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SAFETY DATA SHEET
Issuing Date January 5, 2015
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox Commercial Solutions® Green Works® 97% Naturally Derived All-Purpose
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Address
Clorox Professional Products Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone numbe
Emergency Phone Numbers
Revision Date August 24, 2015
Cleaner - Original Scent
None
Multi-purpose spray cleaner
No information available
For Medical Emergencies call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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Revision Number 1
Clorox Commercial Solutions® Green Works® 97% Naturally Derived
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
2. HAZARDS IDENTIFICATION
Classification
This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
GHS Label elements, including precautionary statements
Emergency Overview
This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Appearance Clear, light green
Precautionary Statements - Prevention
None
Precautionary Statements - Response
None
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
1.9% of the mixture consists of ingredient(s) of unknown toxicity
Other information
May cause slight eye irritation.
Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product contains no substances that at their given concentrations are considered to be hazardous to health.
Physical State T hin liquid
Odor Fr esh Lemon
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Clorox Commercial Solutions® Green Works® 97% Naturally Derived
A
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye Contact
Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove
contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison
control center or doctor for further treatment advice.
Skin Contact
Rinse skin with plenty of water. If irritation persists, call a doctor.
Inhalation
Move to fresh air. If breathing problems develop, call a doctor.
Ingestion
Drink a glassful of water. Call a doctor or poison control center.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
May cause slight eye irritation.
Indication of any immediate medical attention and special treatment need ed
Notes to Physician
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Hazardous Combustion Products
Oxides of carbon.
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
s in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
No.
No.
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Clorox Commercial Solutions® Green Works® 97% Naturally Derived
A
A
All-Purpose Cleaner - Original Scent
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
void contact with eyes.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
See Section 12 for additional ecological information.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
bsorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
eyes, skin, and clothing. Do not eat, drink, or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed.
Incompatible Products
None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Appropriate engineering controls
Engineering Measures
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Skin and Body Protection
Respiratory Protection
Hygiene Measures
This product does not contain any ingredients with occupational exposure limits that are at
concentrations below their cut-off values/concentrations and that contribute to the hazard
classification of the product.
Showers
Eyewash stations
Ventilation systems
No special protective equipment required.
No special protective equipment required.
No protective equipment is needed under normal use conditions. If irritation is experienced,
ventilation and evacuation may be required.
Handle in accordance with good industrial hygiene and safety practice.
Revision Date August 24, 2015
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Clorox Commercial Solutions® Green Works® 97% Naturally Derived
V
V
V
V
All-Purpose Cleaner - Original Scent
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Appearance
Color
Thin liquid
Clear
Light green
Property
pH
Melting/freezing point
Boiling point / boiling range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower flammability limit
apor pressure
apor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive Properties
Oxidizing Properties
alues
11 - 11.5
No data available
No data available
>94°C
No data available
No data available
No data available
No data available
No data available
No data available
~1.0
Complete
No data available
No data available
No data available
No data available
No data available
No data available
Not explosive
No data available
Other Information
Softening Point
OC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None known.
Conditions to avoid
None known.
Incompatible materials
None known.
Hazardous Decomposition Products
None known.
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Odor
Odor Threshold
Remarks/ Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
Revision Date August 24, 2015
Fresh lemon
No information available
Clorox Commercial Solutions® Green Works® 97% Naturally Derived
A
A
X
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
Information on toxicological effects
Symptoms
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Ethanol
64-17-5
CGIH (American Conference of Governmental Industrial Hygienists)
3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
- Present
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
Aspiration Hazard
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document No information available.
.
Exposure to vapor or mist may irritate respiratory tract.
May cause slight irritation.
May cause slight irritation.
Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract.
May cause slight redness and tearing of eyes.
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
A3 Group 1 Known X
No information available.
No information available.
No information available.
Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in
long-term studies only when consumed as alcoholic beverage. Contains a known or
suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when
consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and
blood-forming system. May cause adverse liver effects. Repeated abuse can have
long-term health effects.
Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system.
Not an aspiration hazard.
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Clorox Commercial Solutions® Green Works® 97% Naturally Derived
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
12. ECOLOGICAL INFORMATION
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms
LC50: 12.0 - 16.0 mL/L (96 h
static) Oncorhynchus mykiss
Ethanol
64-17-5
LC50: 13400 - 15100 mg/L
(96 h flow-through)
Pimephales promelas
LC50: > 100 mg/L (96 h
static) Pimephales promelas
EC50 = 34634 mg/L 30 min
EC50 = 35470 mg/L 5 min
Daphnia Magna (Water
LC50: 9268 - 14221 mg/L (48
h ) Daphnia magna
EC50: 10800 mg/L (24 h )
Daphnia magna
EC50: 2 mg/L (48 h Static)
Daphnia magna
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Ethanol
64-17-5
-0.32
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local re gulations.
14. TRANSPORT INFORMATION
DOT
TDG
ICAO
IATA
IMDG/IMO
Not regulated.
Not regulated.
Not regulated.
Not regulated
Not regulated
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Flea)
Clorox Commercial Solutions® Green Works® 97% Naturally Derived
A
A
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
15. REGULATORY INFORMATION
Chemical Inventories
TSCA
DSL/NDSL
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regiona l, or state level
pertaining to releases of this material.
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental
hazard when it is ingested as an alcoholic beverage.
Chemical Name California Proposition 65
Ethanol
64-17-5
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Ethanol
64-17-5
International Regulations
Canada
WHMIS Hazard Class
Not controlled.
ll components of this product are either on the TSCA 8(b) Inventory or otherwise exempt
from listing.
ll components are on the DSL or NDSL.
No
No
No
No
No
Developmental
X
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Clorox Commercial Solutions® Green Works® 97% Naturally Derived
A
r
All-Purpose Cleaner - Original Scent
Revision Date August 24, 2015
16. OTHER INFORMATION
NFPA
HMIS
Prepared By
Health Hazard 0 Flammability 0
Health Hazard 0 Flammability 0
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Instability 0
Physical Hazard 0 Personal Protection -
Physical and Chemical Hazards -
Revision Date
ugust 24, 2015
Revision Note
Reference
General Disclaime
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the
date of its publication. The in formation given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal, and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision Section 9.
1123927/128987.001
End of Safety Data Sheet
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