Chemtronics 2702 User Manual

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Page 1

Ion Emitter Tip Cleaner

propan-2-ol; 2-Propanol; isopropanol; isopropyl alcohol

Ion Emitter Tip Cleaner

1510

2702

Industrial applications

Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152

Tel. 770-424-4888 or toll free 800-645-5244

Chemtrec - 1-800-424-9300 or collect 703-527-3887 24/7

Chemtronics 8125 Cobb Center Drive Kennesaw, GA 30152

Tel. 770-424-4888 or toll free 800-645-5244

10/21/2013.

Material Safety Data Sheet

Product name

Supplier

Synonym

Trade name

Material uses

Manufacturer

Code

MSDS #

Validation date

Print date

In case of emergency

1. Product and company identification

Ion Emitter Tip Cleaner

: :::

Product type

Liquid.

10/21/2013.

Oral dermal Ocular Inhalation

Signal word

2. Hazards identification

Routes of entry

Potential acute health effects

Harmful by inhalation. At very high concentrations, can displace the normal air and cause suffocation from lack of oxygen.

Severely irritating to eyes. Risk of serious damage to eyes.

Harmful if swallowed.

Slightly irritating to the skin.

Eyes

Skin

Inhalation Ingestion

Physical state

Liquid.

WARNING!

FLAMMABLE LIQUID AND VAPOR. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

:::

Odor

Alcohol-like.

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Potential chronic health effects

Carcinogenicity

No known significant effects or critical hazards.

Chronic effects

May cause target organ damage, based on animal data.

Color

Colorless.

Emergency overview

Hazard statements

Precautionary measures

Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks and flame. Keep container tightly closed. Wash thoroughly after handling.

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2. Hazards identification

See toxicological information (Section 11)

Medical conditions aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

No known significant effects or critical hazards.

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Over-exposure signs/symptoms

Ingestion

Adverse symptoms may include the following: Irritating to mouth, throat and stomach. nausea or vomiting

Skin

Adverse symptoms may include the following: irritation redness

Eyes

Adverse symptoms may include the following: pain or irritation watering redness

Inhalation

Adverse symptoms may include the following: dizziness/vertigo drowsiness/fatigue headache

Target organs

May cause damage to the following organs: blood, kidneys, liver, spleen, upper respiratory tract, skin, eyes, central nervous system (CNS), eye, lens or cornea. Isopropyl alcohol

67-63-0

100

3. Composition/information on ingredients

Name

CAS number

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

4. First aid measures

Eye contact

Skin contact

Inhalation Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Notes to physician

: : :

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

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Use dry chemical,

CO₂,

water spray (fog) or foam.

5. Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special exposure hazards

Do not use water jet.

Suitable

Not suitable

Hazardous thermal decomposition products

Decomposition products may include the following materials: carbon dioxide carbon monoxide

Flammability of the product

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Environmental precautions

6. Accidental release measures

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Personal precautions

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods for cleaning up

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical

7. Handling and storage

Handling

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7. Handling and storage

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

(ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

Isopropyl alcohol

ACGIH TLV (United States, 3/2012).

TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes.

OSHA PEL 1989 (United States, 3/1989).

TWA: 400 ppm 8 hours. TWA: 980 mg/m³ 8 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m³ 15 minutes.

NIOSH REL (United States, 1/2013).

TWA: 400 ppm 10 hours. TWA: 980 mg/m³ 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2010).

TWA: 400 ppm 8 hours. TWA: 980 mg/m³ 8 hours.

Isopropyl alcohol

ACGIH TLV (United States, 3/2012).

STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours.

NIOSH REL (United States, 1/2013).

STEL: 1225 mg/m³ 15 minutes. STEL: 500 ppm 15 minutes. TWA: 980 mg/m³ 10 hours. TWA: 400 ppm 10 hours.

OSHA PEL (United States, 6/2010).

TWA: 980 mg/m³ 8 hours. TWA: 400 ppm 8 hours.

OSHA PEL 1989 (United States, 3/1989).

STEL: 1225 mg/m³ 15 minutes. STEL: 500 ppm 15 minutes. TWA: 980 mg/m³ 8 hours. TWA: 400 ppm 8 hours.

8. Exposure controls/personal protection

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Ingredient

Exposure limits

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8. Exposure controls/personal protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Hands

Engineering measures

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

83°C (181.4°F)

Liquid.

-90°C (-130°F)

0.79

2.1 [Air = 1]

4.4 kPa (33.002681467 mm Hg) [room temperature]

Alcohol-like.

Colorless.

Boiling/condensation point

Melting/freezing point

1.7 (butyl acetate = 1)

9. Physical and chemical properties

Physical state

Relative density

Vapor pressure

Vapor density

Evaporation rate

Odor

Color::::

:::::

Flash point

Closed cup: 11.7°C (53.1°F)

456°C (852.8°F)

Auto-ignition temperature

Flammable limits

Lower: 2% Upper: 12%

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The product is stable.

Reactive or incompatible with the following materials: oxidizing materials

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.

10. Stability and reactivity

Chemical stability

Conditions to avoid Incompatible materials

Hazardous decomposition products

: :

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

11. Toxicological information

Acute toxicity

Isopropyl alcohol

LD50 Dermal

Rabbit

12800 mg/kg

LD50 Oral

Rat

5000 mg/kg

Isopropyl alcohol

LD50 Dermal

Rabbit

12800 mg/kg

LD50 Oral

Rat

5000 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Conclusion/Summary

Not available.

Chronic toxicity

Conclusion/Summary

Not available.

Carcinogenicity

Conclusion/Summary

Not available.

Mutagenicity

Conclusion/Summary

Not available.

Teratogenicity

Classification

Isopropyl alcohol

-3-A4-

None.

Product/ingredient name

ACGIH

EPA

NIOSH

NTP

IARC

OSHA

Irritation/Corrosion

Product/ingredient name

Result

Score

Exposure

Observation

Conclusion/Summary

Not available.

Sensitizer

Conclusion/Summary

Not available.

Species

Isopropyl alcohol

Eyes - Moderate irritant

Rabbit

24 hours 100 milligrams

Eyes - Moderate irritant

Rabbit

10 milligrams

Eyes - Severe irritant

Rabbit

100 milligrams

Skin - Mild irritant

Rabbit

500 milligrams

Isopropyl alcohol

Eyes - Moderate irritant

Rabbit

24 hours 100 milligrams

Eyes - Moderate irritant

Rabbit

10 milligrams

Eyes - Severe irritant

Rabbit

100 milligrams

Skin - Mild irritant

Rabbit

500 milligrams

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11. Toxicological information

Conclusion/Summary

Not available.

Reproductive toxicity

Conclusion/Summary

Not available.

12. Ecological information

Partition coefficient: noctanol/water

0.05

Ecotoxicity

This product shows a low bioaccumulation potential.

Bioconcentration factor

Not available.

Aquatic ecotoxicity

Isopropyl alcohol

Acute LC50 1400000 to 1950000 µg/l Marine water

Crustaceans - Crangon crangon

48 hours

Acute LC50 1400000 µg/l

Fish - Gambusia affinis

96 hours

Isopropyl alcohol

Acute LC50 1400000 µg/l Marine water

Crustaceans - Crangon crangon

48 hours

Acute LC50 1400000 µg/l

Fish - Gambusia affinis

96 hours

Product/ingredient name

Species

Result

Exposure

Conclusion/Summary

Not available.

Persistence/degradability

Conclusion/Summary

Not available.

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Waste disposal

13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

14. Transport information

ORM-D

DOT Classification

TDG Classification

ORM-D

Consumer commodity ORM-D

--Consumer commodity ORM-D

Regulatory information

UN number

Proper shipping name

Classes

PG*

Label

Additional information

Mexico Classification

Consumer commodity ORM-D

ORM-D

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14. Transport information

ADR/RID Class

ISOPROPANOL

IMDG Class

ISOPROPANOL

3IIISOPROPANOL

UN1219

IATA-DGR Class

UN1219

PG* : Packing group

Flammable liquid Irritating material Target organ effects

HCS Classification

15. Regulatory information

U.S. Federal regulations

SARA 313

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)

Not listed

Clean Air Act Section 602 Class I Substances

Not listed

Clean Air Act Section 602 Class II Substances

Not listed

DEA List I Chemicals (Precursor Chemicals)

Not listed

DEA List II Chemicals (Essential Chemicals)

Not listed

TSCA 8(a) CDR Exempt/Partial exemption

: Not determined

United States inventory (TSCA 8b)

: All components are listed or exempted.

SARA 302/304

SARA 304 RQ

Not applicable.

No products were found.

Composition/information on ingredients

SARA 311/312

Classification

Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard

Isopropyl alcohol

100

Yes.

No.

Yes.

Name

Fire hazard

Sudden release of pressure

Reactive

Immediate (acute) health hazard

Delayed (chronic) health hazard

Composition/information on ingredients

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15. Regulatory information

The following components are listed: ISOPROPYL ALCOHOL

Massachusetts

Australia inventory (AICS)

: All components are listed or exempted.

China inventory (IECSC)

: All components are listed or exempted.

Japan inventory

: All components are listed or exempted.

Korea inventory

: All components are listed or exempted.

Malaysia Inventory (EHS Register)

: All components are listed or exempted.

New Zealand Inventory of Chemicals (NZIoC)

: All components are listed or exempted.

Philippines inventory (PICCS)

: All components are listed or exempted.

Taiwan inventory (CSNN)

: Not determined.

International regulations

International lists

Product name

CAS number

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

Isopropyl alcohol

67-63-0

100

Isopropyl alcohol

67-63-0

100

Form R - Reporting requirements

Supplier notification

Canada inventory

All components are listed or exempted.

Chemical Weapons Convention List Schedule I Chemicals

Not listed

Chemical Weapons Convention List Schedule II Chemicals

Not listed

Chemical Weapons Convention List Schedule III Chemicals

Not listed

New York

None of the components are listed.

New Jersey

The following components are listed: ISOPROPYL ALCOHOL; 2-PROPANOL

Pennsylvania

The following components are listed: 2-PROPANOL

State regulations

16. Other information

Hazardous Material Information System (U.S.A.)

National Fire Protection Association (U.S.A.)

Health

Flammability

Physical hazards

FLAMMABLE LIQUID AND VAPOR. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

Label requirements

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

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16. Other information

031

Health

Special

Instability/Reactivity

Flammability

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of printing

Date of issue

Date of previous issue

Version

10/21/2013.

::::Indicates information that has changed from previously issued version.

10/21/2013.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Prepared by

Not available.

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