Safety Data Sheet
Issue date 02-May-2019 Version 3
1. Identification of the Substance/Preparation and of the Company/Undertaking
Product Identifier
Product name
Chemical name
Other means of identification
Product code
Synonyms
Registration number(s)
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Address
Chase Products Co.
2727 Gardner Road
Broadview, IL 60155
708-865-1000
CHAMPION SPRAYON METERED INSECTICIDE SPRAY
7-7880-4
FG 438-5111-4GHS
Metered Insecticide
498-196
Flying insect killer.
See directions for use on product's label.
Manufacturer Address
Chase Products Co.
2727 Gardner Road
Broadview, IL 60155
708-865-1000
Emergency Telephone Number
Company Phone Number
24 Hour Emergency Phone Number
Emergency telephone
708-865-1000
1-800-255-3924
ChemTel 1-800-255-3924
2. Hazards Identification
Classification
This chemical is regulated by FIFRA.
Acute toxicity - Inhalation (Gases) Category 3
Acute toxicity - Inhalation (Vapors) Category 4
Skin corrosion/irritation Category 2
Aspiration toxicity Category 1
FLAMMABLE AEROSOLS
Gases Under Pressure
Label Elements
EMERGENCY OVERVIEW
DANGER
hazard statements
Toxic if inhaled
CAUSES SKIN IRRITATION
May be fatal if swallowed and enters airways
EXTREMELY FLAMMABLE AEROSOL
Contains gas under pressure; may explode if heated
Category 1
liquefied gas
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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Appearance Clear, dark yellow, light
liquid.
Precautionary Statements - Prevention
Avoid breathing fumes, mist, vapors or spray.
Use only outdoors or in a well-ventilated area
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves, protective clothing, eye protection and face protection.
Keep away from heat, sparks, open flames and hot surfaces. — No smoking
Do not spray on an open flame or other ignition source
Pressurized container: Do not pierce or burn, even after use
Precautionary Statements - Response
Specific treatment: See additional cautionary statements on this label.
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Call a POISON CENTER or doctor/physician
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Physical State Aerosol Odor Characteristic odor of insecticide and
petroleum distillate.
Hazards not otherwise classified (HNOC)
Other Information
• Toxic to aquatic life with long lasting effects
41% of the mixture consists of ingredient(s) of unknown toxicity
3. Composition/information on Ingredients
Common Name
Synonyms
Chemical Family
Formula
Chemical nature
Chemical name CAS No weight-% Trade secret
1,1-Difluoroethane 75-37-6 35-40 *
Petroleum distillates, hydrotreated light 64742-47-8 25-30 *
Heptane 142-82-5 15-20 *
Piperonyl Butoxide 51-03-6 9.0 *
Diethylene Glycol Monoethyl Ether 111-90-0 1-5 *
Pyrethrins 8000-34-7 0.9 *
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Insecticide spray.
Metered Insecticide.
Pesticide.
7-7880-4
Solvent based insecticide.
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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* The exact percentage (concentration) of composition has been withheld as a trade secret.
4. First aid measures
FIRST AID MEASURES
Eye Contact
Skin contact
Inhalation
Ingestion
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control
center or doctor for treatment advice.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for treatment advise.
If overcome by vapor, move person to fresh air. If person is not breathing, call 911 or an
ambulance, then provide artifical respiration, preferably mouth-to-mouth, if possible. Call a
poison control center or doctor for further treatment advise.
Ingestion from an aerosol product is unlikely to occur.
Prolonged contact with skin may cause allergic reactions on some individuals. Harmful if
inhaled.
Contains petroleum distillates, do not induce vomiting because of aspiration neumonia
hazard.
5. Fire-fighting measures
Suitable extinguishing media
CO2 (Carbon Dioxide), dry chemical, or water fog.
Unsuitable extinguishing media
Specific hazards arising from the chemical
Vapors are heavier than air and may travel along the ground and be ignited by pilot lights, other flames, sparks, heaters, smoking
or other ignition sources.
Hazardous combustion products
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Caution: Use of water spray when fighting fire may be inefficient.
Thermal decomposition may yield gases like carbon monoxide, carbon dioxide, hydrofluoric
acid and carbonyl halides.
Contents under pressure, keep away from heat and open flame.
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity).
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions
For emergency responders
Environmental precautions
Use with adequate general or local exhaust ventilation.
Remove all sources of ignition.
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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Environmental precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for Containment
Methods for cleaning up
Provide adequate ventilation. Avoid sources of ignition.
Clean contaminated surface thoroughly.
7. Handling and Storage
Precautions for safe handling
Advice on safe handling
Avoid contact with skin. Avoid getting spray into eyes. Do not deliberately inhale vapor or
mist. Do not contaminate food or food handling surfaces. Keep out of reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Store in a cool, dry place away from heat and open flame. Keep out of reach of children.
AEROSOL STORAGE LEVEL II (NFPA 30B).
Incompatible Materials
Avoid heat, open flame and contact with strong alkali and strong oxidizing agents.
8. Exposure Controls/Personal Protection
Control parameters
Exposure guidelines
See occupational exposure limits listed below.
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
Heptane
142-82-5
STEL: 500 ppm
TWA: 400 ppm
(vacated) TWA: 400 ppm
(vacated) TWA: 1600 mg/m
(vacated) STEL: 500 ppm
(vacated) STEL: 2000 mg/m
Appropriate engineering controls
Engineering controls
Use with adequate general or local exhaust ventilation.
Individual protection measures, such as personal protective equipment
Eye/face Protection
Skin and Body Protection
Respiratory protection
Conventional eyeglasses to guard against splashing.
Rubber, vinyl or household type gloves required.
None required if used in a well-ventilated area . Follow label directions and precautions for
the correct use of the product.
General hygiene considerations
Wash hands thoroughly after handling.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical State
Appearance
Color
Aerosol
Clear, dark yellow, light liquid.
dark yellow
TWA: 500 ppm
TWA: 2000 mg/m
Odor
Odor threshold
3
3
3
IDLH: 750 ppm
Ceiling: 440 ppm 15 min
Ceiling: 1800 mg/m3 15 min
TWA: 85 ppm
TWA: 350 mg/m
3
Characteristic odor of
insecticide and petroleum
distillate.
No information available
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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Property Values Remarks • Method
pH
Melting point/freezing point
Boiling point/boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limits
Lower Flammability Limit
Vapor pressure
Vapor Density
Relative Density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition Temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Not applicable Solvent-based product.
Not applicable No information available
Heptane 203 °F No information available
This product is an aerosol product for
which Flame Projection is 10 inches
with 0 in. flashback. Temperatures
above 122 -°F (50 °C) may cause cans
to burst.
Faster than butyl acetate. No information available
No information available
No information available
0.814 concentrate No information available
No information available
No information available
No information available
No information available
No information available
insoluble
No information available
No information available
No information available
No information available
No information available
No information available
Other Information
Softening point
Molecular weight
VOC content (%)
Density
Bulk Density
No information available
No information available
19.80
6.78 lb/gal
No information available
10. Stability and Reactivity
Reactivity
Not applicable Not applicable
Chemical stability
Stable.
Possibility of hazardous reactions
Temperatures above 130 °F may cause cans to burst with force.
hazardous polymerization
Conditions to Avoid
Temperatures above 122 °F (50 °C).
Incompatible Materials
Avoid heat, open flame and contact with strong alkali and strong oxidizing agents.
Hazardous polymerization does not occur.
Hazardous decomposition products
Thermal decomposition may yield gases like carbon monoxide, carbon dioxide, hydrofluoric acid and carbonyl halides.
11. Toxicological Information
Information on likely routes of exposure
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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Product Information
Inhalation
Eye Contact
Skin contact
Ingestion
Chemical name Oral LD50 dermal LD50 Inhalation LC50
Petroleum distillates, hydrotreated
light
64742-47-8
Heptane
142-82-5
Piperonyl Butoxide
51-03-6
Diethylene Glycol Monoethyl Ether
111-90-0
This product has not been tested as whole. See below for information on ingredients.
No data available.
No data available.
No data available.
No data available.
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h
- = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h
= 4570 mg/kg ( Rat ) = 6150 mg/kg
( Rat )
= 10502 mg/kg ( Rat ) = 4200 µL/kg ( Rabbit ) = 6 mL/kg (
= 1880 mg/kg ( Rabbit ) > 7950
mg/kg ( Rat )
> 5240 mg/m3 ( Rat ) 4 h
Rat ) = 9143 mg/kg ( Rabbit )
-
Information on toxicological effects
Symptoms
Deliberate inhalation of concentrated vapor or mist may cause headache, dizziness and
nausea.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation
Serious eye damage/eye irritation
corrosivity
sensitization
Germ cell mutagenicity
Carcinogenicity
Prolonged and repeated contact with skin may cause allergic reactions in some individuals.
Can cause irritation after contact with the eyes.
Not applicable.
No a skin sensitizer.
No information available.
This product does not contain any carcinogens or potential carcinogens as listed by OSHA,
IARC or NTP.
Chemical name ACGIH IARC NTP OSHA
Piperonyl Butoxide
51-03-6
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration Hazard
No information available.
No information available.
No information available.
Not applicable.
Group 3
Numerical measures of toxicity - Product Information
Unknown acute toxicity
41% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-gas)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
7986 mg/kg
2846 mg/kg
1588 mg/l
9.8 mg/l
11.4 mg/l
12. Ecological Information
ecotoxicity
6.1 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical name Algae/aquatic plants Fish Toxicity to
Microorganisms
Petroleum distillates, 2.2: 96 h Lepomis 4720: 96 h Den-dronereides
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Crustacea
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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hydrotreated light
64742-47-8
Heptane
142-82-5
Diethylene Glycol Monoethyl
Ether
111-90-0
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Chemical name Partition coefficient
Heptane
142-82-5
Diethylene Glycol Monoethyl Ether
111-90-0
macrochirus mg/L LC50
static 45: 96 h Pimephales
promelas mg/L LC50
flow-through 2.4: 96 h
Oncorhynchus mykiss mg/L
LC50 static
375.0: 96 h Cichlid fish mg/L
LC50
19100 - 23900: 96 h
Lepomis macrochirus mg/L
LC50 flow-through 13400:
96 h Salmo gairdneri mg/L
LC50 flow-through 10000:
96 h Lepomis macrochirus
mg/L LC50 static 11400 -
15700: 96 h Oncorhynchus
mykiss mg/L LC50
flow-through 11600 - 16700:
96 h Pimephales promelas
mg/L LC50 flow-through
heteropoda mg/L LC50
10: 24 h Daphnia magna
mg/L EC50
3940 - 4670: 48 h Daphnia
magna mg/L EC50
4.66
-0.8
Other adverse effects
Waste treatment methods
Disposal of wastes
Contaminated packaging
Chemical name California Hazardous Waste Status
Piperonyl Butoxide
DOT
UN/ID no
Proper Shipping Name
Hazard Class
Heptane
142-82-5
51-03-6
No information available
13. Disposal Considerations
Dispose of in accordance with federal, state and local regulations.
Pressurized container: Do not pierce or burn, even after use. Do not puncture or incinerate
container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your
local solid waste agency for disposal instructions.
Toxic
Ignitable
Toxic
14. Transport Information
Limited Quantity
Consumer Commodity
ORM-D
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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IATA
UN/ID no
Proper Shipping Name
Hazard Class
IMDG
UN/ID no
Proper Shipping Name
Hazard Class
Marine pollutant
UN1950
Aerosols, flammable
2.1
UN1950
Aerosols, flammable
2.1
This product contains heptane which is toxic to aquatic life.
15. Regulatory information
International Inventories
TSCA
DSL
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic
Subtances Control Act (TSCA) Chemical Substance Inventory.
All ingredients are listed or are excluded from listing on the DSL.
SARA 313
This product contains the following toxic chemicals (above the de minimis level) subject to the reporting requirements of Section
313 of the Emergency Planning and Community Right-to-Know Act of 1986 and 40 CFR 372. This information must be included in
all SDSs that are copied and distributed for this material.
Chemical name CAS No weight-% SARA 313 - Threshold
Piperonyl Butoxide - 51-03-6 51-03-6 9.0 1.0
Diethylene Glycol Monoethyl Ether - 111-90-0 111-90-0 1-5 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
yes
yes
yes
No
No
Values %
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
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FG 438-5111-4GHS CHAMPION SPRAYON METERED INSECTICIDE SPRAY
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Chemical name New Jersey Massachusetts Pennsylvania
1,1-Difluoroethane
75-37-6
Heptane
142-82-5
Piperonyl Butoxide
51-03-6
Diethylene Glycol Monoethyl Ether
111-90-0
X X
X X X
X
X X
U.S. EPA Label information
EPA Pesticide registration number
498-196
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the
pesticide label: CAUTION: Harmful if inhaled. Avoid breathing spray mist. Avoid contact with skin, eyes and clothing. Prolonged or
frequently repeated skin contact may cause allergic reactions in some individuals.
16. Other information
NFPA Health Hazards 2 Flammability 4 Instability 1 Physical and chemical
properties Not
applicable
HMIS Health Hazards 2 Flammability 4 Physical hazards 1 Personal Protection B -
Eyes and hands
protection
Prepared by
Issue date
Regulatory Department
02-May-2019
Revision note
This SDS supersedes a previous SDS dated February 16, 2017.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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