Page 1
Electro-Wash® CZ
ES7101
Electro-Wash® CZ
3102L
ES7101, ES7105, ES7155, ES7108L, ES7101C, ES7105C, ES7108LC
Cleaners Degreasers
Chemtronics
8125 Cobb Center Drive
Kennesaw, GA 30152
Tel. 770-424-4888 or toll free 800-645-5244
Chemtrec - 1-800-424-9300 or collect 703-527-3887
24/7
Chemtronics
8125 Cobb Center Drive
Kennesaw, GA 30152
Tel. 770-424-4888 or toll free 800-645-5244
7/29/2013.
Material Safety Data Sheet
Product name
Supplier
Synonym
Trade name
Material uses
Manufacturer
Code
MSDS #
Validation date
Print date
In case of emergency
1. Product and company identification
Electro-Wash® CZ
:
:
:
:
:
:::
:
:
:
Product type
:
Liquid.
7/29/2013.
Signal word
2. Hazards identification
Potential acute health effects
Harmful by inhalation. At very high concentrations, can displace the normal air and
cause suffocation from lack of oxygen. Exposure to decomposition products may cause
a health hazard. Serious effects may be delayed following exposure.
May cause eye irritation.
Harmful if swallowed.
May cause skin irritation.
Eyes
Skin
Inhalation
Ingestion
Physical state
Liquid. [Liquid.]
CAUTION!
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION.
CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
:
:
:
:::
Odor
:
Ethereal. [Slight]
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Potential chronic health effects
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Chronic effects
:
Contains material that can cause target organ damage.
Color
:
Colorless.
Emergency overview
Hazard statements
:
Precautionary measures
:
Do not breathe vapor or mist. Do not ingest. Do not eat, drink or smoke when using
this product. Avoid contact with eyes, skin and clothing. Wash thoroughly after
handling.
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Electro-Wash® CZ
2. Hazards identification
See toxicological information (Section 11)
Medical conditions
aggravated by overexposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
:
Teratogenicity
:
No known significant effects or critical hazards.
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Over-exposure signs/symptoms
Ingestion
:
Adverse symptoms may include the following:
nausea or vomiting
central nervous system depression
Skin
:
Adverse symptoms may include the following:
irritation redness
Eyes
:
Adverse symptoms may include the following:
irritation
redness
watering
Inhalation
:
Adverse symptoms may include the following:
dizziness/vertigo
nausea or vomiting
Target organs
:
Contains material which causes damage to the following organs: the nervous system,
eye, lens or cornea.
Contains material which may cause damage to the following organs: kidneys, liver,
heart, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS).
Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-
163702-07-6
20 - 40
Propane, 2-(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoro-
163702-08-7
20 - 40
trans-dichloroethylene
156-60-5
10 - 50
methylcyclohexane
108-87-2
1 - 10
methanol
67-56-1
1 - 3
3. Composition/information on ingredients
Name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:::
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4. First aid measures
No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
Notes to physician
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Use an extinguishing agent suitable for the surrounding fire.
5. Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
In a fire or if heated, a pressure increase will occur and the container may burst.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
Special exposure hazards
:
None known.
Suitable
:
Not suitable
:
Hazardous thermal
decomposition products
:
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
carbonyl halides
Flammability of the product
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Environmental precautions
6. Accidental release measures
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Personal precautions
:
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill
:
Methods for cleaning up
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
7. Handling and storage
Handling
:
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7. Handling and storage
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Storage
:
Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-
AIHA WEEL (United States, 10/2011).
TWA: 750 ppm 8 hours.
Propane, 2-(difluoromethoxymethyl)-1,1,1,2,3,3,
3-heptafluoro-
AIHA WEEL (United States, 10/2011).
TWA: 750 ppm 8 hours.
trans-dichloroethylene
ACGIH TLV (United States, 3/2012).
TWA: 200 ppm 8 hours.
TWA: 793 mg/m³ 8 hours.
methylcyclohexane
ACGIH TLV (United States, 3/2012).
TWA: 1610 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
NIOSH REL (United States, 1/2013).
TWA: 1600 mg/m³ 10 hours.
TWA: 400 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 2000 mg/m³ 8 hours.
TWA: 500 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1600 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
methanol
ACGIH TLV (United States, 3/2012). Absorbed through skin.
STEL: 328 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 262 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
NIOSH REL (United States, 1/2013). Absorbed through skin.
STEL: 325 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 260 mg/m³ 10 hours.
TWA: 200 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 260 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.
STEL: 325 mg/m³ 15 minutes.
STEL: 250 ppm 15 minutes.
TWA: 260 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
8. Exposure controls/personal protection
Engineering measures
:
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Recommended monitoring
procedures
:
If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Ingredient
Exposure limits
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8. Exposure controls/personal protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Personal protection
Eyes
Skin
Respiratory
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Hands
:
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
32°C (89.6°F)
Liquid. [Liquid.]
1.33
29.3 kPa (220 mm Hg) [room temperature]
Ethereal. [Slight]
Colorless.
Boiling/condensation point
>1 (butyl acetate = 1)
9. Physical and chemical properties
Physical state
Relative density
Vapor pressure
Evaporation rate
Odor
Color::
:::
:
:
The product is stable.
Reactive or incompatible with the following materials: metals Aluminum. zinc
Magnesium. Alkaline. alkalis
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
elevated temperature oxidizing agents Avoid all possible sources of ignition (spark or
flame).
10. Stability and reactivity
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
:
:
:
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
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11. Toxicological information
Acute toxicity
trans-dichloroethylene
LC50 Inhalation Gas.
Rat
24100 ppm
4 hours
LD50 Dermal
Rabbit
>5 g/kg
-
LD50 Oral
Rat
1235 mg/kg
-
methanol
LC50 Inhalation Gas.
Rat
145000 ppm
1 hours
LC50 Inhalation Gas.
Rat
64000 ppm
4 hours
LD50 Dermal
Rabbit
15800 mg/kg
-
LD50 Oral
Rat
5600 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Chronic toxicity
Conclusion/Summary
:
Not available.
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Classification
trans-dichloroethylene
-----
None.
methylcyclohexane
-----
None.
methanol
None.
-----
Product/ingredient name
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
Conclusion/Summary
:
Not available.
Sensitizer
Conclusion/Summary
:
Not available.
Species
trans-dichloroethylene
Eyes - Moderate irritant
Rabbit
-
10 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 500
milligrams
-
methylcyclohexane
Eyes - Mild irritant
Rabbit
-
24 hours 100
microliters
-
Skin - Mild irritant
Rabbit
-
24 hours 500
microliters
-
methanol
Eyes - Moderate irritant
Rabbit
-
24 hours 100
milligrams
-
Eyes - Moderate irritant
Rabbit
-
40 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 20
milligrams
-
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12. Ecological information
Ecotoxicity
:
No known significant effects or critical hazards.
Aquatic ecotoxicity
trans-dichloroethylene
Acute LC50 220000 to 290000 µg/l
Fresh water
Daphnia - Daphnia magna
48 hours
methylcyclohexane
Acute LC50 5800 µg/l Marine water
Fish - Morone saxatilis - Juvenile
(Fledgling, Hatchling, Weanling)
96 hours
methanol
Acute EC50 16.912 mg/l Marine water
Algae - Ulva pertusa
96 hours
Acute EC50 10000000 µg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 2500000 µg/l Marine water
Crustaceans - Crangon crangon Adult
48 hours
Acute LC50 100 mg/l Fresh water
Fish - Pimephales promelas Juvenile (Fledgling, Hatchling,
Weanling)
96 hours
Chronic NOEC 9.96 mg/l Marine water
Algae - Ulva pertusa
96 hours
Product/ingredient name
Species
Result
Exposure
Conclusion/Summary
:
Not available.
Persistence/degradability
Conclusion/Summary
:
Not available.
Other adverse effects
:
No known significant effects or critical hazards.
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Waste disposal
13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
United States - RCRA Toxic hazardous waste "U" List
1,2-Dichloroethylene; Ethene, 1,2-dichloro-, (E)-
156-60-5
Listed
U079
Methanol (I); Methyl alcohol (I)
67-56-1
Listed
U154
Ingredient
CAS #
Status
Reference
number
14. Transport information
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14. Transport information
-
Reportable quantity
3333.3 lbs / 1513.3 kg
[300.59 gal / 1137.8 L]
Package sizes
shipped in quantities
less than the product
reportable quantity are
not subject to the RQ
(reportable quantity)
transportation
requirements.
DOT Classification
TDG Classification
-
Cleaning Compound
-
Not
regulated.
Cleaning Compound
-
ADR/RID Class
Cleaning Compound
-
-
IMDG Class
Cleaning Compound
-
-
Cleaning Compound
Not
regulated.
IATA-DGR Class
-
Regulatory
information
UN number
Proper shipping
name
Classes
PG*
Label
Additional
information
-
Not
regulated.
Not
regulated.
-
-
-
Not
regulated.
-
Mexico
Classification
Not
regulated.
Cleaning Compound
--PG* : Packing group
Irritating material
Target organ effects
HCS Classification
15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 307
: trans-dichloroethylene
:
:
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Listed
Clean Air Act Section 602
Class I Substances
:
Not listed
Clean Air Act Section 602
Class II Substances
:
Not listed
DEA List I Chemicals
(Precursor Chemicals)
:
Not listed
DEA List II Chemicals
(Essential Chemicals)
:
Not listed
TSCA 8(a) PAIR
: methylcyclohexane
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: All components are listed or exempted.
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
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15. Regulatory information
The following components are listed: DICHLOROETHYLENE-TRANS;
METHYLCYCLOHEXANE; METHANOL
WARNING:
This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Massachusetts
Australia inventory (AICS)
: All components are listed or exempted.
China inventory (IECSC)
: All components are listed or exempted.
Japan inventory
: Not determined.
Korea inventory
: Not determined.
Malaysia Inventory (EHS Register)
: Not determined.
New Zealand Inventory of Chemicals (NZIoC)
: All components are listed or exempted.
Philippines inventory (PICCS)
: All components are listed or exempted.
Taiwan inventory (CSNN)
: Not determined.
International regulations
International lists
:
:
SARA 313
Product name
CAS number
%
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
methanol
No.
Yes.
No.
No.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
methanol
67-56-1
1 - 3
methanol
67-56-1
1 - 3
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Canada inventory
:
All components are listed or exempted.
Chemical Weapons
Convention List Schedule
I Chemicals
:
Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
:
Not listed
New York
:
The following components are listed: Ethene, trans-1,2-dichloro-; Dichloroethylene;
Methanol
New Jersey
:
The following components are listed: METHYLCYCLOHEXANE; CYCLOHEXANE,
METHYL-; METHYL ALCOHOL; METHANOL
Pennsylvania
:
The following components are listed: ETHENE, 1,2-DICHLORO-, (E)-; CYCLOHEXANE,
METHYL-; METHANOL
State regulations
Classification
:
Immediate (acute) health hazard
Delayed (chronic) health hazard
trans-dichloroethylene
10 - 50
Yes.
No.
No.
Yes.
Yes.
methylcyclohexane
1 - 10
Yes.
No.
No.
No.
Yes.
methanol
1 - 3
Yes.
No.
No.
Yes.
Yes.
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
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15. Regulatory information
Chemical Weapons
Convention List Schedule
III Chemicals
:
Not listed
16. Other information
Hazardous Material
Information System (U.S.A.)
1
0
1
101
National Fire Protection
Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION.
CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
Label requirements
:
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of printing
Date of issue
Date of previous issue
Version
7/29/2013.
:::
:
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
7/29/2013.
No previous validation.
1
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.
Prepared by
:
Not available.
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