SAFETY DATA SHEET
Issuing Date: 09-Jan-2015 Revision Date: 14-May-2018 Version 2.01
1. IDENTIFICATION
Product Name
Product Code(s)
Product Identifier
Product Type:
Recommended Use
Restrictions on Use
Details of the supplier of the safety
data sheet
E-mail Address
Emergency Telephone
CometÒ Cleaner with Bleach - Ready to Use
3-30
15154199_PROF_NG
Finished Product - Professional Use Only
Hard Surface Cleaner.
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
Procter & Gamble Professional
1 P&G Plaza
Cincinnati, Ohio 45202
Procter & Gamble Inc.
P.O. Box 355, Station A
Toronto, ON M5W 1C5
1-800-332-7787
pgsds.im@pg.com
Transportation (24 HR)
CHEMTREC - 1-800-424-9300
(U.S./ Canada) or 1-703-527-3887
Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classified under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Hazard Category
Eye Damage / Irritation
Corrosive to metals
Signal Word
Hazard Statements
Hazard pictograms
Precautionary Statements
Category 2B
Category 1
WARNING
Causes eye irritation
May be corrosive to metals
Wash hands thoroughly after handling
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Keep only in original container
Do not mix with other cleaning products or chemicals as irritating fumes may be formed
Revision Date: 14-May-2018
Precautionary Statements Response
Precautionary Statements - Storage
Precautionary Statements - Disposal
Hazards not otherwise classified
(HNOC)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF SWALLOWED:
Drink 1 or 2 glasses of water
Absorb spillage to prevent material damage
Store in corrosive resistant container
Dispose of contents/container in accordance with local regulation
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
Chemical Name Synonyms Trade Secret CAS-No Weight-%
Sulfuric acid, monooctyl ester, sodium
salt (1:1)
Sulfuric acid monododecyl ester
sodium salt (1:1)
Sodium hypochlorite Hypochlorous acid,
Sulfuric acid, monooctyl
ester, sodium salt (1:1)
Sulfuric acid
monododecyl ester
sodium salt (1:1)
sodium salt (1:1)
Yes 142-31-4 1 - 5
Yes 151-21-3 1 - 5
Yes 7681-52-9 1 - 5
Additional information
Actual concentrations withheld as trade secret in accordance with Canadian HPR
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact
Skin contact
Ingestion
Inhalation
Most important symptoms/effects,
acute and delayed
F. Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician
Rinse with plenty of water. Get medical attention immediately if irritation persists.
Rinse with plenty of water. Get medical attention if irritation develops and persists.
Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if
symptoms occur.
Move to fresh air. If symptoms persist, call a physician.
None under normal use conditions.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, CO 2, alcohol-resistant foam or water spray.
Unsuitable Extinguishing Media
Special hazard
None.
None known.
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Special protective equipment for
fire-fighters
Specific hazards arising from the
chemical
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Advice for emergency responders
Methods and materials for containment and cleaning up
Methods for containment
Methods for cleaning up
Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Use personal protective equipment as required.
Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal.
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible products
Use personal protective equipment as required. Keep container closed when not in use.
Never return spills in original containers for re-use. Keep out of the reach of children.
Keep containers tightly closed in a dry, cool and well-ventilated place. Store in corrosive
resistant container.
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:
No exposure limits noted for ingredient(s).
Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction
Personal Protective Equipment
Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
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Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of inadequate ventilation wear respiratory protection
Revision Date: 14-May-2018
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C
Appearance
Odor
Odor threshold
Property Values Note
pH value
Melting Point / Freezing Point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower Flammability Limit
Vapor pressure
Vapor density
Relative density
Water solubility
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Viscosity
Oxidizing properties
VOC Content (%)
Liquid
Clear
Scented
No information available
12.6 - 13.4
Not available Not available. This property is not relevant for
the safety and classification of this product
No information available
> 93.3 °C / > 200 °F Does not sustain combustion.
Not available Not available. This property is not relevant for
the safety and classification of this product
Not available Not applicable. This property is not relevant
for liquid product forms
No information available
No information available
No information available Not available. This property is not relevant for
the safety and classification of this product
Not available Not available. This property is not relevant for
the safety and classification of this product
1.045
100%
No information available Not available. This property is not relevant for
the safety and classification of this product
Not available Not available. This property is not relevant for
the safety and classification of this product .
Not available Not available. This property is not relevant for
the safety and classification of this product .
No information available < 10 cps
These substances will accelerate burning when involved in a fire.
Products comply with US state and federal regulations for VOC content in consumer
products.
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10. STABILITY AND REACTIVITY
Revision Date: 14-May-2018
Reactivity
Stability
Hazardous polymerization
Hazardous Reactions
Conditions to Avoid
Incompatible materials
Hazardous Decomposition Products
None under normal use conditions.
Stable under normal conditions.
Hazardous polymerization does not occur.
None under normal processing.
None under normal processing.
Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
None under normal use conditions.
11. TOXICOLOGICAL INFORMATION
Product Information
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Respiratory sensitization
Germ cell mutagenicity
Neurological Effects
Reproductive toxicity
Developmental toxicity
Teratogenicity
STOT - single exposure
STOT - repeated exposure
Target Organ Effects
Aspiration hazard
Carcinogenicity
No known effect.
No known effect.
No known effect.
Irritating to eyes.
No known effect.
No known effect.
Irritating to eyes.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
Component Information
Chemical Name CAS-No Oral LD50 Dermal LD50 Inhalation LC50
Sulfuric acid monododecyl ester
sodium salt (1:1)
Sodium hypochlorite 7681-52-9 - > 20000 mg/kg bw (OECD
151-21-3 977 mg/kg bw (OECD 401) > 2000 mg/kg bw (OECD
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic organisms.
Persistence and degradability
Bioaccumulative potential
No information available.
No information available.
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402)
402)
-
> 10.5 mg/L air (OECD
403)
15154199_PROF_NG - CometÒ Cleaner with Bleach - Ready
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Revision Date: 14-May-2018
Mobility
Other adverse effects
Waste treatment methods
Waste from Residues/Unused
Products
Contaminated packaging
California Hazardous Waste Codes
(non-household setting)
DOT
UN no
UN Proper shipping name
Description
Hazard Class
Packing Group
Reportable Quantity (RQ)
Special Provisions
Packaging Exceptions
Bulk packaging
Non-bulk Packaging
Emergency Response Guide
Number
DOT Comment
No information available.
No information available.
13. DISPOSAL CONSIDERATIONS
Products covered by this SDS, in their original form, when disposed as waste, are corrosive
hazardous waste, D002, according to Federal RCRA regulations (40 CFR 261). Disposal
should be in accordance with local, state and federal regulations.
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
331
14. TRANSPORT INFORMATION
UN1760
CORROSIVE LIQUID, N.O.S
UN1760, CORROSIVE LIQUIDS, N.O.S. (Sodium hypochlorite, Sodium hydroxide), 8, III
8
III
(Sodium hypochlorite: RQ (kg)= 45.40)
IB3, T7, TP1, TP28
154
241
203
154
The shipper is responsible for identifying any exemptions, including Limited Quantity, that
may apply based on package size
IMDG
UN Number
UN Proper shipping name
Description
Transport hazard class(es)
Packing Group
Special precautions for user
EmS-No
IMDG Comment
IATA
UN no
UN Proper shipping name
Description
Hazard Class
Packing Group
Special precautions for user
Comments
U.S. Federal Regulations
UN1760
CORROSIVE LIQUID, N.O.S.
UN1760, CORROSIVE LIQUID, N.O.S. (Sodium hypochlorite, Sodium hydroxide), 8, III
8
III
274, 223
F-A, S-B
The shipper is responsible for identifying any exemptions, including Limited Quantity, that
may apply based on package size.
UN1760
CORROSIVE LIQUID, N.O.S.
UN1760, CORROSIVE LIQUID, N.O.S. (Sodium hypochlorite, Sodium hydroxide), 8, III
8
III
A3, A803
. The shipper is responsible for identifying any exemptions, including Limited Quantity, that
may apply based on package size.
15. REGULATORY INFORMATION
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to Use
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):.
Chemical Name CAS-No Hazardous
Substances RQs
Extremely Hazardous
Substances RQs
CERCLA/SARA 302
TPQ
Sodium hypochlorite 7681-52-9 100 lb -
Sodium hydroxide 1310-73-2 1000 lb -
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42):.
Chemical Name CAS-No
Sodium hypochlorite 7681-52-9
Sodium hydroxide 1310-73-2
CWA - Reportable
Quantities
100 lb - - X
1000 lb - - X
CWA - Toxic
Pollutants
CWA - Priority
Pollutants
CWA - Hazardous
Substances
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
.
Chemical Name CAS-No New Jersey
Sodium hypochlorite 7681-52-9 X
Chemical Name CAS-No Massachusetts
Sodium hypochlorite 7681-52-9 X
Chemical Name CAS-No Pennsylvania
Sodium hypochlorite 7681-52-9 X
Sodium hydroxide 1310-73-2 X
Chemical Name CAS-No Rhode Island
Sodium hypochlorite 7681-52-9 X
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Canada
This product is in compliance with CEPA for import by P&G.
Legend
United States Toxic Substances Control Act Section 8(b) Inventory (TSCA)
CEPA - Canadian Environmental Protection Act
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16. OTHER INFORMATION
HMIS Ratings
Health hazard
Flammability
Physical hazard
NFPA Ratings
Health hazard
Flammability
Instability
2
1
0
2
1
0
Revision Date: 14-May-2018
Issuing Date:
Revision Date:
Disclaimer.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text
09-Jan-2015
14-May-2018
End of SDS
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