Chemtronics CTSR-12 User Manual

Konform® SR - CTSR-12

Coating Solution

Konform® SR - CTSR12

0710

CTSR-12, CTSR-12C, CTSR-12E

ITW Chemtronics
8125 Cobb Center Drive
Kennesaw, GA 30152

Tel. [phone] or toll free 800-645-5244

Chemtrec - 1-800-424-9300 or collect 703-527-3887
24/7

ITW Chemtronics
8125 Cobb Center Drive
Kennesaw, GA 30152 ITW Chemtronics
8125 Cobb Center Drive
Kennesaw, GA 30152

Tel. [phone] or toll free 800-645-5244

6/13/2013.

Material Safety Data Sheet

Product name

Supplier

Synonym

Trade name

Manufacturer

Code

MSDS #

Validation date

Print date

In case of emergency

1. Product and company identification

Konform® SR - CTSR-12

:

:::

:
:::

:

:

Product type

:

Aerosol.

6/13/2013.

Signal word

2. Hazards identification

Potential acute health effects

Harmful by inhalation. At very high concentrations, can displace the normal air and
cause suffocation from lack of oxygen.

Severely irritating to eyes. Risk of serious damage to eyes.

Harmful if swallowed. Irritating to mouth, throat and stomach.

Moderately irritating to the skin.

Eyes

Skin

Inhalation
Ingestion

Physical state

Liquid. [Aerosol.]

DANGER!

EXTREMELY FLAMMABLE AEROSOL. CAUSES EYE IRRITATION. MAY BE
HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. CONTAINS
MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL
DATA.

:

:

:

:::

Odor

:

Hydrocarbon.

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Potential chronic health effects

Color

:

Straw.

Emergency overview

Hazard statements

:

Precautionary measures

:

Do not breathe vapor or mist. Do not ingest. Do not eat, drink or smoke when using
this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks,
open flames and hot surfaces. - No smoking. Do not spray on an open flame or other
ignition source. Pressurized container: Do not pierce or burn, even after use. Protect
from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Wash
thoroughly after handling.

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2. Hazards identification

See toxicological information (Section 11)

Medical conditions
aggravated by over­exposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.

:

Carcinogenicity

:

No known significant effects or critical hazards.

Mutagenicity

:

No known significant effects or critical hazards.

Teratogenicity

:

No known significant effects or critical hazards.

Developmental effects

:

No known significant effects or critical hazards.

Chronic effects

:

Contains material that may cause target organ damage, based on animal data.

Fertility effects

:

No known significant effects or critical hazards.

Over-exposure signs/symptoms

Ingestion

:

Adverse symptoms may include the following:
Irritating to mouth, throat and stomach.
May cause optic nerve damage.

Skin

:

Adverse symptoms may include the following:
irritation
redness

Eyes

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Inhalation

:

Adverse symptoms may include the following:
respiratory tract irritation
coughing

Target organs

:

Contains material which may cause damage to the following organs: blood, kidneys, the
nervous system, the reproductive system, liver, heart, upper respiratory tract, skin,
central nervous system (CNS), eye, lens or cornea.
hexane

107-83-5

15 - 30

propane

74-98-6

10 - 15

Butane

106-97-8

10 - 15

acetone

67-64-1

5 - 15

3-methylpentane

96-14-0

5 - 15

toluene

108-88-3

5 - 10

2,3-dimethylbutane

79-29-8

5 - 10

2-methoxy-1-methylethyl acetate

108-65-6

2 - 5

2,2-dimethylbutane

75-83-2

1 - 5

3. Composition/information on ingredients

Name

CAS number

%

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.

4. First aid measures

Eye contact

Skin contact

:

:

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4. First aid measures

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.

Inhalation
Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.

Notes to physician

:
:
:

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Use an extinguishing agent suitable for the surrounding fire.

5. Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled
from a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Special protective
equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

Special exposure hazards

:

None known.

Suitable

:

Not suitable

:

Hazardous thermal
decomposition products

:

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide

Flammability of the product

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).

Environmental precautions

6. Accidental release measures

:

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Personal precautions

:

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Methods for cleaning up

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6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Large spill

:

Store in accordance with local regulations. Store in a segregated and approved area.
Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Use appropriate containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Pressurized container: protect from sunlight and do not expose to temperatures
exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact
with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use non-sparking tools. Empty containers retain product residue and can
be hazardous.

7. Handling and storage

Handling

Storage

:

:

hexane

ACGIH TLV (United States, 3/2012).

TWA: 500 ppm 8 hours.
TWA: 1760 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3500 mg/m³ 15 minutes.

OSHA PEL 1989 (United States, 3/1989).

TWA: 500 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3600 mg/m³ 15 minutes.

NIOSH REL (United States, 1/2013).

TWA: 100 ppm 10 hours.
TWA: 350 mg/m³ 10 hours.
CEIL: 510 ppm 15 minutes.
CEIL: 1800 mg/m³ 15 minutes.

propane

ACGIH TLV (United States, 3/2012).

TWA: 1000 ppm 8 hours.

NIOSH REL (United States, 1/2013).

TWA: 1800 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.

OSHA PEL (United States, 6/2010).

TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.

8. Exposure controls/personal protection

Ingredient

Exposure limits

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8. Exposure controls/personal protection

Butane

ACGIH TLV (United States, 3/2012).

TWA: 1000 ppm 8 hours.

NIOSH REL (United States, 1/2013).

TWA: 1900 mg/m³ 10 hours.
TWA: 800 ppm 10 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 1900 mg/m³ 8 hours.
TWA: 800 ppm 8 hours.

acetone

ACGIH TLV (United States, 3/2012).

STEL: 1782 mg/m³ 15 minutes.
STEL: 750 ppm 15 minutes.
TWA: 1188 mg/m³ 8 hours.
TWA: 500 ppm 8 hours.

NIOSH REL (United States, 1/2013).

TWA: 590 mg/m³ 10 hours.
TWA: 250 ppm 10 hours.

OSHA PEL (United States, 6/2010).

TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.

OSHA PEL 1989 (United States, 3/1989).

STEL: 2400 mg/m³ 15 minutes.
STEL: 1000 ppm 15 minutes.
TWA: 1800 mg/m³ 8 hours.
TWA: 750 ppm 8 hours.

3-methylpentane

ACGIH TLV (United States, 3/2012).

TWA: 500 ppm 8 hours.
TWA: 1760 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3500 mg/m³ 15 minutes.

OSHA PEL 1989 (United States, 3/1989).

TWA: 500 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3600 mg/m³ 15 minutes.

NIOSH REL (United States, 1/2013).

TWA: 100 ppm 10 hours.
TWA: 350 mg/m³ 10 hours.
CEIL: 510 ppm 15 minutes.
CEIL: 1800 mg/m³ 15 minutes.

toluene

ACGIH TLV (United States, 3/2012).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 1/2013).

STEL: 560 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 375 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.

OSHA PEL 1989 (United States, 3/1989).

STEL: 560 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 375 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.

OSHA PEL Z2 (United States, 11/2006).

AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.

2,3-dimethylbutane

ACGIH TLV (United States, 3/2012).

TWA: 500 ppm 8 hours.

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8. Exposure controls/personal protection

TWA: 1760 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3500 mg/m³ 15 minutes.

OSHA PEL 1989 (United States, 3/1989).

TWA: 500 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3600 mg/m³ 15 minutes.

NIOSH REL (United States, 1/2013).

TWA: 100 ppm 10 hours.
TWA: 350 mg/m³ 10 hours.
CEIL: 510 ppm 15 minutes.
CEIL: 1800 mg/m³ 15 minutes.

2-methoxy-1-methylethyl acetate

AIHA WEEL (United States, 10/2011).

TWA: 50 ppm 8 hours.

2,2-dimethylbutane

ACGIH TLV (United States, 3/2012).

TWA: 500 ppm 8 hours.
TWA: 1760 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3500 mg/m³ 15 minutes.

OSHA PEL 1989 (United States, 3/1989).

TWA: 500 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 3600 mg/m³ 15 minutes.

NIOSH REL (United States, 1/2013).

TWA: 100 ppm 10 hours.
TWA: 350 mg/m³ 10 hours.
CEIL: 510 ppm 15 minutes.
CEIL: 1800 mg/m³ 15 minutes.

Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Personal protection

Respiratory

:

Engineering measures

:

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Hygiene measures

:

Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Recommended monitoring
procedures

:

If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

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8. Exposure controls/personal protection

Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.

Eyes

Skin::

Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Hands

:

Environmental exposure
controls

:

Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

54°C (129.2°F)

Liquid. [Aerosol.]

89% (v/v)

0.74

>1 [Air = 1]

Hydrocarbon.

Straw.

Boiling/condensation point

>1 (butyl acetate = 1)

9. Physical and chemical properties

Physical state

Relative density

Vapor density

Volatility

Evaporation rate

Odor

Color::

:::

:

::Flash point

:

Closed cup: <-18°C (<-0.4°F) [Tagliabue.]

Type of aerosol

:

Spray

Heat of combustion

:

-29 kJ/g

Aerosol product

The product is stable.

Reactive or incompatible with the following materials: oxidizing materials alkalis

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. open
flames, sparks and static discharge Do not spray on a naked flame or any incandescent
material.

10. Stability and reactivity

Chemical stability

Conditions to avoid

Incompatible materials

Hazardous decomposition
products

:

:

:

:

Possibility of hazardous
reactions

:

Under normal conditions of storage and use, hazardous reactions will not occur.

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11. Toxicological information

Acute toxicity

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

acetone

LD50 Oral

Rat

5800 mg/kg

-

toluene

LC50 Inhalation Vapor

Rat

49 g/m³

4 hours

LD50 Oral

Rat

636 mg/kg

-

2-methoxy-1-methylethyl
acetate

LD50 Dermal

Rabbit

>5 g/kg

-

LD50 Oral

Rat

8532 mg/kg

-

Product/ingredient name

Result

Species

Dose

Exposure

Conclusion/Summary

:

Not available.

Chronic toxicity

Conclusion/Summary

:

Not available.

Carcinogenicity

Conclusion/Summary

:

Not available.

Mutagenicity

Classification

propane

-----

None.

acetone

---A4-

None.

toluene

-3-A4-

None.

2-methoxy-1-methylethyl
acetate

-----

None.

Product/ingredient name

ACGIH

EPA

NIOSH

NTP

IARC

OSHA

Irritation/Corrosion

Product/ingredient name

Result

Score

Exposure

Observation

Conclusion/Summary

:

Not available.

Sensitizer

Conclusion/Summary

:

Not available.

Species

acetone

Eyes - Mild irritant

Human

-

186300 parts
per million

-

Eyes - Mild irritant

Rabbit

-

10 microliters

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20
milligrams

-

Eyes - Severe irritant

Rabbit

-

20 milligrams

-

Skin - Mild irritant

Rabbit

-

24 hours 500
milligrams

-

Skin - Mild irritant

Rabbit

-

395
milligrams

-

toluene

Eyes - Mild irritant

Rabbit

-

0.5 minutes
100
milligrams

-

Eyes - Mild irritant

Rabbit

-

870
Micrograms

-

Eyes - Severe irritant

Rabbit

-

24 hours 2
milligrams

-

Skin - Mild irritant

Pig

-

24 hours 250
microliters

-

Skin - Mild irritant

Rabbit

-

435
milligrams

-

Skin - Moderate irritant

Rabbit

-

24 hours 20
milligrams

-

Skin - Moderate irritant

Rabbit

-

500
milligrams

-

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11. Toxicological information

Conclusion/Summary

:

Not available.

Teratogenicity

Conclusion/Summary

:

Not available.

Reproductive toxicity

Conclusion/Summary

:

Not available.

12. Ecological information

Ecotoxicity

:

No known significant effects or critical hazards.

Aquatic ecotoxicity

acetone

Acute EC50 20.565 mg/l Marine water

Algae - Ulva pertusa

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 10000 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 100 mg/l Fresh water

Fish - Pimephales promelas ­Juvenile (Fledgling, Hatchling,
Weanling)

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna ­Neonate

21 days

toluene

Acute EC50 433 ppm Marine water

Algae - Skeletonema costatum

96 hours

Acute EC50 12500 µg/l Fresh water

Algae - Pseudokirchneriella
subcapitata

72 hours

Acute EC50 11600 µg/l Fresh water

Crustaceans - Gammarus
pseudolimnaeus - Adult

48 hours

Acute EC50 6000 µg/l Fresh water

Daphnia - Daphnia magna ­Juvenile (Fledgling, Hatchling,
Weanling)

48 hours

Acute LC50 5500 µg/l Fresh water

Fish - Oncorhynchus kisutch - Fry

96 hours

Chronic NOEC 500000 µg/l Fresh water

Algae - Pseudokirchneriella
subcapitata

96 hours

Chronic NOEC 1000 µg/l Fresh water

Daphnia - Daphnia magna

21 days

Product/ingredient name

Species

Result

Exposure

Conclusion/Summary

:

Not available.

Persistence/degradability

Conclusion/Summary

:

Not available.

Other adverse effects

:

No known significant effects or critical hazards.

The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Waste disposal

13. Disposal considerations

:

United States - RCRA Toxic hazardous waste "U" List

Acetone (I); 2-Propanone (I)

67-64-1

Listed

U002

Toluene; Benzene, methyl-

108-88-3

Listed

U220

Ingredient

CAS #

Status

Reference
number

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13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14. Transport information

ORM-D

Use ORM-D Label

Reportable quantity

13333.3 lbs / 6053.3
kg [2161 gal / 8180.2
L]
Package sizes
shipped in quantities
less than the product
reportable quantity are
not subject to the RQ
(reportable quantity)
transportation
requirements.

DOT Classification

TDG Classification

ORM-D

Consumer
commodity ORM-D

-

-

Consumer
commodity ORM-D

-

ADR/RID Class

Aerosol. Flammable

2

-

IMDG Class

Aerosols, flammable
(hexane, propane)

2.1-Aerosol. Flammable

1950

IATA-DGR Class

2.1

Regulatory
information

UN number

Proper shipping
name

Classes

PG*

Label

Additional
information

-

1950

1950

Tunnel code

(D)

-

-

-

-

Mexico
Classification

-

Consumer
commodity ORM-D

ORM-D

-

­PG* : Packing group

Flammable aerosol
Irritating material
Target organ effects

HCS Classification

15. Regulatory information

U.S. Federal regulations

Clean Water Act (CWA) 307

: toluene

Clean Water Act (CWA) 311

: toluene

Clean Air Act (CAA) 112 regulated flammable substances

: propane; Butane

:

:

Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)

:

Listed

TSCA 8(a) PAIR

: 2-methoxy-1-methylethyl acetate

TSCA 8(a) CDR Exempt/Partial exemption

: Not determined

United States inventory (TSCA 8b)

: All components are listed or exempted.

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15. Regulatory information

The following components are listed: ISOHEXANE; PROPANE; BUTANE; ACETONE;
3-METHYLPENTANE; TOLUENE; 2,3-DIMETHYLBUTANE; 2,2-DIMETHYLBUTANE

Massachusetts

:

SARA 313

Product name

CAS number

%

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

toluene

108-88-3

5 - 10

toluene

108-88-3

5 - 10

Form R - Reporting
requirements

Supplier notification

California Prop. 65

Clean Air Act Section 602
Class I Substances

:

Not listed

Clean Air Act Section 602
Class II Substances

:

Not listed

DEA List I Chemicals
(Precursor Chemicals)

:

Not listed

DEA List II Chemicals
(Essential Chemicals)

:

Listed

New York

:

The following components are listed: Acetone; 2-Propanone; Toluene

New Jersey

:

The following components are listed: 2-METHYLPENTANE; ISOHEXANE; PROPANE;
BUTANE; ACETONE; 2-PROPANONE; TOLUENE; BENZENE, METHYL-; 2,
3-DIMETHYLBUTANE; BUTANE, 2,3-DIMETHYL-; NEOHEXANE; 2,2 DIMETHYL
BUTANE

Pennsylvania

:

The following components are listed: PENTANE, 2-METHYL-; PROPANE; BUTANE;
2-PROPANONE; PENTANE, 3-METHYL-; BENZENE, METHYL-; BUTANE, 2,
3-DIMETHYL-; BUTANE, 2,2-DIMETHYL-

State regulations

SARA 302/304

SARA 304 RQ

:

Not applicable.

No products were found.

Composition/information on ingredients

SARA 311/312

Classification

:

Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard

hexane

15 - 30

Yes.

No.

No.

No.

Yes.

propane

10 - 15

Yes.

Yes.

No.

No.

Yes.

Butane

10 - 15

Yes.

Yes.

No.

No.

Yes.

acetone

5 - 15

Yes.

No.

No.

Yes.

Yes.

3-methylpentane

5 - 15

Yes.

No.

No.

No.

Yes.

toluene

5 - 10

Yes.

No.

No.

Yes.

Yes.

2,3-dimethylbutane

5 - 10

Yes.

No.

No.

No.

Yes.

2-methoxy-1-methylethyl acetate

2 - 5

Yes.

No.

No.

No.

Yes.

2,2-dimethylbutane

1 - 5

No.

No.

No.

No.

Yes.

Name

%

Fire
hazard

Sudden
release of
pressure

Reactive

Immediate
(acute)
health
hazard

Delayed
(chronic)
health
hazard

Composition/information on ingredients

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15. Regulatory information

WARNING:

This product contains a chemical known to the State of California to cause birth defects or other

reproductive harm.

Australia inventory (AICS)

: All components are listed or exempted.

China inventory (IECSC)

: All components are listed or exempted.

Japan inventory

: Not determined.

Korea inventory

: All components are listed or exempted.

Malaysia Inventory (EHS Register)

: Not determined.

New Zealand Inventory of Chemicals (NZIoC)

: All components are listed or exempted.

Philippines inventory (PICCS)

: All components are listed or exempted.

Taiwan inventory (CSNN)

: Not determined.

International regulations

International lists

:

toluene

No.

Yes.

No.

7000 µg/day
(ingestion)
13000 µg/day
(inhalation)

Ingredient name

Cancer

Reproductive

No significant risk
level

Maximum
acceptable dosage
level

Canada inventory

:

All components are listed or exempted.

Chemical Weapons
Convention List Schedule
I Chemicals

:

Not listed

Chemical Weapons
Convention List Schedule
II Chemicals

:

Not listed

Chemical Weapons
Convention List Schedule
III Chemicals

:

Not listed

16. Other information

Hazardous Material
Information System (U.S.A.)

2

3

1

National Fire Protection
Association (U.S.A.)

Health

Flammability

Physical hazards

EXTREMELY FLAMMABLE AEROSOL. CAUSES EYE IRRITATION. MAY BE
HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. CONTAINS
MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL
DATA.

Label requirements

:

:

:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].

The customer is responsible for determining the PPE code for this material.

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16. Other information

132

Health

Special

Instability/Reactivity

Flammability

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of printing

Date of issue

Date of previous issue

Version

6/13/2013.

:

:::

Indicates information that has changed from previously issued version.

6/13/2013.

6/13/2013.

2

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not
the complete and official position of the National Fire Protection Association, on the referenced subject which is
represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA
49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not,
anyone using the 704 systems to classify chemicals does so at their own risk.

Prepared by

:

Not available.

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