CGW Abrasives 36266 User Manual

SAFETY DATA SHEET

1. Identification

Resin Bonded AbrasivesProduct identifier
Other means of identification
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information

None.

Industrial use.

None known.

Manufacturer
Address
Telephone number
e-mail
Contact person

Supplier
Address
Telephone number
e-mail
Emergency telephone

number

2. Hazard(s) identification

Physical hazards
Health hazards

CGW Camel Grinding Wheel Works Ltd.

Kibbutz Sarid 3658900 Israel

[phone]

[e-mail]

Joseph O'Mera

CGW Camel Grinding Wheels, Inc.

7525 N Oak Park Ave. Niles, IL 60714 United States

800-447-3731

[e-mail]

800-447-3731

Not classified.

Category 4Acute toxicity, inhalation
Category 2Skin corrosion/irritation
Category 2Serious eye damage/eye irritation
Category 1BCarcinogenicity
Effects on or via lactationReproductive toxicity
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 1 (lungs, skeletal)Specific target organ toxicity, repeated

exposure

Environmental hazards

OSHA defined hazards
Label elements

Signal word
Hazard statement

Resin Bonded Abrasives SDS US
929894 Version #: 01 Revision date: - Issue date: 21-August-2015

hazard

long-term hazard

Not classified.

Danger

Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory

irritation. May cause cancer. May cause harm to breast-fed children. Causes damage to organs

(lungs, skeletal) through prolonged or repeated exposure. Toxic to aquatic life with long lasting

effects.

Category 2Hazardous to the aquatic environment, acute

Category 2Hazardous to the aquatic environment,

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Precautionary statement

Prevention

Response

Storage
Disposal

Hazard(s) not otherwise
classified (HNOC)

Supplemental information

Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Do not breathe dust. Avoid contact during pregnancy/while nursing. Wash

thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors

or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective

clothing/eye protection/face protection.

If exposed or concerned: Get medical advice/attention. If inhaled: Remove person to fresh air and

keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If on skin: Wash

with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated

clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get

medical advice/attention. Collect spillage.

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.

None known.

None.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name

1344-28-1 40 - 95Aluminum oxide
1314-23-4 40 - 95Zirconium dioxide

hexafluoroaluminate

Composition comments

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important
symptoms/effects, acute and
delayed

Indication of immediate
medical attention and special
treatment needed

General information

409-21-2 40 - 95Silicon carbide whiskers

60304-36-1 5 - 40Aluminum potassium fluoride

471-34-1 2 - 30Calcium carbonate
15096-52-3 2 - 30Trisodium hexafluoroaluminate
13775-52-5 0 - 25Tripotassium

65997-17-3 13Fiberglass

All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.

Immediately remove from further exposure. Get immediate medical assistance. For those
providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection.
Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a
mechanical device.

Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get
medical advice/attention. Wash contaminated clothing before reuse.

Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops and persists.

Rinse mouth thoroughly with water and give large amounts of milk or water to people not
unconscious. Get medical attention immediately.

Moderate eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. May cause respiratory irritation. Coughing. Skin irritation. May cause redness and pain.
Prolonged exposure may cause chronic effects. Absorbed fluoride can cause metabolic
imbalances with irregular heartbeat, nausea, dizziness, vomiting and seizures.

Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.

IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.

Resin Bonded Abrasives SDS US
929894 Version #: 01 Revision date: - Issue date: 21-August-2015

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5. Fire-fighting measures

Suitable extinguishing media
Unsuitable extinguishing

media
Specific hazards arising from

the chemical
Special protective equipment

and precautions for firefighters
Fire fighting

equipment/instructions
Specific methods
General fire hazards

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.

During fire, gases hazardous to health may be formed.

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Use water spray to cool unopened containers.

Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.

6. Accidental release measures

Personal precautions,
protective equipment and
emergency procedures

Methods and materials for
containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Avoid inhalation of dust. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.

Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Prevent product
from entering drains. Stop the flow of material, if this is without risk. Collect in approved containers
and seal securely. Containers must be labeled.

Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste
container. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe
up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual
contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmental precautions

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling

Conditions for safe storage,
including any incompatibilities

Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Minimize dust generation and accumulation. Avoid breathing dust. Avoid contact
with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke.
Pregnant or breastfeeding women must not handle this product. Should be handled in closed
systems, if possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal
protective equipment. Wash hands thoroughly after handling. Avoid release to the environment.
Observe good industrial hygiene practices.

Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components

1344-28-1)

fluoride (CAS 60304-36-1)
471-34-1)

(CAS 409-21-2)

Type

PEL 5 mg/m3 Respirable fraction.Aluminum oxide (CAS

PEL 2.5 mg/m3Aluminum potassium
PEL 5 mg/m3 Respirable fraction.Calcium carbonate (CAS

PEL 5 mg/m3 Respirable fraction.Silicon carbide whiskers

Value

15 mg/m3 Total dust.

15 mg/m3 Total dust.

Form

Resin Bonded Abrasives SDS US
929894 Version #: 01 Revision date: - Issue date: 21-August-2015

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