SAFETY DATA SHEET
Issuing Date January 5, 2015
Revision Date New
Revision Number 0
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name
Clorox Commercial Solutions® Clorox® Disinfecting Spray
Other means of identification
EPA Registration Number
67619-21
Recommended use of the chemical and restrictions on use
Recommended Use
Aerosol disinfectant, sanitizer, and deodorizer
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Address
Clorox Professional Products Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
For Medical Emergencies call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
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2. HAZARDS IDENTIFICATION
Classification
This mixture is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Eye damage/irritation
Category 2A
Germ cell mutagenicity
Category 1B
Carcinogenicity
Category 1B
Flammable aerosols
Category 2
GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Danger
Hazard statements
Causes serious eye irritation
May cause genetic effects
May cause cancer
Flammable aerosol
Appearance Clear, colorless
Physical State Thin liquid
Odor Green, fresh, fruity
Precautionary Statements - Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wear eye protection such as safety glasses.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Pressurized container: Do not pierce or burn, even after use.
Do not spray on an open flame or other ignition source.
Wash hands and any exposed skin thoroughly after handling.
Precautionary Statements - Response
If exposed or concerned: Get medical attention.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Precautionary Statements - Disposal
Dispose of contents/container in accordance with all applicable federal, state, and local regulations.
Hazards not otherwise classified (HNOC)
0.5% of the mixture consists of ingredient(s) of unknown toxicity
Unknown Toxicity
None
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Other information
Very toxic to aquatic life with long lasting effects.
Interactions with Other Chemicals
Can react with strong oxidizers, inorganic acids, and halogens.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS-No
Weight %
Trade Secret
Ethanol
64-17-5
50 - 70
*
Isobutane
75-28-5
5 - 10
*
Propane
74-98-6
1 - 5
*
Sodium nitrite
7632-00-0
<0.2
*
n-Alkyl (40% C12, 50% C14, 10% C16) dimethyl
benzyl ammonium chloride
68424-85-1
0.1 - 0.3
*
Octyl decyl dimethyl ammonium chloride
32426-11-2
0.1 - 0.3 * * The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye Contact
Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control
center or doctor for treatment advice.
Skin Contact
Wash skin with soap and water. If irritation persists, call a doctor.
Inhalation
Move to fresh air. If breathing is affected, call a doctor.
Ingestion
Drink a glassful of water. Call a doctor or poison control center.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms/Effects
May cause substantial eye irritation. Inhalation of high concentrations may cause irritation of
the respiratory tract, headaches, dizziness, nausea, vomiting, and malaise.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, carbon dioxide (CO2), foam, or water spray.
Unsuitable Extinguishing Media
Do not extinguish a leaking gas fire unless leak can be stopped.
Specific Hazards Arising from the Chemical
Containers may rupture at temperatures greater than 50C.
NFPA Aerosol Classification: Level 1
Explosion Data
Sensitivity to Mechanical Impact
None
Sensitivity to Static Discharge
Yes.
Protective Equipment and Precautions for Firefighters
Containers may rupture at temperatures greater than 50C. Cool exposed containers to avoid potential bursting or venting. Use
equipment or shielding to protect personnel from bursting containers. As in any fire, wear self-contained breathing apparatus
pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Avoid contact with eyes, skin, and clothing. Wear respiratory protection for large spills.
Other Information
Eliminate all potential sources of ignition, and ventilate area. Take precautionary measures
against static discharge. Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
Prevent entry into waterways, sewers, basements, and confined areas.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so. Keep out of drains, sewers, ditches, and
waterways.
Methods for Cleaning Up
Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
eyes, skin, and clothing. Avoid breathing vapors. Contents under pressure. Do not
puncture or incinerate containers. Keep away from heat, sparks, open flames, and hot
surfaces. Do not eat, drink, or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Store in accordance with NFPA 30B for Level 1 aerosols. Do not store at temperatures above
50C. Keep containers in a dry, cool, and well-ventilated place. Keep away from heat and
ignition sources. Protect from sunlight.
Incompatible Products
Strong oxidizers, inorganic acids, and halogens.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Ethanol
64-17-5
STEL: 1000 ppm
TWA: 1000 ppm
TWA: 1900 mg/m3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
TWA: 1900 mg/m3
Isobutane
75-28-5
STEL: 1000 ppm
None
TWA: 800 ppm
TWA: 1900 mg/m3
Propane
74-98-6
TWA: 1000 ppm
TWA: 1000 ppm
TWA: 1800 mg/m3
IDLH: 2100 ppm
TWA: 1000 ppm
TWA: 1800 mg/m3
Sodium nitrite
7632-00-0
None
None
None
n-Alkyl (40% C12, 50% C14, 10% C16) dimethyl
benzyl ammonium chloride
68424-85-1
None
None
None
Octyl decyl dimethyl ammonium chloride
32426-11-2
None
None
None
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Wear safety glasses.
Skin and Body Protection
Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
protection should be worn. Positive-pressure supplied air respirators may be required for high
airborne contaminant concentrations. Respiratory protection must be provided in accordance
with current local regulations.
Hygiene Measures
Do not eat, drink, or smoke when using this product. Wash hands with soap and water after
use.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Thin liquid
Appearance
Clear
Odor
Green, fresh, fruity
Color
Colorless
Odor Threshold
No information available
Property
Values
Remarks/ Method
pH
9 - 11 (liquid)
None known
Melting/freezing point
No data available
None known
Boiling Point/Range
No data available
None known
Flash Point
17.5°C (liquid, closed cup)
None known
Flame extension
15 inches (38 cm) without flashback
Evaporation rate
No data available
None known
Flammability (solid, gas)
No data available
None known
Flammability Limits in Air
Upper flammability limit
No data available
None known
Lower flammability limit
No data available
None known
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Specific Gravity
~0.86 (liquid)
None known
Water Solubility
Soluble in water.
None known
Solubility in other solvents
No data available
None known
Partition coefficient: n-octanol/water
No data available
None known
Autoignition temperature
No data available
None known
Decomposition temperature
No data available
None known
Kinematic viscosity
No data available
None known
Dynamic viscosity
No data available
None known
Explosive Properties
Not explosive
Oxidizing Properties
No data available
Other Information
Softening Point
No data available
VOC Content (%)
No data available
Particle Size
No data available
Particle Size Distribution
No data available
10. STABILITY AND REACTIVITY
Reactivity
Can react with strong oxidizers, inorganic acids, and halogens
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Do not store at temperatures above 50C. Keep away from heat, sparks, open flames, and hot surfaces.
Incompatible materials
Strong oxidizers, inorganic acids, and halogens
Hazardous Decomposition Products
None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Inhalation of high concentrations may cause irritation of the respiratory tract, headaches,
dizziness, nausea, vomiting, and malaise.
Eye Contact
May cause substantial eye irritation.
Skin Contact
Prolonged contact may cause slight irritation.
Ingestion
Ingestion may cause central nervous system depression, gastrointestinal irritation, nausea,
vomiting, and diarrhea.
Component Information
Chemical Name
LD50 Oral
LD50 Dermal
LC50 Inhalation
Ethanol
64-17-5
-
-
124.7 mg/L (Rat) 4 h
Isobutane
75-28-5
-
-
658 mg/L (Rat) 4 h
Propane
74-98-6
-
-
658 mg/L (Rat) 4 h
Sodium nitrite
7632-00-0
85 mg/kg (Rat)
-
5.5 mg/L (Rat) 4 h
Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
No information available.
Mutagenic Effects
No information available.
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
Chemical Name
ACGIH
IARC
NTP
OSHA
Ethanol
64-17-5
A3
Group 1
Known
X
Sodium nitrite
7632-00-0
Group 2A
X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity
No information available
STOT - single exposure
No information available.
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11. TOXICOLOGICAL INFORMATION
STOT - repeated exposure
No information available.
Chronic Toxicity
Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in
long-term studies only when consumed as alcoholic beverage. Sodium nitrite produced
stomach tumors in female mice when fed exaggerated doses. Contains a known or
suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when
consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and
blood-forming system. May cause adverse liver effects. Repeated abuse can have
long-term health effects.
Target Organ Effects
Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system.
Aspiration Hazard
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
14.2 g/kg
ATEmix (inhalation-dust/mist)
215 mg/L
12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic life with long lasting effects.
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name
Log Pow
Ethanol
64-17-5
-0.32
Propane
74-98-6
2.3
Sodium nitrite
7632-00-0
-3.7
Other Adverse Effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Dispose of in accordance with all applicable federal, state, and local regulations.
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14. TRANSPORT INFORMATION
DOT
Limited quantity.
TDG
UN-No
UN1950
Proper Shipping Name
AEROSOLS
Hazard Class
2.1
Description
UN1950, AEROSOLS, 2.1
ICAO
UN-No
UN1950
Proper Shipping Name
AEROSOLS
Hazard Class
2.1
Description
UN1950, AEROSOLS, 2.1
IATA
UN-No
UN1950
Proper Shipping Name
AEROSOLS, FLAMMABLE
Hazard Class
2.1
Description
UN1950, AEROSOLS, FLAMMABLE, 2.1
IMDG/IMO
UN-No
UN1950
Proper Shipping Name
AEROSOLS
Hazard Class
2.1
EMs No.
F-D, S-U
Description
UN1950, AEROSOLS, 2.1
15. REGULATORY INFORMATION
Chemical Inventories
TSCA
All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from
listing.
DSL/NDSL
All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains the following
chemical that is subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name
CAS-No
Weight %
SARA 313
Threshold Values %
Sodium nitrite
7632-00-0
7632-00-0
0.1 - 1
1.0
SARA 311/312 Hazard Categories
Acute Health Hazard
Yes
Chronic Health Hazard
Yes
Fire Hazard
Yes
Sudden Release of Pressure Hazard
Yes
Reactive Hazard
No
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Clean Water Act
This product contains the following substance that is regulated as a pollutant pursuant to the Clean Water Act (40 CFR 122.21 and
40 CFR 122.42).
Chemical Name
CWA - Reportable
Quantities
CWA - Toxic Pollutants
CWA - Priority Pollutants
CWA - Hazardous
Substances
Sodium nitrite
7632-00-0
100 lb.
X
CERCLA
This material, as supplied, contain the following substance regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization
Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of
this material.
Chemical Name
Hazardous Substances RQs
Extremely Hazardous Substances
RQs
RQ
Sodium nitrite
7632-00-0
100 lb
RQ 100 lb final RQ
RQ 45.4 kg final RQ
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING: Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Wear protective eye wear
(safety glasses). Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Wash
thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse. If skin contact with
product occurs, wash thoroughly with soap and water, especially prior to food handling and preparation. Remove or cover
aquariums and cages before use.
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental
hazard when it is ingested as an alcoholic beverage.
Chemical Name
California Proposition 65
Ethanol
64-17-5
Developmental
U.S. State Right-to-Know Regulations
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
Ethanol
64-17-5
X
Isobutane
75-28-5
X X X
Propane
74-98-6
X X X
Sodium nitrite
7632-00-0
X X X X
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International Regulations
Canada
WHMIS Hazard Class
D2A Very toxic materials
D2B Toxic materials
A Compressed gases
B5 Flammable aerosol
16. OTHER INFORMATION
NFPA
Health Hazard 1
Flammability 3
Instability 0
Physical and Chemical
Hazards -
HMIS
Health Hazard 1*
Flammability 3
Physical Hazard 0
Personal Protection A
*Indicates a chronic health hazard
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Preparation/Revision Date
January 5, 2015
Revision Date
New
Revision Note
Reference
New
CLX161939-001/161939.001
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process, unless specified in the text
End of Safety Data Sheet
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