Page 1
SAFETY DATA SHEET
Issuing Date: 17-Apr-2015 Revision Date: 17-Apr-2015
1. IDENTIFICATION
Product Name
Product ID:
Product Type:
Recommended Use
Restrictions on Use
Manufacturer
E-mail Address
Cheer Fresh Clean Scent
99474116_RET_NG
Finished Product - Consumer (Retail) Use Only
Laundry Care
Use only as directed on label.
PROCTER & GAMBLE - Fabric and Home Care Division
Ivorydale Technical Centre
5289 Spring Grove Avenue
Cincinnati, Ohio 45217-1087 USA
Procter & Gamble Inc.
P.O. Box 355, Station A
Toronto, ON M5W 1C5
1-800-331-3774
Version 1
Emergency Telephone
Transportation (24 HR)
CHEMTREC - 1-800-424-9300
(U.S./ Canada) or 1-703-527-3887
Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumer
duration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is being
provided as a courtesy to help assist in the safe handling and proper use of the product.
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Hazard Category
Skin corrosion/irritation
Eye Damage / Irritation
Signal Word
Hazard Statements
Hazard pictograms
Category 2
Category 2A
WARNING
Causes serious eye irritation
Causes skin irritation
Page 1 / 8
Page 2
99474116_RET_NG - Cheer Fresh Clean Scent
Revision Date: 17-Apr-2015
Precautionary Statements Prevention
Precautionary Statements Response
Precautionary Statements Storage
Precautionary Statements Disposal
Hazards not otherwise classified
(HNOC)
Wash hands thoroughly after handling
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF SWALLOWED:
Drink 1 or 2 glasses of water
IF ON SKIN:
Rinse with plenty of water
If skin irritation occurs, get medical advice/attention
None
None
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
Chemical Name Synonyms Trade Secret CAS-No Weight %
Sodium carbonate - No 497-19-8 35 - 40
Silicic acid, aluminum sodium salt - No 1344-00-9 15 - 20
Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
Carbonic acid disodium salt, compd.
with hydrogen peroxide
Silicic acid, sodium salt - No 1344-09-8 1 - 5
Sulfuric acid, mono-C14-18-alkyl
esters, sodium salts
Heptadecanol, hydrogen sulfate,
branched, sodium salt
Poly(oxy-1,2-ethanediyl),
alpha-sulfo-omega-hydroxy-,
C10-16-alkyl ethers, sodium salts
Hexadecanol, hydrogen sulfate,
branched, sodium salt
- No 68081-81-2 5 - 10
- No 15630-89-4 1 - 5
- No 68081-98-1 1 - 5
- No 343978-15-4 1 - 5
- No 68585-34-2 1 - 5
- No 343978-24-5 1 - 5
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact
Skin contact
Rinse with plenty of water. Get medical attention immediately if irritation persists.
Rinse with plenty of water. Get medical attention if irritation develops and persists.
Page 2 / 8
Page 3
99474116_RET_NG - Cheer Fresh Clean Scent Revision Date: 17-Apr-2015
Ingestion
Inhalation
Most important symptoms/effects,
acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician
Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if
symptoms occur.
Move to fresh air. If symptoms persist, call a physician.
None under normal use conditions.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Unsuitable Extinguishing Media
Special hazard
Special protective equipment for
fire-fighters
Specific hazards arising from the
chemical
Dry chemical, CO 2, alcohol-resistant foam or water spray.
None.
None known.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Advice for emergency responders
Methods and materials for containment and cleaning up
Methods for containment
Methods for cleaning up
Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Use personal protective equipment as required.
Prevent dust cloud. Prevent further leakage or spillage if safe to do so.
Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with
local regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Incompatible products
Use personal protective equipment as required. Keep container closed when not in use.
Never return spills in original containers for re-use. Keep out of the reach of children.
Keep containers tightly closed in a dry, cool and well-ventilated place.
None known.
Control parameters
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Page 3 / 8
Page 4
99474116_RET_NG - Cheer Fresh Clean Scent
Revision Date: 17-Apr-2015
Exposure Guidelines
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL
Silicic acid, aluminum sodium salt 1344-00-9 TWA: 1 mg/m3 respirable
Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia
Silicic acid, aluminum sodium
salt
.
fraction
1344-00-9 TWA: 1 mg/m
3
TWA: 1.0 mg/m
No relevant exposure guidelines for other ingredients
Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:
Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction
Personal Protective Equipment
Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
3
Hand Protection Distribution, Workplace and Household Settings:
For sensitive skin or prolonged use, wear gloves
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C
Appearance
Odor
Odor threshold
solid
white powder
Scented
No information available
Property
pH value
Melting/freezing point
Boiling point/boiling range
Flash point
Values
10 - 11.5
No information available
No information available
No information available
Page 4 / 8
Note
Page 5
99474116_RET_NG - Cheer Fresh Clean Scent
Revision Date: 17-Apr-2015
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower Flammability Limit
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Viscosity of Product
VOC Content (%)
Reactivity
Stability
Hazardous polymerization
Hazardous Reactions
No information available
No information available
No information available
No information available
No information available
No information available
420 -650 g/L
Moderately soluble @ 20 °C
No information available
No information available
No information available .
No information available .
No information available
Products comply with US state and federal regulations for VOC content in consumer
products.
10. STABILITY AND REACTIVITY
None under normal use conditions.
Stable under normal conditions.
Hazardous polymerization does not occur.
None under normal processing.
Conditions to Avoid
Materials to avoid
Hazardous Decomposition Products
None under normal processing.
None in particular.
None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye irritation
Skin sensitization
Respiratory sensitization
Germ cell mutagenicity
Neurological Effects
Reproductive toxicity
Developmental toxicity
Teratogenicity
STOT - single exposure
STOT - repeated exposure
Target Organ Effects
Aspiration hazard
Carcinogenicity
No known effect.
Irritating to skin.
No known effect.
Causes serious eye irritation.
No known effect.
Irritating to skin.
Causes serious eye irritation.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
No known effect.
Component Information
Page 5 / 8
Page 6
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation
Sodium carbonate 497-19-8 2800 mg/kg bw > 2000 mg/kg bw (US EPA
Silicic acid, aluminum sodium salt 1344-00-9 > 10000 mg/kg bw
Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
Carbonic acid disodium salt, compd.
with hydrogen peroxide
Silicic acid, sodium salt 1344-09-8 3400 mg/kg bw (Similar to
Poly(oxy-1,2-ethanediyl),
alpha-sulfo-omega-hydroxy-,
C10-16-alkyl ethers, sodium salts
68081-81-2 1090.00 mg/kg (rat) - -
15630-89-4 893 mg/kg bw (U.S. EPA
68585-34-2 >2001 mg/kg - -
(//OECD 401)
Office of Pesticides and
Toxic Substances (1984)
"Acute Exposure Oral
Toxicity"; standard acute
method; rat)
OECD 401; standard acute
method; rat)
12. ECOLOGICAL INFORMATION
Ecotoxicity
16 CFR 1500.40)
> 5000 mg/kg bw (//OECD
402)
> 2000 mg/kg bw (EPA
Guideline; standard acute
method; rabbit)
> 5000 mg/kg bw (Read
across data on AgSil TM
25 Potassium silicate
solution; rat)
Revision Date: 17-Apr-201599474116_RET_NG - Cheer Fresh Clean Scent
-
> 2.08 mg/L air (//OECD
403)
-
> 2.06 mg/L air (Read
across data AgSil TM 25
Potassium silicate solution;
EPA OPPTS 870.1300;
standard acute method;
rat)
The product is not expected to be hazardous to the environment.
Persistence and degradability
Bioaccumulative potential
Mobility
Other adverse effects
No information available.
No information available.
No information available.
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment
Waste from Residues / Unused
Products
Contaminated packaging
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
California Hazardous Waste Codes
331
(non-household setting)
14. TRANSPORT INFORMATION
DOT
Not regulated
IMDG
IATA
U.S. Federal Regulations
Not regulated
Not regulated
15. REGULATORY INFORMATION
Page 6 / 8
Page 7
99474116_RET_NG - Cheer Fresh Clean Scent Revision Date: 17-Apr-2015
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical Name CAS-No Hazardous
Substances RQs
Extremely Hazardous
Substances RQs
CERCLA/SARA 302
TPQ
Sodium hydroxide 1310-73-2 1000 lb -
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42):
Chemical Name CAS-No
Sodium hydroxide 1310-73-2
CWA - Reportable
Quantities
1000 lb - - X
CWA - Toxic
Pollutants
CWA - Priority
Pollutants
CWA - Hazardous
Substances
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
Chemical Name CAS-No Massachusetts
Sulfuric acid sodium salt (1:2) 7757-82-6 X
Chemical Name CAS-No Pennsylvania
Sulfuric acid sodium salt (1:2) 7757-82-6 X
Sodium hydroxide 1310-73-2 X
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Canada
This product is in compliance with CEPA for import by P&G.
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
CEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
Issuing Date:
Revision Date:
17-Apr-2015
17-Apr-2015
Page 7 / 8
Page 8
99474116_RET_NG - Cheer Fresh Clean Scent Revision Date: 17-Apr-2015
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text
End of SDS
Page 8 / 8
Loading...