Y-102
Safety Data Sheet
Revision Number: 007.0
Issue Date: 04/17/2015
Combat Insect Control Systems C/O The Dial Corporation, a Henkel Company; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Combat® Insecticide
Page 1 of 5
HAZARD CLASS
HAZARD CATEGORY
SKIN SENSITIZATION
1
The hazards described in this OSHA Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and does
not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label.
1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
Product identifier used on the label: Combat® MAX Ant Killing Gel
Other means of identification: 1532043; EPA Reg. 64240-42
Recommended use of the chemical and restrictions on use: Insecticide (Ant gel), Use biocides safety. Always read the label and product information
Name, address and telephone number of the chemical manufacturer:
Emergency telephone number: Medical Emergencies: 1-888-689-9082
Combat Insect Control Systems C/O The Dial Corporation
7201 E. Henkel Way
Scottsdale, AZ 85255-9672 USA
CHEMTREC: 1-800-424-9300 (24 hours daily)
Internet: www.henkelna.com
Combat® Source Kill Max A2
before use
2. HAZARD IDENTIFICATION
Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200
Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200
Signal word: WARNING
Hazard Statement(s): May cause an allergic skin reaction.
Symbol(s):
Precautionary Statements:
Prevention: Avoid breathing vapors, mist, or spray.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves.
Response: IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical attention.
Wash contaminated clothing before reuse.
Storage: Not prescribed.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations.
Hazards not otherwise classified: Not available.
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United
Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.
Combat Insect Control Systems C/O The Dial Corporation; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Combat® Insecticide
Page 2 of 5
Chemical Name*
CAS Number (Unique Identifier)
Concentration
Table Sugar
Proprietary
10 – 30 %
Sugar
Proprietary
1 – 5 %
Preservative
Proprietary
0.1 – 1 %
Fipronil
120068-37-3
0.001 %
Hazardous Component(s)
ACGIH
OSHA PEL
AIHA WEEL
OTHER
*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in
accordance with paragraph (i) of §1910.1200.
4. FIRST AID MEASURES
Description of necessary measures
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Inhalation: Remove from exposure area to fresh air. Treat symptomatically and supportively. If any symptoms appear, get medical attention.
Skin contact: Rinse affected area with mild soap and water until no evidence of product remains. Get medical attention if irritation persists.
Eye contact: Rinse eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention if pain or irritation
develops.
Ingestion: Dilution by rinsing the mouth and giving water or milk to drink is generally recommended. Contact physician or local poison control
center.
After eye contact: May cause irritation. After skin contact: Repeated or prolonged excessive exposure may cause irritation or dermatitis or
sensitization in previously exposed individuals. After ingestion: Nausea and possible vomiting may occur. After inhalation: Unlikely to occur
due to the physical properties of the product.
After eye contact: Rinse eyes with plenty of water until no evidence of product remains. After skin contact: Rinse affected area with mild soap
and water until no evidence of product remains. After ingestion: Dilution by rinsing the mouth and giving a glass of water to drink is generally
recommended. After inhalation: Remove from exposure area to fresh air.
5. FIRE FIGHTING MEASURES
Suitable (and unsuitable) extinguishing media
Specific hazards arising from the chemical
Irritating smoke, carbon monoxide, and carbon dioxide.
Special protective equipment and precautions for fire-fighters
In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Shut off all ignition sources. Apply cooling water
to sides of containers that are exposed to flames until well after fire is out. Isolate area. Keep unnecessary personnel away. Avoid breathing vapors,
keep upwind.
Suitable extinguishing media: Dry chemical, carbon dioxide, water spray or regular foam.
Unsuitable extinguishing media: None known
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear skin, eye and respiratory protection as recommended in Section 8. Ventilate spill area if possible. Do not touch spilled material. Spills present a
slipping hazard. Keep unnecessary personnel away. Make sure area is slip-free before re-opening to traffic.
Methods and materials for containment and cleaning up
SMALL SPILLS: Sweep or scoop up and place into containers for later disposal. Wash site of spillage thoroughly with water. LARGE SPILLS: Ventilate
closed spaces before entering. Sweep or scoop up and place into suitable clean, dry containers for reclamation or later disposal. Do not flush spilled
material into sewer. Dispose in suitable waste container. Keep unnecessary people away from spill.
7. HANDLING AND STORAGE
Precautions for safe handling
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Keep the containers closed when not in use. Avoid
generating dusts.
Conditions for safe storage, including any incompatibilities
Store in a cool, dry, ventilated area out of reach of children and away from sources of heat, moisture, and incompatible substances. Store in suitable
labeled containers. Store the containers tightly closed. Storage areas for large quantities (warehouse) should be well ventilated.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV),
and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the safety data sheet,
where available.
Combat Insect Control Systems C/O The Dial Corporation; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Combat® Insecticide
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Table Sugar
10 mg/m3 TWA
5 mg/m3 PEL Respirable fraction.
15 mg/m3 PEL Total dust.
None
None
Sugar
10 mg/m3 TWA
5 mg/m3 PEL Respirable fraction.
15 mg/m3 PEL Total dust.
None
None
Fipronil
None
None
None
TWA: 0.1 mg/m3; 0.032 mg/m3
Appropriate engineering controls
Provide local exhaust or general dilution ventilation to keep exposure to airborne contaminants below the permissible exposure limits where mists or
vapors may be generated.
Individual protection measures
Respiratory: Air contamination monitoring should be carried out where mists or vapors are likely to be generated, to assure that the
employees are not exposed to airborne contaminants above the permissible exposure limits. If respiratory protection is required, it must be
based on the contamination levels found in the workplace, must not exceed the working limits of the respirator and be jointly approved by the
National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA).
Eye: Safety glasses are required to prevent eye contact where dusty conditions may occur.
Hand/Body: Protective gloves are required where repeated or prolonged skin contact may occur.
Protective clothing is required where repeated or prolonged skin contact may occur.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: gel, yellow
Odor: characteristic
Odor threshold: Not available
pH: Not applicable
Melting point/ range: 60°C (140°F)
Boiling point/range: Not available.
Flash point: > 93.3 °C (> 199.94 °F)
Evaporation rate: Not available.
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available.
Autoignition temperature: Not available.
Decomposition temperature: Not available.
Viscosity: Not available.
VOC content: Not available.
Specific gravity: 1.27 g/ml
10. STABILITY AND REACTIVITY
Reactivity: This product may react with strong reducing agents.
Chemical stability: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm).
Possibility of hazardous reactions: Hazardous polymerization has not been reported to occur under normal temperatures and pressures.
Conditions to avoid: Avoid storing in direct sunlight and avoid extremes of temperature.
Incompatible materials: Strong oxidizers and reducing agents
Hazardous decomposition products: Thermal decomposition products may include oxides of carbon.
11. TOXICOLOGICAL INFORMATION
Likely routes of exposure including symptoms related to characteristics
Other relevant toxicity information:
This product is an insecticide. The use of this product by consumers is safe under normal and reasonable foreseen use.
Acute oral product toxicity: LD50 > 5,000 mg/kg
Inhalation: Unlikely to occur due to the physical properties of the product. Dust may cause mucous membrane irritation with coughing,
dryness and sore throat.
Skin contact: Repeated or prolonged excessive exposure may cause irritation or sensitization dermatitis in previously exposed individuals.
Eye contact: May cause mild irritation.
Ingestion: May cause mild gastrointestinal irritation with nausea, vomiting, diarrhea and abdominal pain.
Physical/Chemical: No physical/chemical hazards are anticipated for this product.
Combat Insect Control Systems C/O The Dial Corporation; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Combat® Insecticide
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Acute dermal product toxicity: LD50 > 2,000 mg/kg
Hazardous Component(s)
LD50s and LC50s
Immediate and Delayed Health Effects
Table Sugar
Oral LD50 (RAT) = 29,700 mg/kg
Skin, Nuisance dust
Sugar
None
Irritant
Other Food Ingredients
None
Allergen, Irritant
Preservative
None
Irritant, Allergen, Respiratory
Hazardous Component(s)
NTP Carcinogen
IARC Carcinogen
OSHA Carcinogen
Table Sugar
No
No
No
Sugar
No
No
No
Other Food Ingredients
No
No
No
Preservative
No
No
No
Hazardous substances
Value type
Value
Acute toxicity
study
Exposure
time
Species
Method
Table Sugar
LC50
>700 mg/l
Fish
48 h
Danio rerio
Sugar
LC50
490 mg/l
Fish
96 h
Oncorhynchus
mykiss
OECD 203
Other Food Ingredients
LC50
> 100 mg/l
Fish
96 h OECD 203
Preservative
LC50
1.4 mg/l
Fish
96 h
Oncorhynchus
mykiss
OECD 203
Hazardous substances
Value type
Value
Acute toxicity
study
Exposure
time
Species
Method
Sugar
EC50
980 mg/l
Daphnia
48 h
Daphnia magna
OECD 202
Other Food Ingredients
EC50
> 100 mg/l
Daphnia
48 h
Daphnia magna
OECD 202
Preservative
EC50
1.05 mg/l
Daphnia
48 h
Daphnia magna
OECD 202
Hazardous substances
Value type
Value
Acute toxicity
study
Exposure time
Species
Method
Other Food Ingredients
EC50
> 100 mg/l
Algae
72 h
Desmodesmus
subspicatus
OECD 201
Preservative
EC50
0.11 mg/l
Algae
72 h
Pseudokirchnerella
subcapitata
OECD 201
Hazardous substances
Result value
Route of application
Species
Method
Table Sugar
Readily biodegradable
aerobic
73 – 90 %
EU Method C.4-E (closed
bottle)
Sugar
Readily biodegradable
aerobic
91 – 95 %
EU Method C.4-E (closed
bottle)
Other Food Ingredients
Readily biodegradable
aerobic
88 – 100 %
EU Method C.4-E (closed
bottle)
Numerical measures of toxicity, including delayed and immediate effect
Carcinogenicity information
Carcinogenicity None of the ingredients in this product are listed as carcinogens by the International Agency for Research on Cancer
(IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health Administration (OSHA).
Mutagenicity None of the ingredients in this product are known to cause mutagenicity.
Toxicity to reproduction None of the ingredients in this product are known to have reproductive, fetal, or developmental hazards.
12. ECOLOGICAL INFORMATION
Aquatic Toxicity:
This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal use conditions. The following
toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided as reference for the occupational settings.
Toxicity to fish:
Toxicity to aquatic invertebrates:
Toxicity to algae:
Persistence and Degradability: The persistence and degradability of this product has not been determined.
Bioaccumulation Potential: The bioaccumulation potential of this product has not been determined.
Mobility: The mobility of this product (in soil and water) has not been determined.
13. DISPOSAL CONSIDERATIONS
Waste Number and Description: Not applicable, not regulated.
Disposal Considerations:
Combat Insect Control Systems C/O The Dial Corporation; 7201 E. Henkel Way; Scottsdale, AZ 85255-9672
Combat® Insecticide
Page 5 of 5
Disposal of products: Pesticide wastes may be acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is
a violation of Federal Law.
Disposal of packages: Do not reuse this container. Never place unused product down any indoor or outdoor drain. Dispose of
container and unused contents in accordance with federal, state and local requirements.
Additional information: Observe all federal, state and local regulations when storing or disposing of this substance
14. TRANSPORT INFORMATION
The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
15. REGULATORY INFORMATION
Occupational Safety and Health Act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety and Health
Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in the workplace.
Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDS may contain health
hazard information not relevant to consumer use.
United States Regulatory Information:
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302: None above reporting de minimis
CERCLA/SARA Section 311/312: Not available.
CERCLA/SARA Section 313: None above reporting de minimis
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Export Restrictions: This is a pesticide product registered by the US Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and
for workplace labels of non-pesticide chemicals. Refer to the pesticide label for specific hazard information. The pesticide label also includes other
important information, including directions for use.
Canada Regulatory Information:
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the
Non-Domestic Substances List.
16. OTHER INFORMATION
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its
affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s
responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such
precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any
Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and
fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental
damages of any kind, including lost profits.
This safety data sheet contains changes from the previous version in sections: 2, 3, 8, 11, 12
Prepared by: R&D Support Services
Issue date: 04/17/2015 Supercedes: Rev. 6, 08/11/2014
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