Chemtronics AR CTAR-12 User Manual

Page 1
Konform® AR - CTAR12, CTAR-12C
(formerly Konform® AR2000)
Konform® AR
0708
CTAR12, CTAR-12C
ITW Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152
Tel. 770-424-4888 or toll free 800-645-5244
Chemtrec - 1-800-424-9300 or collect 703-527-3887 24/7
ITW Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152
5/21/2013.
Material Safety Data Sheet
Product name
Supplier
Synonym
Trade name
Manufacturer
Code
MSDS #
Validation date
Print date
In case of emergency
1. Product and company identification
Konform® AR - CTAR12, CTAR-12C
:
:
:
:
: :::
:
:
Product type
:
Aerosol.
5/21/2013.
Inhalation Dermal Eyes
Signal word
2. Hazards identification
Routes of entry
Potential acute health effects
Toxic by inhalation. At very high concentrations, can displace the normal air and cause suffocation from lack of oxygen. Vapors may cause drowsiness and dizziness.
Severely irritating to eyes. Risk of serious damage to eyes.
Harmful if swallowed. Irritating to mouth, throat and stomach.
Moderately irritating to the skin.
Eyes
Skin
Inhalation Ingestion
Physical state
Liquid. [Aerosol.]
DANGER!
FLAMMABLE AEROSOL. HARMFUL IF INHALED. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
:
:::
:::
Odor
:
Fruity. Ethereal. Solvent. [Strong]
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential chronic health effects
Color
:
Clear. Colorless.
Emergency overview
Hazard statements
:
Precautionary measures
:
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks, open flames and hot surfaces. ­No smoking. Keep container closed. Use personal protective equipment as required. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Wash thoroughly after handling.
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2. Hazards identification
See toxicological information (Section 11)
Medical conditions aggravated by over­exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product.
:
Carcinogenicity
:
Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
No known significant effects or critical hazards.
Developmental effects
:
No known significant effects or critical hazards.
Chronic effects
:
Contains material that can cause target organ damage.
Fertility effects
:
No known significant effects or critical hazards.
Over-exposure signs/symptoms
Ingestion
:
Adverse symptoms may include the following: Irritating to mouth, throat and stomach. nausea or vomiting
Skin
:
Adverse symptoms may include the following: irritation redness
Eyes
:
Adverse symptoms may include the following: pain or irritation watering redness
Inhalation
:
Adverse symptoms may include the following: respiratory tract irritation coughing headache dizziness/vertigo drowsiness/fatigue
Target organs
:
Contains material which causes damage to the following organs: the nervous system, eye, lens or cornea. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the reproductive system, liver, heart, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS). n-butyl acetate
123-86-4
10 - 20
propyl acetate
109-60-4
10 - 20
2-methoxy-1-methylethyl acetate
108-65-6
10 - 20
ethanol
64-17-5
10 - 20
Butane
106-97-8
10 - 20
propane
74-98-6
10 - 20
butanone
78-93-3
2 - 5
3. Composition/information on ingredients
Name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
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Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
4. First aid measures
Eye contact
Skin contact
Inhalation Ingestion
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Notes to physician
:
::: :
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Use an extinguishing agent suitable for the surrounding fire.
5. Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Special protective equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
Special exposure hazards
:
None known.
Suitable
:
Not suitable
:
Hazardous thermal decomposition products
:
Decomposition products may include the following materials: carbon dioxide carbon monoxide
Flammability of the product
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions
6. Accidental release measures
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Personal precautions
:
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6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods for cleaning up
Do not store below the following temperature: 48.889°C (120°F). Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Empty containers retain product residue and can be hazardous.
7. Handling and storage
Handling
Storage
:
:
n-butyl acetate
ACGIH TLV (United States, 3/2012).
STEL: 200 ppm 15 minutes. TWA: 150 ppm 8 hours.
NIOSH REL (United States, 1/2013).
STEL: 950 mg/m³ 15 minutes. STEL: 200 ppm 15 minutes. TWA: 710 mg/m³ 10 hours. TWA: 150 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 710 mg/m³ 8 hours. TWA: 150 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 950 mg/m³ 15 minutes. STEL: 200 ppm 15 minutes. TWA: 710 mg/m³ 8 hours. TWA: 150 ppm 8 hours.
propyl acetate
ACGIH TLV (United States, 3/2012).
STEL: 1040 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes.
8. Exposure controls/personal protection
Ingredient
Exposure limits
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8. Exposure controls/personal protection
TWA: 835 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
NIOSH REL (United States, 1/2013).
STEL: 1050 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 840 mg/m³ 10 hours. TWA: 200 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 840 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 1050 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 840 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
2-methoxy-1-methylethyl acetate
AIHA WEEL (United States, 10/2011).
TWA: 50 ppm 8 hours.
ethanol
ACGIH TLV (United States, 3/2012).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 1/2013).
TWA: 1900 mg/m³ 10 hours. TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.
Butane
ACGIH TLV (United States, 3/2012).
TWA: 1000 ppm 8 hours.
NIOSH REL (United States, 1/2013).
TWA: 1900 mg/m³ 10 hours. TWA: 800 ppm 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1900 mg/m³ 8 hours. TWA: 800 ppm 8 hours.
propane
ACGIH TLV (United States, 3/2012).
TWA: 1000 ppm 8 hours.
NIOSH REL (United States, 1/2013).
TWA: 1800 mg/m³ 10 hours. TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 6/2010).
TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.
butanone
ACGIH TLV (United States, 3/2012).
STEL: 885 mg/m³ 15 minutes. STEL: 300 ppm 15 minutes. TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
NIOSH REL (United States, 1/2013).
STEL: 885 mg/m³ 15 minutes. STEL: 300 ppm 15 minutes. TWA: 590 mg/m³ 10 hours. TWA: 200 ppm 10 hours.
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8. Exposure controls/personal protection
OSHA PEL (United States, 6/2010).
TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 885 mg/m³ 15 minutes. STEL: 300 ppm 15 minutes. TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Personal protection
Eyes
Skin
Respiratory
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Hands
:
Engineering measures
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Recommended monitoring procedures
:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
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>210°C (>410°F)
Liquid. [Aerosol.]
<1 [Air = 1]
1.6 kPa (12 mm Hg) [room temperature]
Fruity. Ethereal. Solvent. [Strong]
Clear. Colorless.
Boiling/condensation point
>1 (butyl acetate = 1)
9. Physical and chemical properties
Physical state
Vapor pressure
Vapor density
Evaporation rate
Odor
Color::::
:
::Flash point
:
Closed cup: -1.1111°C (30°F) [Tagliabue.]
Type of aerosol
:
Spray
Heat of combustion
:
-19.39 kJ/g
Aerosol product
The product is stable.
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Avoid all possible sources of ignition (spark or flame).
10. Stability and reactivity
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition products
:
:
:
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological information
Acute toxicity
n-butyl acetate
LC50 Inhalation Gas.
Rat
390 ppm
4 hours
LD50 Dermal
Rabbit
>17600 mg/kg
-
LD50 Oral
Rat
10768 mg/kg
-
propyl acetate
LD50 Oral
Rat
9370 mg/kg
-
2-methoxy-1-methylethyl acetate
LD50 Dermal
Rabbit
>5 g/kg
-
LD50 Oral
Rat
8532 mg/kg
-
ethanol
LC50 Inhalation Vapor
Rat
124700 mg/m³
4 hours
LD50 Oral
Rat
7 g/kg
-
Butane
LC50 Inhalation Vapor
Rat
658000 mg/m³
4 hours
butanone
LD50 Dermal
Rabbit
6480 mg/kg
-
LD50 Oral
Rat
2737 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Chronic toxicity
Conclusion/Summary
:
Not available.
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
Species
n-butyl acetate
Eyes - Moderate irritant
Rabbit
-
100 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 500 milligrams
-
propyl acetate
Eyes - Mild irritant
Rabbit
-
24 hours 500 milligrams
-
Skin - Mild irritant
Rabbit
-
500 milligrams
-
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11. Toxicological information
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Classification
n-butyl acetate
---A4-
None.
propyl acetate
-----
None.
2-methoxy-1-methylethyl acetate
-----
None.
ethanol
-1-A3-
-
propane
-----
None.
butanone
-----
None.
Product/ingredient name
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Conclusion/Summary
:
Not available.
Sensitizer
Conclusion/Summary
:
Not available.
ethanol
Eyes - Mild irritant
Rabbit
-
24 hours 500 milligrams
-
Eyes - Moderate irritant
Rabbit
-
0.066666667 minutes 100 milligrams
-
Eyes - Moderate irritant
Rabbit
-
100 microliters
-
Eyes - Severe irritant
Rabbit
-
500 milligrams
-
Skin - Mild irritant
Rabbit
-
400 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 20 milligrams
-
butanone
Skin - Mild irritant
Rabbit
-
24 hours 14 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 500 milligrams
-
12. Ecological information
Ecotoxicity
:
No known significant effects or critical hazards.
Aquatic ecotoxicity
n-butyl acetate
Acute LC50 32000 µg/l Marine water
Crustaceans - Artemia salina ­Nauplii
48 hours
Acute LC50 62000 µg/l
Fish - Danio rerio
96 hours
propyl acetate
Acute LC50 60000 to 64000 µg/l Fresh water
Fish - Pimephales promelas
96 hours
ethanol
Acute EC50 17.921 mg/l Marine water
Algae - Ulva pertusa
96 hours
Acute EC50 2000 µg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 25500 µg/l Marine water
Crustaceans - Artemia franciscana - Larvae
48 hours
Acute LC50 42000 µg/l Fresh water
Fish - Oncorhynchus mykiss
4 days
Product/ingredient name
Species
Result
Exposure
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12. Ecological information
Chronic NOEC 4.995 mg/l Marine water
Algae - Ulva pertusa
96 hours
Chronic NOEC 0.375 ul/L Fresh water
Fish - Gambusia holbrooki ­Larvae
12 weeks
butanone
Acute EC50 >500000 µg/l Marine water
Algae - Skeletonema costatum
96 hours
Acute LC50 520000 µg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 400 ppm Marine water
Fish - Cyprinodon variegatus ­Juvenile (Fledgling, Hatchling, Weanling)
96 hours
Conclusion/Summary
:
Not available.
Persistence/degradability
Conclusion/Summary
:
Not available.
Other adverse effects
:
No known significant effects or critical hazards.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
Waste disposal
13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.
United States - RCRA Toxic hazardous waste "U" List
Methyl ethyl ketone (MEK) (I,T); 2-Butanone (I,T)
78-93-3
Listed
U159
Ingredient
CAS #
Status
Reference number
14. Transport information
ORM-D
Use ORM-D Label
Reportable quantity
33333.3 lbs / 15133.3 kg [4393.2 gal / 16630 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.
DOT Classification
TDG Classification
ORM-D
Consumer commodity ORM-D
-
-
Consumer commodity ORM-D
-
Regulatory information
UN number
Proper shipping name
Classes
PG*
Label
Additional information
-
Use ORM-D Label
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14. Transport information
ADR/RID Class
Aerosol. Flammable
2.1-IMDG Class
Aerosols, flammable (propane, Butane)
2.1
-
Aerosol. Flammable
1950
IATA-DGR Class
2.1
-
UN1950
1950
Tunnel code
(D)
-
Cargo Aircraft Only
Quantity limitation: 150 kg Packaging instructions: 203
Limited Quantities ­Passenger Aircraft
Quantity limitation: 75 kg Packaging instructions: 203
Mexico Classification
-
Consumer commodity ORM-D
ORM-D
-
Use ORM-D Label PG* : Packing group
Flammable aerosol Toxic material Irritating material Carcinogen Target organ effects
HCS Classification
15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311
: n-butyl acetate
Clean Air Act (CAA) 112 regulated flammable substances
: Butane; propane
:
:
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602 Class I Substances
:
Not listed
Clean Air Act Section 602 Class II Substances
:
Not listed
DEA List I Chemicals (Precursor Chemicals)
:
Not listed
DEA List II Chemicals (Essential Chemicals)
:
Listed
TSCA 8(a) PAIR
: 2-methoxy-1-methylethyl acetate
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: Not determined.
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
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15. Regulatory information
The following components are listed: BUTYL ACETATE; N-PROPYL ACETATE; ETHYL ALCOHOL; BUTANE; PROPANE; METHYL ETHYL KETONE (MEK)
WARNING:
This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Massachusetts
Australia inventory (AICS)
: Not determined.
China inventory (IECSC)
: Not determined.
Japan inventory
: Not determined.
Korea inventory
: Not determined.
Malaysia Inventory (EHS Register)
: Not determined.
New Zealand Inventory of Chemicals (NZIoC)
: Not determined.
Philippines inventory (PICCS)
: Not determined.
Taiwan inventory (CSNN)
: Not determined.
International regulations
International lists
:
:
SARA 313
Product name
CAS number
%
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
ethanol
No.
Yes.
No.
No.
Ingredient name
Cancer
Reproductive
No significant risk level
Maximum acceptable dosage level
butanone
78-93-3
2 - 5
butanone
78-93-3
2 - 5
Form R - Reporting requirements
Supplier notification
California Prop. 65
Canada inventory
:
Not determined.
New York
:
The following components are listed: Butyl acetate; Methyl ethyl ketone; 2-Butanone
New Jersey
:
The following components are listed: n-BUTYL ACETATE; ACETIC ACID, BUTYL ESTER; n-PROPYL ACETATE; ACETIC ACID, PROPYL ESTER; ETHYL ALCOHOL; ALCOHOL; BUTANE; PROPANE; METHYL ETHYL KETONE; 2-BUTANONE
Pennsylvania
:
The following components are listed: ACETIC ACID, BUTYL ESTER; ACETIC ACID, PROPYL ESTER; DENATURED ALCOHOL; BUTANE; PROPANE; 2-BUTANONE
State regulations
Classification
:
Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard
n-butyl acetate
10 - 20
Yes.
No.
No.
Yes.
Yes.
propyl acetate
10 - 20
Yes.
No.
No.
No.
Yes.
2-methoxy-1-methylethyl acetate
10 - 20
Yes.
No.
No.
No.
Yes.
ethanol
10 - 20
Yes.
No.
No.
Yes.
Yes.
Butane
10 - 20
Yes.
Yes.
No.
No.
Yes.
propane
10 - 20
Yes.
Yes.
No.
No.
Yes.
butanone
2 - 5
Yes.
No.
No.
Yes.
Yes.
Name
%
Fire hazard
Sudden release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
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15. Regulatory information
Chemical Weapons Convention List Schedule I Chemicals
:
Not listed
Chemical Weapons Convention List Schedule II Chemicals
:
Not listed
Chemical Weapons Convention List Schedule III Chemicals
:
Not listed
16. Other information
Hazardous Material Information System (U.S.A.)
1
3
1
131
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
FLAMMABLE AEROSOL. HARMFUL IF INHALED. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Label requirements
:
Notice to reader
Date of printing
Date of issue
Date of previous issue
Version
5/21/2013.
:::
:
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Indicates information that has changed from previously issued version.
5/21/2013.
5/21/2013.
2
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Prepared by
:
Not available.
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16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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