Chemtronics NR ES1613 User Manual

Page 1
New & Improved Pow-R-Wash™ NR
Pow-R-Wash™ NR
1613
ES1613
Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152
Chemtrec - 1-800-424-9300 or collect 703-527-3887 24/7
Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152
7/25/2013.
Material Safety Data Sheet
Product name
Supplier
Trade name
Manufacturer
Code
MSDS #
Validation date
Print date
In case of emergency
1. Product and company identification
New & Improved Pow-R-Wash™ NR
:
:
:
:
: :::
:
Product type
:
Aerosol.
7/25/2013.
Signal word
2. Hazards identification
Potential acute health effects
Harmful by inhalation. At very high concentrations, can displace the normal air and cause suffocation from lack of oxygen. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Moderately irritating to eyes.
Harmful if swallowed.
Slightly irritating to the skin.
Eyes
Skin
Inhalation
Ingestion
Physical state
Liquid. [Aerosol.]
CAUTION!
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.
:
:::::
Odor
:
Characteristic.
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential chronic health effects
Carcinogenicity
:
Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure.
Chronic effects
:
Contains material that may cause target organ damage, based on animal data.
Color
:
Colorless.
Emergency overview
Hazard statements
:
Precautionary measures
:
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe vapor or mist. Do not ingest. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Use personal protective equipment as required. Wash thoroughly after handling.
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2. Hazards identification
See toxicological information (Section 11)
Medical conditions aggravated by over­exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product.
:
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
No known significant effects or critical hazards.
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Over-exposure signs/symptoms
Ingestion
:
No specific data.
Skin
:
Adverse symptoms may include the following: irritation redness
Eyes
:
Adverse symptoms may include the following: irritation watering redness
Inhalation
:
Adverse symptoms may include the following: respiratory tract irritation coughing
Target organs
:
Contains material which may cause damage to the following organs: lungs, the nervous system, the reproductive system, liver, gastrointestinal tract, cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. 1-bromopropane
106-94-5
65 - 75
norflurane
811-97-2
5 - 25
propan-1-ol
71-23-8
1 - 5
Carbon dioxide
124-38-9
1 - 5
1,2-epoxybutane
106-88-7
0.1 - 1
3. Composition/information on ingredients
Name
CAS number
%
1-bromopropane
106-94-5
65 - 75
norflurane
811-97-2
5 - 25
propan-1-ol
71-23-8
1 - 5
Carbon dioxide
124-38-9
1 - 5
1,2-epoxybutane
106-88-7
0.1 - 1
Name
CAS number
%
United States
Canada
Name
CAS number
%
propan-1-ol
71-23-8
UN1993
1 - 5
800 ppm
230
-
1-bromopropane
106-94-5
Not available.
65 - 75
-020-
Carbon dioxide
124-38-9
Not available.
1 - 5
40000 ppm
000
-
IDLH
HFR
Special
Classification
UN number Mexico
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3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
4. First aid measures
Eye contact
Skin contact
Inhalation Ingestion
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Notes to physician
:
:
: : :
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Use an extinguishing agent suitable for the surrounding fire.
5. Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
In a fire or if heated, a pressure increase will occur and the container may burst. Bursting aerosol containers may be propelled from a fire at high speed.
Special protective equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
Special exposure hazards
:
None known.
Suitable
:
Not suitable
:
Hazardous thermal decomposition products
:
Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides
Flammability of the product
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions
6. Accidental release measures
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Personal precautions
:
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6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods for cleaning up
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Empty containers retain product residue and can be hazardous.
7. Handling and storage
Handling
Storage
:
:
1-bromopropane
ACGIH TLV (United States, 3/2012).
TWA: 10 ppm 8 hours.
norflurane
AIHA WEEL (United States, 10/2011).
TWA: 1000 ppm 8 hours.
propan-1-ol
ACGIH TLV (United States, 3/2012).
TWA: 100 ppm 8 hours.
NIOSH REL (United States, 1/2013). Absorbed through skin.
STEL: 625 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 500 mg/m³ 10 hours. TWA: 200 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 500 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 625 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 500 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
Carbon dioxide
ACGIH TLV (United States, 3/2012). Oxygen Depletion [Asphyxiant].
STEL: 54000 mg/m³ 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m³ 8 hours.
8. Exposure controls/personal protection
United States
Ingredient
Exposure limits
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8. Exposure controls/personal protection
TWA: 5000 ppm 8 hours.
NIOSH REL (United States, 1/2013).
STEL: 54000 mg/m³ 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 9000 mg/m³ 10 hours. TWA: 5000 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 9000 mg/m³ 8 hours. TWA: 5000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 54000 mg/m³ 15 minutes. STEL: 30000 ppm 15 minutes. TWA: 18000 mg/m³ 8 hours. TWA: 10000 ppm 8 hours.
1,2-epoxybutane
AIHA WEEL (United States, 10/2011).
TWA: 2 ppm 8 hours.
Consult local authorities for acceptable exposure limits.
1-bromopropane
ACGIH TLV (United States, 3/2012).
TWA: 10 ppm 8 hours.
propan-1-ol
NOM-010-STPS (Mexico, 9/2000). Absorbed through skin.
LMPE-CT: 625 mg/m³ 15 minutes. LMPE-CT: 250 ppm 15 minutes. LMPE-PPT: 500 mg/m³ 8 hours. LMPE-PPT: 200 ppm 8 hours.
Carbon dioxide
NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 27000 mg/m³ 15 minutes. LMPE-CT: 15000 ppm 15 minutes. LMPE-PPT: 9000 mg/m³ 8 hours. LMPE-PPT: 5000 ppm 8 hours.
Canada
Mexico
Ingredient
Exposure limits
Occupational exposure limits
Ingredient
List name
ppm
mg/m³Other
ppm
mg/m³Other
ppm
mg/m³Other
Notations
1-bromopropane
US ACGIH 3/2012
10--------
BC 4/2012
10--------
ON 1/2013
10--------
Carbon dioxide
US ACGIH 3/2012
5000
9000
-
30000
54000
----[2]
AB 4/2009
5000
9000
-
30000
54000
----BC 4/2012
5000--
15000
-----
ON 1/2013
5000
9000
-
30000
54000
---
-
QC 12/2012
5000
9000
-
30000
54000
---
-
norflurane
US AIHA 10/2011
1000--------
propan-1-ol
US ACGIH 3/2012
100--------
AB 4/2009
200
492-400
984----
[3]
BC 4/2012
100--------
ON 1/2013
100--------
QC 12/2012
200
492-250
614----
[1]
1,2-epoxybutane
US AIHA 10/2011
2--------
TWA (8 hours)
STEL (15 mins)
Ceiling
[1]Absorbed through skin. [2]Oxygen Depletion [Asphyxiant] [3]Skin sensitization
Occupational exposure limits
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8. Exposure controls/personal protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Personal protection
Eyes Skin
Respiratory
: :
:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Hands
:
Engineering measures
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Recommended monitoring procedures
:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
70°C (158°F)
Liquid. [Aerosol.]
1.35
14.8 kPa (110.8 mm Hg) [room temperature]
Characteristic.
Colorless.
Boiling/condensation point
>1 (butyl acetate = 1)
9. Physical and chemical properties
Physical state
Relative density
Vapor pressure
Evaporation rate
Odor
Color::
:::
:
:
Flash point
:
None.
460°C (860°F)
:
Auto-ignition temperature
Flammable limits
:
Lower: 3.8% Upper: 9.5%
Type of aerosol
:
Spray
Heat of combustion
:
0.9162 kJ/g
Aerosol product
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The product is stable.
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
No specific data.
10. Stability and reactivity
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition products
:
:
:
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
United States
Acute toxicity
1-bromopropane
LD50 Oral
Rat
3600 mg/kg
-
norflurane
LC50 Inhalation Vapor
Rat
1500 g/m³
4 hours
propan-1-ol
LD50 Dermal
Rabbit
5040 mg/kg
-
LD50 Oral
Rat
1870 mg/kg
-
1,2-epoxybutane
LC50 Inhalation Vapor
Rat
6300 mg/m³
4 hours
LD50 Oral
Rat
500 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Chronic toxicity
Conclusion/Summary
:
Not available.
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Classification
norflurane
-----
None.
propan-1-ol
---A4-
None.
1,2-epoxybutane
-2B---
-
Product/ingredient name
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
Conclusion/Summary
:
Not available.
Sensitizer
Conclusion/Summary
:
Not available.
Species
propan-1-ol
Eyes - Moderate irritant
Rabbit
-
24 hours 20 milligrams
-
Skin - Mild irritant
Human
-
47 hours 100 Percent
-
Skin - Mild irritant
Human
-
24 hours 100 Percent
-
Skin - Mild irritant
Rabbit
-
500 milligrams
-
1,2-epoxybutane
Eyes - Moderate irritant
Rabbit
-
24 hours 100 milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500 milligrams
-
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11. Toxicological information
Canada
Mexico
Acute toxicity
1-bromopropane
LD50 Oral
Rat
3600 mg/kg
-
norflurane
LC50 Inhalation Vapor
Rat
1500 g/m³
4 hours
propan-1-ol
LD50 Dermal
Rabbit
5040 mg/kg
-
LD50 Oral
Rat
1870 mg/kg
-
1,2-epoxybutane
LC50 Inhalation Vapor
Rat
6300 mg/m³
4 hours
LD50 Oral
Rat
500 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Acute toxicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Chronic toxicity
Conclusion/Summary
:
Not available.
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Classification
norflurane
---
None.
--propan-1-ol
A4--
None.
--1,2-epoxybutane
-2B---
-
Product/ingredient name
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
propan-1-ol
Eyes - Moderate irritant
Rabbit
-
24 hours 20 milligrams
-
Skin - Mild irritant
Human
-
47 hours 100 Percent
-
Skin - Mild irritant
Human
-
24 hours 100 Percent
-
Skin - Mild irritant
Rabbit
-
500 milligrams
-
1,2-epoxybutane
Eyes - Moderate irritant
Rabbit
-
24 hours 100 milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500 milligrams
-
Conclusion/Summary
:
Not available.
Sensitizer
Conclusion/Summary
:
Not available.
Species
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11. Toxicological information
propan-1-ol
LD50 Dermal
Rabbit
5040 mg/kg
-
LD50 Oral
Rat
1870 mg/kg
-
1-bromopropane
LD50 Oral
Rat
3600 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Chronic toxicity
Conclusion/Summary
:
Not available.
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Classification
norflurane
---
None.
--propan-1-ol
A4--
None.
-
-
1,2-epoxybutane
-2B---
-
Product/ingredient name
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
propan-1-ol
Eyes - Moderate irritant
Rabbit
-
24 hours 20 milligrams
-
Skin - Mild irritant
Human
-
47 hours 100 Percent
-
Skin - Mild irritant
Human
-
24 hours 100 Percent
-
Skin - Mild irritant
Rabbit
-
500 milligrams
-
Conclusion/Summary
:
Not available.
Sensitizer
Conclusion/Summary
:
Not available.
Score
12. Ecological information
United States
Ecotoxicity
:
No known significant effects or critical hazards.
Aquatic ecotoxicity
1-bromopropane
Acute LC50 67300 µg/l Fresh water
Fish - Pimephales promelas
96 hours
propan-1-ol
Acute EC50 4480000 µg/l Fresh water
Algae - Selenastrum sp.
96 hours
Acute LC50 1000000 µg/l Fresh water
Crustaceans - Gammarus pulex
48 hours
Acute LC50 2950000 µg/l Fresh water
Daphnia - Daphnia pulex
48 hours
Acute LC50 3800000 µg/l Marine water
Fish - Alburnus alburnus
96 hours
Product/ingredient name
Species
Result
Exposure
Conclusion/Summary
:
Not available.
Persistence/degradability
Conclusion/Summary
:
Not available.
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12. Ecological information
Canada
Mexico
Aquatic ecotoxicity
1-bromopropane
Acute LC50 67300 µg/l Fresh water
Fish - Pimephales promelas
96 hours
propan-1-ol
Acute EC50 4480000 µg/l Fresh water
Algae - Selenastrum sp.
96 hours
Acute LC50 1000000 µg/l Fresh water
Crustaceans - Gammarus pulex
48 hours
Acute LC50 2950000 µg/l Fresh water
Daphnia - Daphnia pulex
48 hours
Acute LC50 3800000 µg/l Marine water
Fish - Alburnus alburnus
96 hours
Product/ingredient name
Species
Result
Exposure
Conclusion/Summary
:
Not available.
Persistence/degradability
Conclusion/Summary
:
Not available.
Aquatic ecotoxicity
propan-1-ol
Acute EC50 4480000 µg/l Fresh water
Algae - Selenastrum sp.
96 hours
Acute LC50 1000000 µg/l Fresh water
Crustaceans - Gammarus pulex
48 hours
Acute LC50 2950000 µg/l Fresh water
Daphnia - Daphnia pulex
48 hours
Acute LC50 3800000 µg/l Marine water
Fish - Alburnus alburnus
96 hours
1-bromopropane
Acute LC50 67300 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Product/ingredient name
Species
Result
Exposure
Conclusion/Summary
:
Not available.
Persistence/degradability
Conclusion/Summary
:
Not available.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
Waste disposal
13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.
14. Transport information
Regulatory information
UN number
Proper shipping name
Classes
PG*
Label
Additional information
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14. Transport information
ORM-D
Reportable quantity
18181.8 lbs / 8254.5 kg [1615.3 gal / 6114. 5 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
DOT Classification
TDG Classification
ORM-D
Consumer commodity ORM-D
-
-
Consumer commodity ORM-D
-
ADR/RID Class
AEROSOLS, non­flammable
2-IMDG Class
AEROSOLS (Non-flammable)
2.2
-
AEROSOLS, non­flammable
1950
IATA-DGR Class
2.2
-
1950
1950
Tunnel code
(E)
-
-
-
-
Mexico Classification
-
Consumer commodity ORM-D
ORM-D
-
­PG* : Packing group
Irritating material Carcinogen Target organ effects
HCS Classification
15. Regulatory information
U.S. Federal regulations
:
:
United States
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602 Class I Substances
:
Not listed
Clean Air Act Section 602 Class II Substances
:
Not listed
DEA List I Chemicals (Precursor Chemicals)
:
Not listed
DEA List II Chemicals (Essential Chemicals)
:
Not listed
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: All components are listed or exempted.
SARA 302/304
Composition/information on ingredients
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15. Regulatory information
The following components are listed: N-PROPYL BROMIDE; CARBON DIOXIDE; PROPYL ALCOHOL
WARNING:
This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Massachusetts
The following components are listed: Volatile organic compounds
WHMIS (Canada)
Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic).
:
:
SARA 313
Canada
Product name
CAS number
%
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
1-bromopropane
No.
Yes.
No.
No.
Ingredient name
Cancer
Reproductive
No significant risk level
Maximum acceptable dosage level
1,2-epoxybutane
106-88-7
0.1 - 1
1,2-epoxybutane
106-88-7
0.1 - 1
Form R - Reporting requirements
Supplier notification
Canadian NPRI
:
California Prop. 65
United States inventory (TSCA 8b)
:
All components are listed or exempted.
New York
:
The following components are listed: 1,2-Epoxybutane
New Jersey
:
The following components are listed: 1-BROMOPROPANE; PROPANE, 1-BROMO-; CARBON DIOXIDE; CARBONIC ACID GAS; PROPYL ALCOHOL; 1-PROPANOL; 1, 2-BUTYLENE OXIDE; 1,2-EPOXYBUTANE
Pennsylvania
:
The following components are listed: PROPANE, 1-BROMO-; CARBON DIOXIDE; 1-PROPANOL; OXIRANE, ETHYL-
State regulations
CEPA Toxic substances
:
The following components are listed: Carbon dioxide; Volatile organic compounds; Ethyloxirane
Canadian lists
SARA 304 RQ
:
Not applicable.
No products were found.
SARA 311/312
Classification
:
Immediate (acute) health hazard Delayed (chronic) health hazard
1-bromopropane
65 - 75
Yes.
No.
No.
No.
Yes.
Carbon dioxide
1 - 5
No.
No.
No.
No.
Yes.
norflurane
5 - 25
No.
Yes.
No.
No.
Yes.
propan-1-ol
1 - 5
Yes.
No.
No.
Yes.
Yes.
1,2-epoxybutane
0.1 - 1
Yes.
No.
No.
Yes.
Yes.
Name
%
Fire hazard
Sudden release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
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New & Improved Pow-R-Wash™ NR
15. Regulatory information
Australia inventory (AICS)
: All components are listed or exempted.
China inventory (IECSC)
: All components are listed or exempted.
Japan inventory
: All components are listed or exempted.
Korea inventory
: All components are listed or exempted.
Malaysia Inventory (EHS Register)
: Not determined.
New Zealand Inventory of Chemicals (NZIoC)
: All components are listed or exempted.
Philippines inventory (PICCS)
: All components are listed or exempted.
Taiwan inventory (CSNN)
: Not determined.
International regulations
International lists
:
Mexico
121
Health
Flammability
Reactivity
Special
Classification
:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Canada inventory
:
Not determined.
Chemical Weapons Convention List Schedule I Chemicals
:
Not listed
Chemical Weapons Convention List Schedule II Chemicals
:
Not listed
Chemical Weapons Convention List Schedule III Chemicals
:
Not listed
16. Other information
Hazardous Material Information System (U.S.A.)
2
1
1
National Fire Protection Association (U.S.A.)
Health
Flammability
Physical hazards
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.
Label requirements
:
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
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New & Improved Pow-R-Wash™ NR
16. Other information
112
Health
Special
Instability/Reactivity
Flammability
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of printing
Date of issue
Date of previous issue
Version
7/25/2013.
:
:::
Indicates information that has changed from previously issued version.
7/25/2013.
No previous validation.
1
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Prepared by
:
Not available.
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