The247-L CONDUCTIVITY & TEMPERATURE PROBE is warranted by
CAMPBELL SCIENTIFIC, INC. to be free from defects in materials and
workmanship under nor mal use and service for twelve (12) months from date of
shipment unless specifi ed otherwise. Batteries have no warranty. CAMPBELL
SCIENTIFIC, INC.'s obligation under this warranty is limited to repairing or
replacing (at CAMPBELL SCIENTIFIC, INC.'s option) defective products.
The customer shall assume all costs of removing, reinstalling, and shipping
defective products to CAMPBELL SCIENTIFIC, INC. CAMPBELL
SCIENTIFIC, INC. will return such products by surface carrier prepaid. This
warranty shall not apply to any CAMPBELL SCIENTIFIC, INC. products
which have been subjected to modification, misuse, neglect, accidents of
nature, or shipping damage. This warranty is in lieu of all other warranties,
expressed or implied, including warranties of merchantability or fitness for a
particular purpose. CAMPBELL SCIENTIFIC, INC. is not liable for special,
indirect, incidental, or consequential damages.
Products may not be returned without prior authorization. The following
contact information is for US and International customers residing in countries
served by Campbell Scientific, Inc. directly. Affiliate companies handle repairs
for customers wi thin their territories. Please visi t www.campbellsci.com to
determine which Campbell Scientific company serves your country. To obtain
a Returned Materials Authorization (RMA), contact CAMPBELL
SCIENTIFIC, INC., phone (435) 753-2342. After an applications engineer
determines the nature of the problem, an RMA number will be issued. Please
write this number clearly on the outside of the shipping container.
CAMPBELL SCIENTIFIC's shipping address is:
CAMPBELL SCIENTIFIC, INC.
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CAMPBELL SCIENTIFIC, INC. does not accept collect calls.
Page 3
247 Table of Contents
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12. Long Lead Lengths Temperature...........................10
Page 5
247 CONDUCTIVITY AND TEMPERATURE PROBES
1. OVERVIEW
247 Probes (247-L and 247W-L) are designed for
measuring the electrical conductivity, dissolved
solids, and temperature of fresh water with
Campbell Scientific dataloggers. They require the
use of negative excitation, so they can be used
with the CR10(X), 21X, and CR7 dataloggers but
not with the BDR301 or BDR320.
Electrical conductivity (EC) of a solution is a
simple physical property, but measurements can
be difficult to interpret. This manual instructs the
user how to make EC measurements with the
247. Accuracy specifications apply to
measurements of EC in water containing KCl,
Na
calibration compounds, and to EC not yet
compensated for temperature effects.
Statements made on methods of temperature
compensation or estimating dissolved solids are
included to introduce common ways of refining and
interpreting data, but are not definitive.
Authoritative sources to consult include the USGS
Water-Supply Paper 1473, The pH and Conductivity
Handbook published by OMEGA Engineering,
physical chemistry texts, and other sources.
1.1 EC SENSOR
The EC sensor consists of three stainless steel
rings mounted in an epoxy tube as shown in
Figure 4-1. Resistance of water passing
, NaHCO3, and/or NaCl, which are typical
2SO4
through the tube is measured by excitation of
the center electrode with positive and negative
voltage. The two outer electrodes return the
signal to the datalogger.
This electrode configuration eliminates the
ground looping problems associated with
sensors in electrical contact with earth ground.
1.2 TEMPERATURE SENSOR
Temperature is measured with a thermistor in a
three wire half bridge configuration.
2. SPECIFICATIONS
2.1 PROBE
Construction: The probe housing is epoxy with
rounded ends to facilitate installation and removal.
Size: Length 3.125". Diameter 0.75". The
diameter of the weighted 247W-L version with
the stainless steel sleeve is 1.05".
Maximum Cable Length: 1000 ft. The sensor
must be ordered with desired length as cable
cannot be added to existing probes.
Depth Rating: Maximum 1000 ft. In
applications that require probe placement in
well casings, the weighted 247W-L is strongly
recommended.
pH Range: Solution pH of less than 3.0 or greater
than 9.0 may damage the epoxy housing.
SOLDER
SIDE
LAC-2
2292
FIGURE 1-1. 247 Conductivity and Temperature Probe
1
Page 6
247 CONDUCTIVITY AND TEMPERATURE PROBES
2.2 EC SENSOR
Electrodes: Passivated 316 SS with DC
isolation capacitors.
Cell constant: Individually calibrated. The cell
constant (Kc) is found on a label near the
termination of the cable.
Temp. Range of Use: Above freezing to 50°C.
EC Range: Approx. 0.005 to 7.5 mS cm-1.
Accuracy: in KCl and Na2SO4, NaHCO3, and
NaCl standards at 25°C:
±5% of reading 0.44 to 7.0 mS cm
±10% of reading 0.005 to 0.44 mS cm
2.3 TEMPERATURE SENSOR
Thermistor: Betatherm 100K6A1.
Range: 0°C to 50°C.
Accuracy: Error ±0.4°C (See Section 8.2).
3. INSTALLATION
CAUTION: Rapid heating and cooling of the
probe, such as leaving it in the sun and then
submersing it in a cold stream, may cause
irreparable damage.
4. WIRING
The 247s manufactured after January 1, 1994
are connected to a Campbell Scientific
datalogger as illustrated in Figure 4-1.
NOTE: The excitation channel used for EC
must be separate from the one used for
temperature or measurement errors will result.
To make previous versions of the 247 (those
without an orange lead) compatible with the
information in this manual, connect existing
-1
.
-1
.
wires as shown in Figure 4-1. Attach one end
of a short piece of insulated wire to the
excitation channel servicing the black lead and
the other end to the H side of the selected
differential channel (this wire acts as the absent
orange lead). If your probe has a blue lead, it is
no longer needed. Tape the exposed portion to
avoid shorting the sensor.
5. PROGRAMMING
5.1 PROGRAMMING OVERVIEW
Typical datalogger programs to measure the
247 consist of four parts:
1. Measurement of EC and temperature
3.1 SITE SELECTION
The EC sensor measures the EC of water
inside the epoxy tube, so detection of rapid
changes in EC requires that the probe be
flushed continuously. This is easy to
accommodate in a flowing stream by simply
orienting the sensor parallel to the direction of
flow. In stilling wells and ground wells,
however, diffusion rate of ions limits the
response time.
3.2 MOUNTING
The epoxy housing and sensor cable are made
of water impervious, durable materials. Care
should be taken, however, to mount the probe
where contact with abrasives and moving
objects will be avoided. Weighting to facilitate
installation in wells is provided by the stainless
steel sleeve on the 247W-L. Strain on cables
can be minimized by using a split mesh strain
relief sleeve on the cable, which is
recommended for cables over 100 ft. The
strain relief sleeve is available from Campbell
Scientific as part number 7421.
2. Correction of ionization errors in EC
measurements
3. Correction of temperature errors in EC
measurements
4. Output processing
All example programs may require modification
by the user to fit the specific application's wiring
and programming needs. Example programs in
this manual assume that the orange lead is
connected to 1H, the white to 1L, the red to 2H,
the green to E2, and the black to E1.
2
Page 7
247 CONDUCTIVITY AND TEMPERATURE PROBES
FIGURE 4-1. 247 Wiring Diagram
5.2 MEASUREMENT PROGRAMMING.
EC Results from Instructions 5 or 6 (chosen
automatically as part of the autoranging feature
of the following program segment) are
processed with Instruction 59 to produce the
resistance across the electrodes:
Make a preliminary measurement of resistance
for autoranging.
01:P6Full Bridge
01:1Rep
02:152500 mV fast Range
(Use 5000 mV fast for 21X)
03:1IN Chan
04:1Excite all reps w/EXchan 1
05: 2500mV Excitation
(5000 mV for 21X)
06:1Loc [:Rs ]
07:-.001Mult
08:1Offset
02:P59BR Transform Rf[X/(1-X)]
01:1Rep
02:1Loc [:Rs ]
03:1Multiplier (Rf)
Test the preliminary measurement against each
case and make a refined measurement.
03:P93Case
01:1Case Loc Rs
04:P83 If Case Location < F
01:1.8F
02:30Then Do
05:P5AC Half Bridge
01:1Rep
02:152500 mV fast Range
(Use 5000 mV fast for 21X)
03:2IN Chan
04:1Excite all reps w/EXchan 1
05: 2500mV Excitation
(Use 5000 mV for 21X)
06:1Loc [:Rs ]
07:1Mult
08:0Offset
06:P95End
07:P83If Case Location < F
01:9.25F
02:30Then Do
08:P6Full Bridge
01:1Rep
02:152500 mV fast Range
(Use 5000 mV fast for 21X)
03:1IN Chan
04:1Excite all reps w/EXchan 1
05: 2500mV Excitation
(5000 mV for 21X)
06:1Loc [:Rs ]
07:-.001Mult
08:1Offset
09:P95End
10:P83If Case Location < F
01:280F
02:30Then Do
3
Page 8
247 CONDUCTIVITY AND TEMPERATURE PROBES
11:P6Full Bridge
01:1Rep
02:14250 mV fast Range
(Use 500 mV fast for 21X)
03:1IN Chan
04:1Excite all reps w/EXchan 1
05: 2500mV Excitation
(Use 5000 mV for 21X)
06:1Loc [:Rs ]
07:-.001Mult
08:1Offset
Subtract resistance errors (Rp) caused by the
blocking capacitors (0.005 kΩ) and the cable
-1
length (0.000032 kΩ ft
). Enter cable lead
length in nnn below.
15:P30Z=F
01:nnnF Enter Lead Length
in Feet
02:00Exponent of 10
03:5Loc [:Rp ]
16:P37Z=X*F
01:5Loc Rp
02:.00032 F
03:5Loc [:Rp ]
17:P37Z=X*F
01:5Loc Rp
02:-.1F
03:5Loc [:Rp ]
18:P34Z=X+F
01:5Loc [Rp ]
02:-.005
03:5Loc [:Rp ]
NOTE: The cell constant (K
) is printed on the
c
label of each sensor. It is entered in place of
nnn in this segment.
20:P42Z=1/X
01:1X Loc Rs
02:2Z Loc [:1/Rs ]
21:P37Z=X*F
01:2X Loc 1/Rs
02:nnnF ENTER CELL
CONSTANT
03:3Z Loc [:Ct ]
Temperature Temperature is measured with a
single instruction, P11, that measures the
thermistor resistance and calculates
temperature. Output is °C when a multiplier of
1 and an offset of 0 is used. See Section 10 for
detailed information on the function of
Instruction P11.
22:P11Temp 107 Probe
01:1Rep
02:3IN Chan
03:2Excite all reps w/EXchan 2
04:4Loc [:Temp °C ]
05:1Mult
06:0Offset
5.3 CORRECTION OF IONIZATION ERRORS IN
EC MEASUREMENT
Ionization caused by the excitation of the EC
sensor can cause large errors. Campbell
Scientific has developed a linear correction for
measurements between 0.005 and 0.44 mS cm
and a quadratic correction for measurements
-1
between 0.44 and 7.0 mS cm
. Corrections were
determined in standard salt solutions containing
KCl, Na
, NaHCO3, and NaCl.
2SO4
The following program segment automatically
chooses which correction to apply to the
measurement.
23:P89If X<=>F
-1
,
19:P33Z=X+Y
01:1X Loc Rs
02:5Y Loc Rp
03:1Z Loc [:Rs ]
EC is then calculated by multiplying the
reciprocal of resistance, which is conductance,
by the cell constant to arrive at EC.
4
01:3X Loc Ct
02:4<
03:.474F
04:30Then Do
24:P37Z=X*F
01:3X Loc Ct
02:.95031 F
03:3Z Loc [:Ct ]
Page 9
247 CONDUCTIVITY AND TEMPERATURE PROBES
25:P34Z=X+F
01:3X Loc Ct
02:-.00378 F
03:3Z Loc [:Ct ]
26:P94Else
27:P55Polynomial
01:1Rep
02:3X Loc Ct
03:3F(X) Loc [:Ct ]
04:-.02889 C0
05:.98614 C1
06:.02846 C2
07:0.0000C3
08:0.0000C4
09:0.0000C5
28:P95End
5.4 CORRECTION OF TEMPERATURE ERRORS
The effect of temperature on the sample
solution can cause large errors in the EC
measurement. A simple method of correcting
for this effect is to assume a linear relationship
between temperature and EC. This method
generally produces values to within 2% to 3% of
a measurement made at 25°C.
The best corrections are made when the
temperature coefficient is determined at a
temperature near field conditions. See Section
9 for details on how to determine the
temperature coefficient. If determining the
temperature coefficient is not possible, use a
-1
value of 2% °C
as a rough estimate.
The following program segment implements a
previously determined temperature coefficient
(TC) and calculates the corrected conductivity.
32:P34Z=X+F
01:9X Loc TC PROCES
02:100F
03:9Z Loc [:TC PROCES]
33:P38Z=X/F
01:8X Loc 100*Ct
02:9Y Loc TC PROCES
03:10Z Loc [:C25mScm-1]
5.5 OUTPUT PROCESSING
Over large ranges, EC is not linear and is best
reported as samples (70). In limited ranges,
averaging (71) measurements over time may be
acceptable. Convention requires that the
temperature at the time of the measurement be
reported.
6. CALIBRATION
6.1 CONVERSION FACTORS
1 S (Siemens) = 1 mho = 1/ohm
Although mS·cm
commonly used units of EC, the SI base unit is
-1
. The result of the example programs is
S·m
mS·cm
-1
EC measurements can be used to estimate
dissolved solids. For high accuracy, calibration
to the specific stream is required. However, for
rough estimates, values between 550 and 750
-1
/ mS·cm-1 are typical with the higher
mg·l
values generally being associated with waters
high in sulfate concentration (USGS WaterSupply Paper #1473, p. 99). A common
practice is to multiply the EC in mS·cm
to produce ppm or mg·l
6.2 TYPICAL RANGES
-1
and µS·cm-1 are the
-1
.
-1
by 500
29:P34Z=X+F
01:4X Loc Temp °C
02:-25F
03:6Z Loc [:A ]
30:P37Z=X*F
01:3X Loc Ct
02:100F
03:8Z Loc [:100*Ct ]
31:P37Z=X*F
01:6X Loc A
02:nnnF Enter TC (%°C
03:9Z Loc [:TC PROCES]
Single distilled water will have an EC of at least
-1
0.001 mS·cm
range from 0.002 to 0.042 mS·cm
. ECs of melted snow usually
-1
. ECs of
stream water usually range from 0.05 to 50.0
-1
mS·cm
, the higher value being close to the EC
of sea water (USGS Water-Supply Paper 1473,
p. 102).
6.3 FACTORY CALIBRATION
The 247 is shipped with a cell constant
calibrated in a 0.01 molal KCl solution at 25.0°C
-1
)
±0.05°C. The solution has a EC of 1.408 mS
-1
.
cm
5
Page 10
247 CONDUCTIVITY AND TEMPERATURE PROBES
6.4 FIELD CALIBRATION
The cell constant is a dimensional number
-1
expressed in units of cm
. The unit cm-1 is
slightly easier to understand when expressed as
-2
cm·cm
. Because it is dimensional, the cell
constant as determined at any one standard,
will change only if the physical dimensions
inside the 247 probe change. Error due to
thermal expansion and contraction is negligible.
Corrosion and abrasion, however, have the
potential of causing significant errors.
A field calibration of the 247 cell constant can
be accomplished as follows:
1. Make a 0.01 molal KCL solution by
dissolving 0.7456 g of reagent grade KCl in
1000 g of distilled water.
2. Clean the probe thoroughly with the black
nylon brush shipped with the 247 and a
small amount of soapy water. Rinse
thoroughly with distilled water, dry
thoroughly, and place in the KCl solution.
3. Connect the 247 to the datalogger using the
wiring described in Section 4. Enter the
following program into the datalogger.
The calibration solution temperature must be
between 1°C and 35°C; the polynomial in step 11
(58) corrects for temperature errors within this
range. The solution constant of 1.408 mS cm
entered in step 13 (37), is valid only for a 0.01
molal KCl solution. Location 8, generated by step
14, will contain the resultant cell constant.
01:P5AC Half Bridge
01:1Rep
02:152500 mV fast Range
(5000 mV fast for 21X)
03:2IN Chan
04:1Excite all reps w/EXchan 1
05: 2500mV Excitation
(5000 mV for 21X)
06:1Loc [:Rs ]
07:1Mult
08:0Offset
01:3X Loc (t-25).01
02:.01F
03:3Z Loc [:(t-25).01]
11:P55Polynomial
01:1Rep
02:3X Loc (t-25).01
03:4F(X) Loc [:f(t) ]
04:.99124 C0
05:-1.8817C1
06:3.4789C2
07:-3.51C3
08:-1.2C4
09:-43C5
12:P42Z=1/X
01:4X Loc f(t)
02:6Z Loc [:1/f(t) ]
13:P37Z=X*F
01:6X Loc 1/f(t)
02:1.408F
03:7Z Loc [:Act'l Con]
14:P36Z=X*Y
01:7X Loc Act'l Con
02:1Y Loc Rs
03:8Z Loc [:Kc (cm-1)]
6
Page 11
247 CONDUCTIVITY AND TEMPERATURE PROBES
7. MAINTENANCE
Routine maintenance includes thoroughly
cleaning the orifice of the 247 probe with the
black nylon brush provided and a little soapy
water. Rinse thoroughly.
3. Ionization Error of KCl and Na+ Solutions
After Correction:
< 2.0%, 0.45 to 7.0 mS cm
< 8.0%, 0.005 to 0.45 mS cm
-1
-1
Correction of Ionization Errors. Figures 8.1-1 and
8.1-2 show the amount of correction applied by the
example program to compensate for ionization
effects on the measurements. Also shown is an
ideal correction. Factors were derived by
measuring the standard solutions described in
Section 2.2 with values of 0.0234, 0.07, 0.4471,
-1
07, 1.413, 2.070, 3.920, and 7.0 mS cm
.
FIGURE 8.1-1. Plot of Ideal and Actual Correction between 0 and 0.44 mS cm
FIGURE 8.1-2. Plot of Ideal and Actual Correction between 0.44 and 7.0 mS cm
-1
-1
7
Page 12
247 CONDUCTIVITY AND TEMPERATURE PROBES
8.2 TEMPERATURE MEASUREMENT ERROR
The overall probe accuracy is a combination of the
thermistor's interchangeability specification, the
precision of the bridge resistors, and the polynomial
error. In a "worst case" all errors add to an
accuracy of ±0.4°C over the range of -24° to 48°C
and ±0.9°C over the range of -38°C to 53°C. The
major error component is the interchangeability
specification of the thermistor, tabulated in
Table 8.2-1. For the range of 0° to 50°C the
interchangeability error is predominantly offset and
can be determined with a single point calibration.
Compensation can then be done with an offset
entered in the measurement instruction. The bridge
resistors are 0.1% tolerance with a 10 ppm
temperature coefficient. Polynomial errors are
tabulated in Table 8.2-2 and plotted in Figure 8.2-1.
TABLE 8.2-1. Thermistor Interchangeability
Specification
Temperature
Temperature (°C)Tolerance (
−400.40
−300.40
−200.32
−100.25
0 to +500.20
TABLE 8.2-2. Polynomial Error
-40 to +56<±1.0°C
-38 to +53<±0.5°C
-24 to +48<±0.1°C
±°C)
FIGURE 8.2-1. Error Produced by Polynomial Fit to Published Values
8
Page 13
247 CONDUCTIVITY AND TEMPERATURE PROBES
9. DERIVING A TEMPERATURE
COMPENSATION COEFFICIENT
1. Place the 247 in a sample of the solution to
be measured. Bring the sample and the
probe to 25°C.
2. Enter the example program from Section
5.2 in the datalogger and record C
from Location 3. This number will be C
the formula in Step 4.
3. Bring the solution and the probe to a
temperature (t) near the temperature at
which field measurements will be made.
This temperature will be t (in °C) in the
formula. Record C
at the new temperature
t
from Location 3. This number will be C in
the formula in Step 4.
4. Calculate the temperature coefficient (TC)
using the following formula.
)
25
= % / °C
25
TC = 100 *
(C - C
_____________
(t - 25) * C
Enter TC in the appropriate location (nnn)
as shown in the program segment in
Section 5.4.
10. INSTRUCTION 11 DETAILS
Understanding the details in this section are not
necessary for general operation of the 247
probe with CSI's dataloggers.
Instruction 11 outputs a precise 2 VAC
excitation (4 V with the 21X) and measures the
voltage drop due to the sensor resistance. The
thermistor resistance changes with
temperature. Instruction 11 calculates the ratio
of voltage measured to excitation voltage
(Vs/Vx) which is related to resistance, as shown
below:
Vs/Vx = 1000/(Rs+249000+1000)
where Rs is the resistance of the thermistor.
See the measurement section of the datalogger
manual for more information on bridge
measurements.
at 25°C
t
25
in
(Vs/Vx)*800. Resistance and datalogger output
at several temperatures are shown in Table 10-1.
TABLE 10-1. Temperature , Resistance, and
Datalogger Output
0.00351017-0.06
2.003152881.96
4.002835583.99
6.002553376.02
8.002302108.04
10.0020780710.06
12.0018780312.07
14.0016992414.06
16.0015392316.05
18.0013958818.02
20.0012672919.99
22.0011517921.97
24.0010479623.95
26.009544925.94
28.008702627.93
30.007942829.95
32.007256731.97
34.006636533.99
36.006075236.02
38.005566838.05
40.005105840.07
42.004687342.07
44.004307144.05
46.003961346.00
48.003646547.91
50.003359849.77
52.003098351.59
54.002859553.35
56.002641355.05
58.002441956.70
60.002259358.28
TABLE 10-2. Polynomial Coefficients
COEFFICIENTVALUE
C0-53.4601
C19.08067
C2-8.32569 x 10
C35.22829 x 10
C4-1.67234 x 10
C52.21098 x 10
-01
-02
-03
-05
Instruction 11 then calculates temperature using a
fifth order polynomial equation correlating Vs/Vx
with temperature. The polynomial coefficients are
given in Table 10-2. The polynomial input is
9
Page 14
247 CONDUCTIVITY AND TEMPERATURE PROBES
11. ELECTRICALLY NOISY
ENVIRONMENTS
AC power lines can be the source of electrical
noise. If the datalogger is in an electronically
noisy environment, the 107/107B temperature
measurement should be measured with the AC
half bridge (Instruction 5) with the 60 Hz rejection
integration option on the CR10(X) and slow
integration on the 21X and CR7 (see Section 13
of the datalogger manual for more information
on noise). Instruction 11's fast integration will
not reject 60 Hz noise.
01:1Rep
02:11*X Loc Air_Temp
03:11*F(X) Loc [:Air_Temp ]
04:-53.46C0
05:90.807C1
06:-83.257C2
07:52.283C3
08:-16.723C4
09:2.211C5
*Proper entries will vary with program and
datalogger channel and input location
assignments.
** On the 21X and CR7 use the 15 mV input
range and 4000 mV excitation.
12. LONG LEAD LENGTHS
TEMPERATURE
If the 247-L/247W-L has lead lengths of more
than 300 feet, use the DC Half Bridge
instruction (Instruction 4) with a 2 millisecond
delay to measure temperature. The delay
provides a longer settling time before the
measurement is made. Do not use the
247-L/247W-L with long lead lengths in an
electrically noisy environment.