
Keep the containers closed when not in use.
Conditions for safe storage, including any incompatibilities
Store in a cool, dry, ventilated area out of reach of children and away from sources of heat, moisture, and incompatible substances.
Store in suitable labeled containers. Store the containers tightly closed. Storage areas for large quantities (warehouse) should be
well ventilated.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit
Value (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing
the safety data sheet, where available.
Hazardous Component(s)
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
Table sugar
10 mg/m3 TWA
5 mg/m3 PEL
Respirable fraction.
15 mg/m3 PEL Total
dust.
None
None
Appropriate engineering controls
Provide local exhaust or general dilution ventilation to keep exposure to airborne contaminants below the permissible exposure
limits where mists or vapors may be generated.
Individual protection measures
Respiratory:
Air contamination monitoring should be carried out where mists or vapors are likely to be
generated, to assure that the employees are not exposed to airborne contaminants above the
permissible exposure limits.
Eye:
Safety glasses are required to prevent eye contact where dusty conditions may occur.
Hand/Body:
Protective gloves are required where repeated or prolonged skin contact may occur.
Protective clothing is required where repeated or prolonged skin contact may occur.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
gel brown
Odor:
characteristic
Odor threshold:
Not available.
pH:
Not available.
Melting point/ range:
Not available.
Boiling point/range:
Not available.
Flash point:
> 93.3 °C (> 199.94 °F)
Evaporation rate:
Not available.
Flammable/Explosive limits - lower:
Not available.
Flammable/Explosive limits - upper:
Not available.
Vapor pressure:
Not available.
Vapor density:
Not available.
Solubility in water:
Not available.
Partition coefficient (n-octanol/water):
Not available.
Autoignition temperature:
Not available.
Decomposition temperature:
Not available.
Viscosity:
Not available.
VOC content:
Not available.
Page 3 of 7
Page 4
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
10. STABILITY AND REACTIVITY
Reactivity:
This product may react with strong alkalies.
Chemical stability:
Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm).
Possibility of hazardous
reactions:
Hazardous polymerization has not been reported to occur under normal temperatures and
pressures.
Conditions to avoid:
Avoid storing in direct sunlight and avoid extremes of temperature.
Incompatible materials:
Strong oxidizers and reducing agents.
Hazardous decomposition
products:
Thermal decomposition products may include oxides of carbon.
11. TOXICOLOGICAL INFORMATION
Likely routes of exposure including symptoms related to characteristics
Inhalation:
Unlikely to occur due to the physical properties of the product. Dust may cause mucous
membrane irritation with coughing, dryness and sore throat.
Skin contact:
Repeated or prolonged excessive exposure may cause irritation or dermatitis.
Eye contact:
Mild eye irritation.
Ingestion:
May cause mild gastrointestinal irritation with nausea, vomiting, diarrhea and abdominal pain.
Physical/Chemical:
No physical/chemical hazards are anticipated for this product.
Other relevant toxicity
information:
This product is an insecticide. The use of this product by consumers is safe under normal and
reasonable foreseen use.
Numerical measures of toxicity, including delayed and immediate effect
Hazardous Component(s)
LD50s and LC50s
Immediate and Delayed Health Effects
Gelling agent
None
Irritant
Preservative
None
Irritant, Allergen, Respiratory
Fipronil
Oral LD50 (RAT) = 92 mg/kg
Oral LD50 (RAT) = 103 mg/kg
Dermal LD50 () = 445 mg/kg
Dermal LD50 () = 354 mg/kg
Dermal LD50 (RAT) = > 2,000 mg/kg
Inhalation LC50 (, 4 h) = 0.68 mg/l
No Data
Carcinogenicity information
Hazardous Component(s)
NTP Carcinogen
IARC Carcinogen
OSHA Carcinogen
Gelling agent
No
No
No
Preservative
No
No
No
Fipronil
No
No
No
Carcinogenicity
None of the ingredients in this product are listed as carcinogens by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational
Safety and Health Administration (OSHA).
Mutagenicity
None of the ingredients in this product are known to cause mutagenicity.
Toxicity for reproduction
None of the ingredients in this product are known as reproductive, fetal, or developmental
hazards.
12. ECOLOGICAL INFORMATION
Aquatic Toxicity:
This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use
conditions. The active ingredient Fipronil is toxic birds, fish, and aquatic invertebrates.
Page 4 of 7
Page 5
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
Toxicity to fish:
Hazardous substances
CAS-No.
Value
type
Value
Acute
Toxicity
Study
Exposure
time
Species
Method
Gelling agent
LC50
490 mg/l
Fish
96 h
Oncorhynchus mykiss
OECD Guideline
203 (Fish, Acute
Toxicity Test)
Preservative
LC50
1.4 mg/l
Fish
96 h
Salmo gairdneri (new name:
Oncorhynchus mykiss)
OECD Guideline
203 (Fish, Acute
Toxicity Test)
NOEC
0.21 mg/l
Fish
30 d
Oncorhynchus mykiss
OECD Guideline
215 (Fish,
Juvenile Growth
Test)
5-amino-1-[2,6-dichloro-4(trifluoromethyl)phenyl]-4-
[(trifluoromethyl)sulfinyl]-
120068-37-3
LC50
0.25 mg/l
Fish
96 h
Oncorhynchus mykiss
OECD Guideline
203 (Fish, Acute
Toxicity Test)
Toxicity to aquatic invertebrates:
Hazardous substances
CAS-No.
Value
type
Value
Acute
Toxicity
Study
Exposure
time
Species
Method
Gelling agent
EC50
980 mg/l
Daphnia
48 h
Daphnia magna
OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
Preservative
EC50
1.05 mg/l
Daphnia
48 h
Daphnia magna
OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
5-amino-1-[2,6-dichloro-4(trifluoromethyl)phenyl]-4-
[(trifluoromethyl)sulfinyl]-
120068-37-3
EC50
0.19 mg/l
Daphnia
48 h
Daphnia magna
OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
Toxicity to algae:
Hazardous substances
CAS-No.
Value
type
Value
Acute
Toxicity
Study
Exposure
time
Species
Method
Preservative
EC50
0.11 mg/l
Algae
72 h
Pseudokirchnerella
subcapitata
OECD Guideline
201 (Alga,
Growth Inhibition
Test)
EC10
0.04 mg/l
Algae
72 h
Pseudokirchnerella
subcapitata
OECD Guideline
201 (Alga,
Growth Inhibition
Test)
5-amino-1-[2,6-dichloro-4(trifluoromethyl)phenyl]-4-
[(trifluoromethyl)sulfinyl]-
120068-37-3
EC50
0.07 mg/l
Algae
96 h
Desmodesmus subspicatus
(reported as Scenedesmus
subspicatus)
OECD Guideline
201 (Alga,
Growth Inhibition
Test)
Page 5 of 7
Page 6
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
Persistence and degradability
Hazardous substances
CAS-No.
Result value
Route of
application
Species
Method
Gelling agent
readily biodegradable
aerobic
91 - 95 %
EU Method C.4-E
(Determination of the "Ready"
BiodegradabilityClosed Bottle
Test)
Preservative
Rapidly degradable
not specified
> 70 %
OECD Guideline 309 (Aerobic
Mineralisation in Surface
WaterSimulation
Biodegradation Test)
Bioaccumulative potential
The bioaccumulation potential of this product has not been determined.
Mobility in soil
The mobility of this product (in soil and water) has not been determined.
13. DISPOSAL CONSIDERATIONS
Description of waste residues:
Hazardous waste number:
Not applicable
Safe handling and disposal methods:
Recommended method of disposal:
Pesticide wastes may be acutely hazardous. Improper disposal of excess
pesticide, spray mixture, or rinsate is a violation of Federal Law.
Disposal of uncleaned packages:
Do not reuse this container. Never place unused product down any indoor or
outdoor drain. Dispose of container and unused contents in accordance with
federal, state and local requirements.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper shipping classification may vary by packaging, properties, and mode of
transportation.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name:
Not regulated
Hazard class or division:
None
Identification number:
None
Packing group:
None
International Air Transportation (ICAO/IATA)
Proper shipping name:
Not regulated
Hazard class or division:
None
Identification number:
None
Packing group:
None
Water Transportation (IMO/IMDG)
Proper shipping name:
Not regulated
Hazard class or division:
None
Identification number:
None
Packing group:
None
Page 6 of 7
Page 7
RS Number: 420259
Combat Source Kill Max Roach Killing Gel, EPA Reg. 64240-45
15. REGULATORY INFORMATION
TSCA 8 (b) Inventory Status:
FIFRA listed All components are listed or are exempt from listing on the Toxic Substances
Control Act inventory.
TSCA 12 (b) Export Notification:
CERCLA/SARA Section 302 EHS:
None above reporting de minimis.
CERCLA/SARA Section 311/312:
Not available.
CERCLA/SARA Section 313:
None above reporting de minimis.
California Proposition 65:
No California Proposition 65 listed chemicals are known to be present.
FIFRA Regulated Products:
This is a pesticide product registered by the US Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements
differ from the classification criteria and hazard information required for safety data sheets
(SDS), and for workplace labels of non-pesticide chemicals. Refer to the pesticide label for
specific hazard information. The pesticide label also includes other important information,
including directions for use. EPA Signal Word: Caution
EPA Precautionary Language: Harmful if absorbed through skin. Causes moderate eye
irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water
after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
CEPA DSL/NDSL Status:
One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.
16. OTHER INFORMATION
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.
Prepared by:
R&D Support Services
Issue date:
03/16/2017
Occupational safety and health act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety and
Health Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in the
workplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDS
may contain health hazard information not relevant to consumer use.
United States Regulatory Information
Canada Regulatory Information
Page 7 of 7
Loading...