Extremely flammable aerosol. May be fatal if swallowed and enters airways. May cause an allergic
skin reaction. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid
breathing gas. Contaminated work clothing must not be allowed out of the workplace. Avoid
release to the environment. Wear protective gloves.
If swallowed: Immediately call a poison center/doctor. If on skin: Wash with plenty of water.
Specific treatment (see this label). Do NOT induce vomiting. If skin irritation or rash occurs: Get
medical advice/attention. Wash contaminated clothing before reuse. Collect spillage.
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
ingredients
SDS U
S
1 / 10
Page 2
Chemical name Common name and synonym
Distillates (Petroleum),
Hydrotreated Light
Carbon Dioxide
Permethrin
Piperonyl Butoxide
s
CAS number %
64742-47-8
124-38-9
52645-53-1
51-03-6
Other components below reportable levels 0.01 - 0.1
#: This substance has workplace exposure limit(s).
vPvB: very persistent and very bioaccumulative substance.
PBT: persistent, bioaccumulative and toxic substance.
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4.
First-aid measures
Inhalation
If inhalation of gas/fume/vapor/dust/mist from the material is excessive (air concentration is greater
than the TLV or health effects are noticed), immediately remove the affected person(s) to fresh air.
Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the
substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Get medical attention immediately.
Skin contact
Remove and isolate contaminated clothing and shoes. Get medical attention immediately. Get
medical attention if irritation develops or persists. For minor skin contact, avoid spreading material
on unaffected skin. Wash clothing separately before reuse.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Get medical attention if irritation develops or persists. Continue rinsing.
Get medical attention immediately.
Ingestion
Most
important
symptoms/effects, acute
delayed
Indication of
medical
treatment
General
immediate
attention and
needed
information
special
and
Get medical attention immediately. No need for first aid is anticipated if material is swallowed.
Dermatitis. Aspiration may cause pulmonary edema and pneumonitis. Rash. May cause an allergic
skin reaction.
Provide general supportive measures and treat symptomatically. Oxygen, if needed. Keep victim
warm. Keep victim under observation. Symptoms may be delayed.
Take off contaminated clothing and shoes immediately. Immediate medical attention is required. If
you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Keep victim warm. Wash contaminated clothing
5.
Fire-fighting measures
Suitable
extinguishing media
Unsuitable extinguishing
media
Specific hazards
the
chemical
Special
and
protective equipment
precautions for
arising from
firefighters
Fire-fighting
equipment/instructions
before reuse.
Large Fires: Powder. Alcohol resistant foam. Water spray, fog or regular foam.
Small Fires: Dry chemicals. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear full
protective clothing including self contained breathing apparatus.
In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective
equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. Move containers from fire area if you can do it without risk. Move
containers from fire area if you can do so without risk. Cool containers exposed to heat with water
spray and remove container, if no risk is involved. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or
monitor nozzles, if possible. If not, withdraw and let fire burn out. Some of these materials, if
spilled, may evaporate leaving a flammable residue.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. Cool containers exposed to flames with
water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes.
Consider initial downwind evacuation for at least 500 meters (1/3 mile). Keep unnecessary
personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear
appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. This material is classified as a water pollutant under the Clean Water
Act and should be prevented from contaminating soil or from entering sewage and drainage
systems which lead to waterways. Stop leak if you can do so without risk. Move the cylinder to a
safe and open area if the leak is irreparable. Use water spray to reduce vapors or divert vapor
cloud drift. Isolate area until gas has dispersed. Use a non-combustible material like vermiculite,
sand or earth to soak up the product and place into a container for later disposal. Following
product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS. After removal flush
contaminated area thoroughly with water. This material and its container must be disposed of as
hazardous waste.
Environmental precautions
Avoid release to the environment. Refer to special instructions/safety data sheets. Inform
appropriate managerial or supervisory personnel of all environmental releases. Prevent further
leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water
7.
Handling and
Precautions for safe
storage
handling
courses or onto the ground.
Vapors may form explosive mixtures with air. Pressurized container: Do not pierce or burn, even
after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any
other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry.
Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources
of ignition. All equipment used when handling the product must be grounded. Do not re-use empty
containers. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and
clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in
area provided with appropriate exhaust ventilation. Wear appropriate personal protective
equipment. Wash thoroughly after handling. Avoid release to the environment. Use appropriate
container to avoid environmental contamination. Observe good industrial hygiene practices.
Conditions for safe
including any
incompatibilities
storage,
Level 3 Aerosol.
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Store away from incompatible materials (see Section
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
Hazards
Type
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as
Eye/face
Skin
protection
Hand
protection
protection
Other
personal protective equipment
Face shield is recommended. Face-shield. Avoid contact with eyes.
Wear appropriate chemical resistant gloves.
Avoid contact with the skin. Wear chemical protective equipment that is specifically recommended
by the manufacturer. Use of an impervious apron is recommended. It may provide little or no
thermal protection.
Skin
protection
Respiratory protection
Thermal hazards
General
hygiene
considerations
If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator.
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Avoid contact with
clothing. Keep away from food and drink. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants. Contaminated work
9.
Physical and
Appearance
chemical properties
Physical state
Color
Odor
Odor
threshold
pH
Melting
Initial
range
point/freezing point
boiling point and
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or
Flammability limit (%)
Flammability limit (%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor
pressure
Vapor
density
Relative
density
Solubility(ies)
boiling
lower
upper
clothing should not be allowed out of the workplace.
The product is stable and non-reactive under normal conditions of use, storage and transport.
Risk of explosion. Risk of ignition. Material is stable under normal conditions.
Hazardous polymerization does not occur.
Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible
materials.
None known.
May include oxides of nitrogen. May include oxides of phosphorus. No hazardous decomposition
products are known.
exposure
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Prolonged inhalation may be harmful.
May cause an allergic skin reaction.
Direct contact with eyes may cause temporary irritation.
Dermatitis. Aspiration may cause pulmonary edema and pneumonitis. Rash. May cause an
allergic skin reaction.
Acute LD50: 1969 mg/kg, Rat, Dermal
Acute LC50: 5 mg/l/4h, Rat, Inhalation
May be fatal if swallowed and enters airways. May cause an allergic skin reaction.
* Estimates for product may be based on additional component data not shown.
Skin
corrosion/irritation
Serious eye
irritation
damage/eye
Respiratory or skin
sensitization
Respiratory sensitization
Skin
sensitization
Germ cell
mutagenicity
Carcinogenicity
IARC
Monographs. Overall
Permethrin (CAS 52645-53-1) 3 Not classifiable as to carcinogenicity to humans.
Piperonyl Butoxide (CAS 51-03-6) 3 Not classifiable as to carcinogenicity to humans.
Direct contact with eyes may cause temporary irritation.
Not available.
May cause an allergic skin reaction.
Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria.
Not expected to be hazardous by WHMIS criteria. This product is not considered to be a
carcinogen by IARC, ACGIH, NTP, or OSHA.
Evaluation of
Carcinogenicity
Substances (29 CFR 1910.1001-1050)
Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria.
Not classified.
Not classified.
May be fatal if swallowed and enters airways.
Hazardous by OSHA criteria. Prolonged inhalation may be harmful. Prolonged or repeated
exposure may cause lung injury. Prolonged exposure may cause chronic effects. Not expected to
be hazardous by WHMIS criteria.
This product has no known adverse effect on human health.
LC50: 46.61 mg/L, Fish, 96.00 Hours
Very toxic to aquatic life with long lasting effects.
Special
Packaging exceptions
Packaging non
Packaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
UN
number
UN proper
Transport hazard
Class
Subsidiary risk
Label(s)
Packing
degradability
residues /
shipping name
group
precautions for user
provisions
shipping name
group
unused
class(es)
bulk
class(es)
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Kow)
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. This material and its container must be
disposed of as hazardous waste. Must be incinerated in a suitable incineration plant holding a
permit delivered by the competent authorities. Do not allow this material to drain into sewers/water
supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. After
recovery of solvent dispose of residue as hazardous waste. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
UN1950
Aerosols, flammable, (each not exceeding 1 L capacity)
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable
2.1
-
2.1
Not applicable.
SDS U
7 / 10
S
Page 8
Environmental hazards
ERG
Special
Other
Packaging Exceptions
IMDG
UN
UN proper
Transport hazard
group
hazards
EmS
Special precautions for user
Packaging Exceptions
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
Code
precautions for user
information
Passenger and
aircraft
Cargo
aircraft only
number
Class
Subsidiary risk
Label(s)
Marine
shipping name
Packing
Environmental
pollutant
cargo
class(es)
Yes
10L
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
LTD QTY
UN1950
AEROSOLS
2.1
-
2.1
Not applicable.
Yes
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
LTD QTY
Not applicable.
Pesticides are exempt from TSCA. This product is a "Hazardous Chemical" as defined by the
OSHA Hazard Communication Standard, 29 CFR 1910.1200.
CERCLA/SARA Hazardous Substances - Not applicable.
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Australian Inventory of Chemical Substances (AICS)
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
No
% by wt.
0.1 - 1
0.1 - 1
On inventory (yes/no
)*
No
No
SDS U
S
9 / 10
Page 10
Country(s) or region
China
Europe
Inventory name
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of Existing Commercial Chemical
On inventory (yes/no
Substances (EINECS)
Europe
Japan
Korea
New Zealand
Philippines
European List of Notified Chemical Substances (ELINCS)
No
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
New Zealand Inventory
No
No
Philippine Inventory of Chemicals and Chemical Substances
No
(PICCS)
United States & Puerto Rico
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other
Issue date
Revision date
Version #
Further information
Disclaimer
information, including date of
Toxic Substances Control Act (TSCA) Inventory
preparation or last
10-23-2014
01-02-2015
revision
02
HMIS® is a registered trade and service mark of the NPCA.
We cannot anticipate all conditions under which this information and its product, or the products of
other manufacturers in combination with its product, may be used. It is the user’s responsibility to
ensure safe conditions for handling, storage and disposal of the product, and to assume liability for
loss, injury, damage or expense due to improper use. The information in the sheet was written
based on the best knowledge and experience currently available. The information provided in this
Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not
be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
Revision Information
Product and Company Identification: Alternate Trade Names