Safety Data Sheet
Issue date 05-Sep-2018 Version 2
1. Identification of the Substance/Preparation and of the Company/Undertaking
Product Identifier
Product name
Chemical name
Other means of identification
Product code
Synonyms
Registration number(s)
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Address
Chase Products Co.
2727 Gardner Road
Broadview, IL 60155
708-273-1121
CHAMPION SPRAYON WASP, BEE & HORNET KILLER
7-7736-4
FG 438-5108-9GHS
Wasp, bee and hornet killer
498-156
Insecticide for wasps, hornets and yellow jackets.
DO NOT USE THIS PRODUCT ON LIVING DECORATIVE TREES, SHRUBS OR
ORNAMENTAL PLANTS.
Follow the "Use Restrictions" listed on the label.
Manufacturer Address
Chase Products Co.
2727 Gardner Road
Broadview, IL 60155
708-273-1121
Emergency Telephone Number
Company Phone Number
24 Hour Emergency Phone Number
Emergency telephone
708-865-1000
1-800-255-3924
ChemTel 1-800-255-3924
2. Hazards Identification
Classification
This chemical is regulated by FIFRA.
Acute toxicity - Inhalation (Gases) Category 3
Acute toxicity - Inhalation (Vapors) Category 3
Germ cell mutagenicity Category 1B
Carcinogenicity Category 1B
Aspiration toxicity Category 1
FLAMMABLE AEROSOLS
Gases Under Pressure
Label Elements
EMERGENCY OVERVIEW
DANGER
hazard statements
Toxic if inhaled
May cause genetic defects
May cause cancer
May be fatal if swallowed and enters airways
EXTREMELY FLAMMABLE AEROSOL
Contains gas under pressure; may explode if heated
Category 1
liquefied gas
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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Appearance clear liquid Physical State Aerosol Odor Characteristic odor of insecticide and
petroleum distillate.
Precautionary Statements - Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Avoid breathing fumes, mist, vapors or spray.
Use only outdoors or in a well-ventilated area
Keep away from heat, sparks, open flames and hot surfaces. — No smoking
Pressurized container: Do not pierce or burn, even after use
Do not spray on an open flame or other ignition source
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Specific treatment: See additional cautionary statements on this label.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician
IF SWALLOWED: Immediately call a POISON CENTER or doctor
Do NOT induce vomiting
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Other Information
• Toxic to aquatic life with long lasting effects
3% of the mixture consists of ingredient(s) of unknown toxicity
3. Composition/information on Ingredients
Common Name
Synonyms
Chemical Family
Formula
Chemical nature
Chemical name CAS No weight-% Trade secret
Petroleum distillates, hydrotreated light 64742-47-8 55-60 *
Low Odor Mineral Spirits 64742-47-8 35-40 *
Carbon Dioxide 124-38-9 1-5 *
Petroleum naphtha, light aromatic 64742-95-6 <2 *
Tetramethrin 7696-12-0 0.2 *
d-Phenothrin 26002-80-2 0.125 *
Insecticide spray.
Wasp, bee and hornet killer.
Pesticide.
7-7736-4
Solvent based insecticide.
* The exact percentage (concentration) of composition has been withheld as a trade secret.
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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4. First aid measures
FIRST AID MEASURES
Eye Contact
Skin contact
Inhalation
Ingestion
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control
center or doctor for treatment advice.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for treatment advise.
If overcome by vapor, move person to fresh air. If person is not breathing, call 911 or an
ambulance, then provide artifical respiration, preferably mouth-to-mouth, if possible. Call a
poison control center or doctor for further treatment advise.
Immediately call a poison control center or doctor. Do not induce vomiting unless told to do
so by the poison control center or doctor. Do not give any liquid to the person. Do not give
anything by mouth to an unconscious person.
Prolonged contact with skin may cause allergic reactions on some individuals. Harmful if
inhaled.
Contains petroleum distillates, do not induce vomiting because of aspiration neumonia
hazard.
5. Fire-fighting measures
Suitable extinguishing media
CO2 (Carbon Dioxide), dry chemical, or water fog.
Unsuitable extinguishing media
Specific hazards arising from the chemical
Vapors are heavier than air and may travel along the ground and be ignited by pilot lights, other flames, sparks, heaters, smoking
or other ignition sources.
Hazardous combustion products
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Caution: Use of water spray when fighting fire may be inefficient.
Thermal decomposition may yield gases like carbon monoxide, carbon dioxide and
hydrogen cyanide gas (from active ingredient). Hydrogen cyanide may be formed at 160 F
(71.1 C) or higher, or by contact with alkaline substances such as soda ash and lye.
Contents under pressure, keep away from heat and open flame.
Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static electricity).
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions
For emergency responders
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Shut off ignition sources. Provide adequate ventilation to area being treated. Soak up spills
with chemically inert, absorbent material.
Remove all sources of ignition. Wear respiratory protection.
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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Environmental precautions
Environmental precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for Containment
Methods for cleaning up
Soak up spills with chemically inert, absorbent material.
Clean contaminated surface thoroughly.
7. Handling and Storage
Precautions for safe handling
Advice on safe handling
Avoid contact with skin. Avoid getting spray into eyes. Do not deliberately inhale vapor or
mist. Do not contaminate food or food handling surfaces. Keep out of reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Store in a cool, dry place away from heat and open flame. Keep out of reach of children.
AEROSOL STORAGE LEVEL III (NFPA-30B).
Incompatible Materials
Avoid heat, open flame and contact with strong alkali and strong oxidizing agents.
8. Exposure Controls/Personal Protection
Control parameters
Exposure guidelines
See occupational exposure limits listed below.
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
Carbon Dioxide
124-38-9
STEL: 30000 ppm
TWA: 5000 ppm
TWA: 5000 ppm
TWA: 9000 mg/m
(vacated) TWA: 10000 ppm
(vacated) TWA: 18000 mg/m
(vacated) STEL: 30000 ppm
(vacated) STEL: 54000 mg/m
3
IDLH: 40000 ppm
TWA: 5000 ppm
3
3
TWA: 9000 mg/m
STEL: 30000 ppm
STEL: 54000 mg/m
3
3
Appropriate engineering controls
Engineering controls
Use with adequate general or local exhaust ventilation.
Individual protection measures, such as personal protective equipment
Eye/face Protection
Skin and Body Protection
Respiratory protection
Conventional eyeglasses to guard against splashing.
Rubber, vinyl or household type gloves required.
None required if used in a well-ventilated area . Follow label directions and precautions for
the correct use of the product.
General hygiene considerations
Wash hands thoroughly after handling.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical State
Appearance
Color
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Aerosol
clear liquid
Clear to yellowish
Odor
Odor threshold
Characteristic odor of
insecticide and petroleum
distillate.
No information available
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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Property Values Remarks • Method
pH
Melting point/freezing point
Boiling point/boiling range
Not applicable Solvent-based product.
Not applicable No information available
Hydrotreated Petroleum Dist. 468-529°FNo information available
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limits
Lower Flammability Limit
Vapor pressure
Vapor Density
Relative Density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition Temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
Softening point
Molecular weight
VOC content (%)
Density
Bulk Density
Not Available. This is an aerosol
product for which Flame Projection is
over 18 inches with 1 inches flashback.
Temperatures above 120 F may cause
cans to burst.
Faster than butyl acetate. No information available
No information available
No information available
0.804 +/- 0.005 concentrate No information available
No information available
No information available
No information available
No information available
39.72%
6.70 lb/gal
No information available
No information available
No information available
No information available
insoluble
No information available
No information available
No information available
No information available
No information available
No information available
10. Stability and Reactivity
Reactivity
Not applicable Not applicable
Chemical stability
Stable.
Possibility of hazardous reactions
Temperatures above 130 °F may cause cans to burst with force.
hazardous polymerization
Conditions to Avoid
Temperatures above 122 °F (50 °C).
Incompatible Materials
Avoid heat, open flame and contact with strong alkali and strong oxidizing agents.
Hazardous decomposition products
Thermal decomposition may yield gases like carbon monoxide, carbon dioxide and hydrogen cyanide (from active ingredient).
Hazardous polymerization does not occur.
11. Toxicological Information
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin contact
Ingestion
Chemical name Oral LD50 dermal LD50 Inhalation LC50
Petroleum distillates, hydrotreated
light
64742-47-8
Low Odor Mineral Spirits
64742-47-8
Petroleum naphtha, light aromatic
64742-95-6
Tetramethrin
7696-12-0
d-Phenothrin
26002-80-2
This product has not been tested as whole. See below for information on ingredients.
No data available.
No data available.
No data available.
No data available.
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h
> 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h
= 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h
= 4640 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) > 2500 mg/kg
( Rat )
> 10 g/kg ( Rat ) > 2000 mg/kg ( Rat ) > 5 g/kg ( Rat
)
> 1.18 mg/L ( Rat ) 3 h
> 3760 mg/m3 ( Rat ) 4 h
Information on toxicological effects
Symptoms
Deliberate inhalation of concentrated vapor or mist may cause headache, dizziness and
nausea.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation
Serious eye damage/eye irritation
corrosivity
sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical name ACGIH IARC NTP OSHA
Tetramethrin
7696-12-0
d-Phenothrin
26002-80-2
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration Hazard
Prolonged and repeated contact with skin may cause allergic reactions in some individuals.
Can cause irritation after contact with the eyes.
Not applicable.
No a skin sensitizer.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Group 2A X
Group 2A X
No information available.
No information available.
No information available.
Not applicable.
Numerical measures of toxicity - Product Information
Unknown acute toxicity
3% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-gas)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
7986 mg/kg
2846 mg/kg
1588 mg/l
9.8 mg/l
11.4 mg/l
12. Ecological Information
ecotoxicity
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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6.1 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical name Algae/aquatic plants Fish Toxicity to
Petroleum distillates,
hydrotreated light
64742-47-8
Low Odor Mineral Spirits
64742-47-8
Petroleum naphtha, light
aromatic
64742-95-6
2.2: 96 h Lepomis
macrochirus mg/L LC50
static 45: 96 h Pimephales
promelas mg/L LC50
flow-through 2.4: 96 h
Oncorhynchus mykiss mg/L
LC50 static
2.2: 96 h Lepomis
macrochirus mg/L LC50
static 45: 96 h Pimephales
promelas mg/L LC50
flow-through 2.4: 96 h
Oncorhynchus mykiss mg/L
LC50 static
9.22: 96 h Oncorhynchus
mykiss mg/L LC50
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Other adverse effects
No information available
13. Disposal Considerations
Microorganisms
Crustacea
4720: 96 h Den-dronereides
heteropoda mg/L LC50
4720: 96 h Den-dronereides
heteropoda mg/L LC50
6.14: 48 h Daphnia magna
mg/L EC50
Waste treatment methods
Disposal of wastes
Contaminated packaging
Dispose of in accordance with federal, state and local regulations.
Pressurized container: Do not pierce or burn, even after use. Do not puncture or incinerate
container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your
local solid waste agency for disposal instructions.
Chemical name California Hazardous Waste Status
Tetramethrin
7696-12-0
d-Phenothrin
26002-80-2
Toxic
Toxic
14. Transport Information
DOT
UN/ID no
Proper Shipping Name
Hazard Class
IATA
UN/ID no
Proper Shipping Name
Hazard Class
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Limited Quantity
Consumer Commodity
ORM-D
UN1950
Aerosols, flammable
2.1
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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IMDG
UN/ID no
Proper Shipping Name
Hazard Class
Marine pollutant
UN1950
Aerosols, flammable
2.1
This product does not contain marine pollutants.
15. Regulatory information
International Inventories
TSCA
DSL
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
This product contains the following toxic chemicals (above the de minimis level) subject to the reporting requirements of Section
313 of the Emergency Planning and Community Right-to-Know Act of 1986 and 40 CFR 372. This information must be included in
all SDSs that are copied and distributed for this material.
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic
Subtances Control Act (TSCA) Chemical Substance Inventory.
All ingredients are listed or are excluded from listing on the DSL.
Chemical name CAS No weight-% SARA 313 - Threshold
Tetramethrin - 7696-12-0 7696-12-0 0.2 1.0
d-Phenothrin - 26002-80-2 26002-80-2 0.125 1.0
Values %
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
yes
yes
yes
No
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains <0.1% cumene, a chemical known to State of California to cause cancer.
U.S. State Right-to-Know Regulations
Chemical name New Jersey Massachusetts Pennsylvania
Carbon Dioxide
124-38-9
Tetramethrin
7696-12-0
X X X
X
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FG 438-5108-9GHS CHAMPION SPRAYON WASP, BEE & HORNET KILLER
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d-Phenothrin
26002-80-2
U.S. EPA Label information
EPA Pesticide registration number
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the
pesticide label: CAUTION: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or
clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using
the toilet. Remove and wash contaminated clothing before reuse.
498-156
X
16. Other information
NFPA Health Hazards 2 Flammability 4 Instability 1 Physical and chemical
properties Not
applicable
HMIS Health Hazards 2 Flammability 4 Physical hazards 1 Personal Protection B -
Eyes and hands
protection
Prepared by
Issue date
Revision note
This SDS supersedes a previous SDS dated June 25, 2015.
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
Regulatory Department
05-Sep-2018
End of Safety Data Sheet
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