SAFETY DATA SHEET
Issuing Date June 2, 2015
Revision Date New
Revision Number 0
Page 1 / 10
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name
Clorox Commercial Solutions® Odor Defense™ Aerosol
Other means of identification
Synonyms
None
Recommended use of the chemical and restrictions on use
Recommended Use
Air Freshener
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Address
Clorox Professional Products Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
For Medical Emergencies call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 2 / 10
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Serious eye damage/eye irritation
Category 2A
Flammable liquids
Category 2
Gases under pressure
Compressed gas
GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Danger
Hazard Statements
Causes serious eye irritation
Highly flammable liquid and vapor
Contains gas under pressure; may explode if heated
Appearance Clear
Physical State Thin liquid
Odor Slightly floral
Precautionary Statements - Prevention
Wear eye protection such as safety glasses.
Use personal protective equipment as required
Keep away from heat, sparks, and open flames. No smoking
Keep container tightly closed.
Use explosion-proof electrical equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Precautionary Statements - Response
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical attention.
In case of fire: Use dry chemical, carbon dioxide, foam, or water spray to extinguish.
Precautionary Statements - Storage
Store in a cool, well-ventilated place.
Precautionary Statements - Disposal
Dispose of in accordance with all applicable federal, state, and local regulations.
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
Not applicable
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 3 / 10
Other information
Not applicable
Interactions with Other Chemicals
None known.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS No.
Weight %
Trade Secret
Propane
74-98-6
10-20
*
Acetone
67-64-1
60-80 * *The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.
Skin Contact
Take off contaminated clothing. Wash with plenty of water. Get medical attention if
irritation develops and persists.
Inhalation
Move to fresh air. If breathing is affected, get medical advice/attention.
Ingestion
Drink a glassful of water. Call a poison control center or doctor immediately. DO NOT
induce vomiting unless told to do so by a poison control center or doctor.
Protection of First-aiders
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Stinging and irritation of eyes.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 4 / 10
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available.
Explosion Data
Sensitivity to Mechanical Impact
None.
Sensitivity to Static Discharge
None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Avoid contact with skin, eyes, or clothing. Use personal protective equipment as required.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
Prevent further leakage or spillage if safe to do so. See Section 12 for ecological
information.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink, or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Products
None known.
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 5 / 10
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Acetone
67-64-01
TWA: 500 ppm
STEL: 750 ppm
STEL: 1000 ppm
2400 mg/m
3
TWA: 750 ppm
1800 mg/m
3
250 ppm
590 mg/m3
Propane
74-98-6
1000 ppm
1000 ppm
1000 ppm
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
If splashes are likely to occur: Wear goggles or safety glasses with side shields.
Skin and Body Protection
Wear rubber of neoprene gloves and protective clothing.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
Hygiene Measures
Wash hands after direct contact. Remove and wash contaminated clothing before re-use.
Do not eat, drink, or smoke when using this product.
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 6 / 10
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Thin liquid
Appearance
Clear
Odor
Slightly floral
Color
Clear solution
Odor Threshold
No information available
Property
Values
Remarks/ Method
pH
10 None known
pH (diluted solution - 1:64)
10
Melting / freezing point
No data available
None known
Boiling point / boiling range
No data available
None known
Flash Point
<23°C (closed cup)
None known
Evaporation Rate
No data available
None known
Flammability (solid, gas)
No data available
None known
Flammability Limit in Air
Upper flammability limit
No data available
None known
Lower flammability limit
No data available
None known
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Specific Gravity
0.791
None known
Water Solubility
Soluble
None known
Solubility in other solvents
No data available
None known
Partition coefficient: n-octanol/water
No data available
None known
Autoignition temperature
No data available
None known
Decomposition temperature
No data available
None known
Kinematic viscosity
No data available
None known
Dynamic viscosity
No data available
None known
Explosive Properties
Not explosive
Oxidizing Properties
No data available
Other Information
Softening Point
No data available
VOC Content (%)
No data available
Particle Size
No data available
Particle Size Distribution
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known.
Incompatible materials
None known.
Hazardous Decomposition Products
None known.
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 7 / 10
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Exposure to vapor or mist may irritate respiratory tract.
Eye Contact
May cause eye irritation.
Skin Contact
May cause skin irritation.
Ingestion
Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea,
vomiting, and diarrhea.
Component Information
Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
Acetone
67-64-1
- - -
Propane
74-98-6
- - -
Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes. May cause skin redness.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
No information available.
Mutagenic Effects
No information available.
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen. .
Chemical Name
ACGIH
IARC
NTP
OSHA
Acetone
67-64-1
N/A
N/A
N/A
N/A
Propane
74-98-6
N/A
N/A
N/A
N/A
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity
No information available.
STOT - single exposure
No information available.
STOT - repeated exposure
No information available.
Chronic Toxicity
No information available.
Target Organ Effects
Isobutane and propane did not elicit target organ toxicity at 9000 ppm and 12000 ppm,
respectively.
Aspiration Hazard
No information available.
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 8 / 10
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (inhalation-dust/mist)
Not available
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Chemical Name
Toxicity to Algae
Toxicity to Fish
Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Acetone
67-64-1
-
LC50: 5,540 mg/L (96 h)
Oncorhynchus mykiss
LC50: 8,800 mg/L (48 h)
Daphnia magna
-
LC50: 8,800 mg/L (48 h)
Daphnia magna
Propane
74-98-6
-
- - -
Persistence and Degradability
No information available.
Bioaccumulation
No data available.
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT
Limited quantity
TDG
UN Number
Proper shipping name
Hazard class
Description
UN1950
AEROSOLS
2.1
UN1950, AEROSOLS 2.1
IATA
UN Number
Proper shipping name
Hazard class
Description
UN1950
AEROSOLS
2.1
UN1950, AEROSOLS 2.1
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 9 / 10
IMDG/IMO
UN Number
Proper shipping name
Hazard class
Description
UN1950
AEROSOLS
2.1
UN1950, AEROSOLS 2.1
15. REGULATORY INFORMATION
International Inventories
TSCA
All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt
from listing.
DSL/NDSL
All components are on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard
Yes
Chronic Health Hazard
No
Fire Hazard
Yes
Sudden Release of Pressure Hazard
Yes
Reactive Hazard
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
This product does not contain any Prop 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name
New Jersey
Massachusetts
Pennsylvania
Rhode Island
Illinois
Acetone
67-64-1
x
x
x - -
Propane
74-98-6
x
x
x - -
Clorox Commercial Solutions® Odor Defense™ Aerosol
Revision Number 0
Page 10 / 10
International Regulations
Canada
WHMIS Hazard Class
D2B - Toxic materials
16. OTHER INFORMATION
NFPA
Health Hazards 2
Flammability 2
Instability 0
Physical and Chemical Hazards -
HMIS
Health Hazards 2
Flammability 2
Physical Hazard 0
Personal Protection B
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Preparation/Revision Date
January 5, 2015
Revision Note
Reference
New
CLX124769-001/124769.001
General Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
Loading...