Chemtronics CW2000 User Manual

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Page 1

CircuitWorks® Nickel Conductive Pen

Electrical conductive agents

Conductive Pen

2000

CW2000

Conductive agents

Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152

Tel. 770-424-4888 or toll free 800-645-5244

Chemtrec - 1-800-424-9300 or collect 703-527-3887 24/7

Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152

Tel. 770-424-4888 or toll free 800-645-5244

7/25/2013.

Material Safety Data Sheet

Product name

Supplier

Synonym

Trade name

Material uses

Manufacturer

Code

MSDS #

Validation date

Print date

In case of emergency

1. Product and company identification

CircuitWorks® Nickel Conductive Pen

: :::

Product type

Liquid.

7/25/2013.

Signal word

2. Hazards identification

Potential acute health effects

Toxic by inhalation.

Moderately irritating to eyes.

Harmful if swallowed.

Harmful in contact with skin. Moderately irritating to the skin.

Eyes

Skin

Inhalation

Ingestion

Physical state

Liquid.

WARNING!

FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER.

:::

Odor

Hydrocarbon.

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Potential chronic health effects

Chronic effects

Contains material that can cause target organ damage.

Color

Silver.

Emergency overview

Hazard statements

Precautionary measures

Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Avoid prolonged contact with eyes, skin and clothing. Keep away from heat, sparks and flame. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling.

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CircuitWorks® Nickel Conductive Pen

2. Hazards identification

See toxicological information (Section 11)

Medical conditions aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product.

Carcinogenicity

Contains material which may cause cancer. Risk of cancer depends on duration and level of exposure.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Over-exposure signs/symptoms

Ingestion

Adverse symptoms may include the following: central nervous system depression

Skin

Adverse symptoms may include the following: irritation redness cracking dryness sensitizer

Eyes

Adverse symptoms may include the following: irritation watering redness

Inhalation

Adverse symptoms may include the following: dizziness/vertigo drowsiness/fatigue headache respiratory tract irritation nausea or vomiting

Target organs

Contains material which causes damage to the following organs: eye, lens or cornea. Contains material which may cause damage to the following organs: blood, kidneys, lungs, liver, spleen, lymphatic system, upper respiratory tract, skin, bone marrow, central nervous system (CNS), nose/sinuses. Nickel

7440-02-0

35 - 65

2-methoxy-1-methylethyl acetate

108-65-6

2 - 20

2-butoxyethyl acetate

112-07-2

2 - 20

n-butyl acetate

123-86-4

2 - 20

3. Composition/information on ingredients

Name

CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

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CircuitWorks® Nickel Conductive Pen

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

4. First aid measures

Eye contact

Skin contact

Inhalation Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Notes to physician

::: :

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Use dry chemical,

CO₂,

water spray (fog) or foam.

5. Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special exposure hazards

Do not use water jet.

Suitable

Not suitable

Hazardous thermal decomposition products

Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides

Flammability of the product

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Environmental precautions

6. Accidental release measures

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Personal precautions

Methods for cleaning up

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CircuitWorks® Nickel Conductive Pen

6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

7. Handling and storage

Handling

Storage

Nickel

ACGIH TLV (United States, 3/2012).

TWA: 1.5 mg/m³ 8 hours. Form: Inhalable fraction

NIOSH REL (United States, 1/2013). Notes: as Ni

TWA: 0.015 mg/m³, (as Ni) 10 hours.

OSHA PEL (United States, 6/2010). Notes: as Ni

TWA: 1 mg/m³, (as Ni) 8 hours.

OSHA PEL 1989 (United States, 3/1989). Notes: as Ni

TWA: 1 mg/m³, (as Ni) 8 hours.

2-methoxy-1-methylethyl acetate

AIHA WEEL (United States, 10/2011).

TWA: 50 ppm 8 hours.

2-butoxyethyl acetate

ACGIH TLV (United States, 3/2012).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 1/2013).

TWA: 33 mg/m³ 10 hours. TWA: 5 ppm 10 hours.

8. Exposure controls/personal protection

Ingredient

Exposure limits

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CircuitWorks® Nickel Conductive Pen

8. Exposure controls/personal protection

n-butyl acetate

ACGIH TLV (United States, 3/2012).

STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours.

NIOSH REL (United States, 1/2013).

STEL: 950 mg/m³ 15 minutes. STEL: 200 ppm 15 minutes. TWA: 710 mg/m³ 10 hours. TWA: 150 ppm 10 hours.

OSHA PEL (United States, 6/2010).

TWA: 710 mg/m³ 8 hours. TWA: 150 ppm 8 hours.

OSHA PEL 1989 (United States, 3/1989).

STEL: 950 mg/m³ 15 minutes. STEL: 200 ppm 15 minutes. TWA: 710 mg/m³ 8 hours. TWA: 150 ppm 8 hours.

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

:::

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Hands

Engineering measures

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

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CircuitWorks® Nickel Conductive Pen

8. Exposure controls/personal protection

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Liquid.

Hydrocarbon.

Silver.

<1 (butyl acetate = 1)

9. Physical and chemical properties

Physical state

Evaporation rate

Odor

Color::::

Flash point

Closed cup: 23 to 37.8°C (73.4 to 100°F) [Tagliabue.]

The product is stable.

Reactive or incompatible with the following materials: oxidizing materials

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

10. Stability and reactivity

Chemical stability

Conditions to avoid

Incompatible materials

Hazardous decomposition products

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

11. Toxicological information

Acute toxicity

2-methoxy-1-methylethyl acetate

LD50 Dermal

Rabbit

>5 g/kg

LD50 Oral

Rat

8532 mg/kg

2-butoxyethyl acetate

LD50 Dermal

Rabbit

1500 mg/kg

LD50 Oral

Rat

2400 mg/kg

n-butyl acetate

LC50 Inhalation Gas.

Rat

390 ppm

4 hours

LD50 Dermal

Rabbit

>17600 mg/kg

LD50 Oral

Rat

10768 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Conclusion/Summary

Not available.

Chronic toxicity

Conclusion/Summary

Not available.

Irritation/Corrosion

Product/ingredient name

Result

Score

Exposure

Observation

Conclusion/Summary

Not available.

Sensitizer

Conclusion/Summary

Not available.

Species

2-butoxyethyl acetate

Eyes - Mild irritant

Rabbit

24 hours 500 milligrams

Skin - Mild irritant

Rabbit

500 milligrams

n-butyl acetate

Eyes - Moderate irritant

Rabbit

100 milligrams

Skin - Moderate irritant

Rabbit

24 hours 500 milligrams

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CircuitWorks® Nickel Conductive Pen

11. Toxicological information

Carcinogenicity

Conclusion/Summary

Not available.

Mutagenicity

Conclusion/Summary

Not available.

Teratogenicity

Conclusion/Summary

Not available.

Reproductive toxicity

Conclusion/Summary

Not available.

Classification

Nickel

Reasonably anticipated to be a human carcinogen.

A5-+

2-methoxy-1-methylethyl acetate

-----

None.

2-butoxyethyl acetate

---A3-

None.

n-butyl acetate

---A4-

None.

Product/ingredient name

ACGIH

EPA

NIOSH

NTP

IARC

OSHA

12. Ecological information

Ecotoxicity

No known significant effects or critical hazards.

Aquatic ecotoxicity

Nickel

Acute EC50 2 ppm Marine water

Algae - Macrocystis pyrifera Young

4 days

Acute EC50 450 µg/l Fresh water

Aquatic plants - Lemna minor

4 days

Acute EC50 1000 µg/l Marine water

Daphnia - Daphnia magna

48 hours

Acute IC50 0.31 mg/l Marine water

Crustaceans - Americamysis bahia - Juvenile (Fledgling, Hatchling, Weanling)

48 hours

Acute LC50 47.5 ng/L Fresh water

Fish - Heteropneustes fossilis

96 hours

Chronic NOEC 100 mg/l Marine water

Algae - Glenodinium halli

72 hours

Chronic NOEC 3.5 µg/l Fresh water

Fish - Cyprinus carpio

4 weeks

n-butyl acetate

Acute LC50 32000 µg/l Marine water

Crustaceans - Artemia salina Nauplii

48 hours

Acute LC50 62000 µg/l

Fish - Danio rerio

96 hours

Product/ingredient name

Species

Result

Exposure

Conclusion/Summary

Not available.

Persistence/degradability

Conclusion/Summary

Not available.

Other adverse effects

No known significant effects or critical hazards.

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere

Waste disposal

13. Disposal considerations

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CircuitWorks® Nickel Conductive Pen

13. Disposal considerations

inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

14. Transport information

ORM-D

Reportable quantity

200 lbs / 90.8 kg [14. 11 gal / 53.412 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.

DOT Classification

TDG Classification

ORM-D

Consumer commodity ORM-D

ADR/RID Class

PAINT

III

IMDG Class

PAINT

III

PAINT

UN1263

IATA-DGR Class

Regulatory information

UN number

Proper shipping name

Classes

PG*

Label

Additional information

III

UN1263

--Limited quantity

Mexico Classification

Consumer commodity ORM-D

ORM-D

PG* : Packing group

Flammable liquid Toxic material Irritating material Carcinogen Target organ effects

HCS Classification

15. Regulatory information

U.S. Federal regulations

Clean Water Act (CWA) 307

: Nickel

Clean Water Act (CWA) 311

: n-butyl acetate

::TSCA 8(a) PAIR

: 2-methoxy-1-methylethyl acetate

TSCA 8(a) CDR Exempt/Partial exemption

: Not determined

United States inventory (TSCA 8b)

: Not determined.

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CircuitWorks® Nickel Conductive Pen

15. Regulatory information

The following components are listed: NICKEL; BUTYL ACETATE

WARNING:

This product contains a chemical known to the State of California to cause cancer.

Massachusetts

SARA 313

Product name

CAS number

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

Nickel

7440-02-0

35 - 65

2-butoxyethyl acetate

112-07-2

2 - 20

Nickel

7440-02-0

35 - 65

2-butoxyethyl acetate

112-07-2

2 - 20

Form R - Reporting requirements

Supplier notification California Prop. 65

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)

Listed

Clean Air Act Section 602 Class I Substances

Not listed

Clean Air Act Section 602 Class II Substances

Not listed

DEA List I Chemicals (Precursor Chemicals)

Not listed

DEA List II Chemicals (Essential Chemicals)

Not listed

New York

The following components are listed: Nickel; Butyl acetate

New Jersey

The following components are listed: NICKEL; 2-BUTOXYETHYL ACETATE; ETHANOL, 2-BUTOXY-, ACETATE; n-BUTYL ACETATE; ACETIC ACID, BUTYL ESTER

Pennsylvania

The following components are listed: NICKEL; GLYCOL ETHERS; ACETIC ACID, BUTYL ESTER

State regulations

SARA 302/304

SARA 304 RQ

Not applicable.

No products were found.

Composition/information on ingredients

SARA 311/312

Classification

Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard

Nickel

35 - 65

No.

Yes.

2-methoxy-1-methylethyl acetate

2 - 20

Yes.

No.

Yes.

2-butoxyethyl acetate

2 - 20

Yes.

No.

Yes.

n-butyl acetate

2 - 20

Yes.

No.

Yes.

Name

Fire hazard

Sudden release of pressure

Reactive

Immediate (acute) health hazard

Delayed (chronic) health hazard

Composition/information on ingredients

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CircuitWorks® Nickel Conductive Pen

15. Regulatory information

Australia inventory (AICS)

: Not determined.

China inventory (IECSC)

: Not determined.

Japan inventory

: Not determined.

Korea inventory

: Not determined.

Malaysia Inventory (EHS Register)

: Not determined.

New Zealand Inventory of Chemicals (NZIoC)

: Not determined.

Philippines inventory (PICCS)

: Not determined.

Taiwan inventory (CSNN)

: Not determined.

International regulations

International lists

Nickel

Yes.

No.

Ingredient name

Cancer

Reproductive

No significant risk level

Maximum acceptable dosage level

Canada inventory

Not determined.

Chemical Weapons Convention List Schedule I Chemicals

Not listed

Chemical Weapons Convention List Schedule II Chemicals

Not listed

Chemical Weapons Convention List Schedule III Chemicals

Not listed

16. Other information

Hazardous Material Information System (U.S.A.)

132

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Health

Flammability

Physical hazards

Label requirements

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

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CircuitWorks® Nickel Conductive Pen

16. Other information

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of printing

Date of issue

Date of previous issue

Version

7/25/2013.

:::

Indicates information that has changed from previously issued version.

7/25/2013.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Prepared by

Not available.

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