SAFETY DATA SHEET
Page 1 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
1. PRODUCT IDENTIFICATION
1.1
Product Name:
DeoxIT® D-Series, 100% Spray, (P/N D100S-2), 57 g
1.2
Chemical Name:
See ingredients listed in section 3
1.3
Synonyms:
DeoxIT®, D100S-2, 100% Spray
1.4
Trade Names:
DeoxIT®, D100S-2, 100% Spray
1.5
Product Use:
Clean, Deoxidize & Improve Electrical Contacts & Connectors
1.6
Manufacturer’s Name:
CAIG Laboratories, Inc.
1.7
Manufacturer’s Address:
12200 Thatcher Court, Poway, CA 92064-6876 USA
1.8
Emergency Phone:
CHEMTREC: +1 (703) 527-3887 / +1 (800) 424-3887
1.9
Business Phone:
+1 (800)-224-4123
2. HAZARD IDENTIFICATION
2.1
Hazard Identification:
This product is classified as a HAZARDOUS SUBSTANCE but not as DANGEROUS GOODS according to the
classification criteria of NOHSC: 1008(2004) and ADG Code (Australia).
WARNING! Flammable aerosol. Colorless, volatile liquid with ethereal and faint sweetish odor. Overexposure may
cause dizziness and loss of concentration. At higher levels, CNS depression and cardiac arrhythmia may result from
exposure. Vapors displace air and can cause asphyxiation in confined spaces.
Hazard Statements (H): H223 – Flammable aerosol.
Precautionary Statements (P): P210 – Keep away from heat/sparks/open flames/hot surfaces. P211 – Do not spray
on an open flame or other ignition source. P251 – Pressurized container. Do not pierce or burn, even after use.
P280 – Wear protective gloves and eyewear. P302 + P352 – IF ON SKIN – Wash with plenty of soap and water. P312 –
Call a Poison Control Center or doctor/physician if you feel unwell. P333 + P313 – If skin irritation or rash occurs, get
medical advice/attention. P321 – Refer to section 4 of this Safety Data Sheet (First Aid). P305+P351+P338 – IF IN EYES
- Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue
rinsing. P501 – Dispose of contents/container through licensed treatment, storage or disposal facility.
2.2
Routes of Entry:
Inhalation:
YES
Absorption:
YES
Ingestion:
YES
2.3
Effects of Exposure:
EYES: Mild to moderate irritation.
SKIN: Irritant and potential skin sensitizer. Prolonged or repeated contact may cause contact dermatitis (localized redness or
rash).
INGESTION: Gastrointestinal irritation and central nervous system depression.
INHALATION: Central nervous system depressant. Irritating to the upper respiratory tract.
2.4
Symptoms of Overexposure:
EYES: Mild irritation, redness, and watering.
SKIN: Contact dermatitis, characterized by localized red or puffy dry skin and itching.
INGESTION: Nausea, vomiting, and diarrhea.
INHALATION: Mouth, nose, and throat irritation, dizziness, nausea, light-headedness, drunkenness, and loss of coordination.
2.5
Acute Health Effects:
INGESTION: Gastrointestinal irritation and central nervous system depression.
EYES: Mild to moderate irritation.
SKIN: Irritant and potential skin sensitizer. Prolonged or repeated contact may cause contact dermatitis (localized redness or
rash).
INGESTION: Gastrointestinal irritation and central nervous system depression.
INHALATION: Central nervous system depressant. Irritating to the upper respiratory tract.
2.6
Chronic Health Effects:
EYES: Mild to moderate irritation.
SKIN: Irritant and potential skin sensitizer. Prolonged or repeated contact may cause contact dermatitis (localized redness or
rash).
INGESTION: Gastrointestinal irritation and central nervous system depression.
INHALATION: Central nervous system depressant. Irritating to the upper respiratory tract.
2.7
Target Organs:
Eyes, skin and respiratory system.
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2010 format.
SAFETY DATA SHEET
Page 2 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
3. COMPOSITION & INGREDIENT INFORMATION
CHEMICAL NAME(S)
CAS No.
RTECS No.
EINECS No.
%
EXPOSURE LIMITS IN AIR
ACGIH
NOHSC
OSHA
OTHER
ppm (mg/m3)
ppm (mg/m3)
ppm (mg/m3)
TLV
STEL
ES-
TWA
ES-
STEL
ES-
PEAK
PEL
STEL
IDLH
1,1-DIFLUOROETHANE (R-152a)
75-37-6
KI1410000
200-866-1
60-100
1000
NA
1000
NA
NA
NE
NA
NA
DeoxIT® D-Series, D100L
TRADE SECRET
7-13
NA
NA
NA
NA
NA
NA
NA
NA
4. FIRST AID MEASURES
4.1
First Aid:
EYES: Flush eyes thoroughly with copious amounts of water for at least 15 minutes, holding eyelid(s) open to ensure
complete flushing. If irritation persists, seek immediate medical attention.
SKIN: Remove contaminated clothing and wash affected areas with soap and water. If irritation persists, seek prompt
medical attention. Do not wear contaminated clothing until after it has been properly cleaned.
INGESTION: Drink plenty of water. If irritation persists, contact a physician.
INHALATION: Remove victim to fresh air at once. If breathing is difficult, administer supplemental oxygen and seek immediate
medical attention. If breathing stops, perform artificial respiration.
4.2
Medical Conditions Aggravated by Exposure:
None reported by the manufacturer.
HEALTH
1
FLAMMABILITY
2
PHYSICAL HAZARDS
0
PROTECTIVE EQUIPMENT
B
EYES
SKIN
5. FIREFIGHTING MEASURES
5.1
Flashpoint & Method:
240 °C (464 °F)
5.2
Autoignition Temperature:
NA
5.3
Flammability Limits:
Lower Explosive Limit (LEL):
3.9
Upper Explosive Limit (UEL):
16.9
5.4
Fire & Explosion Hazards:
Level 2 Aerosol. Carbon dioxide, carbon monoxide, hydrocarbons.
5.5
Extinguishing Methods:
CO2, Alcohol foam, Dry Chemical, Water Fog
5.6
Firefighting Procedures:
Wear NIOSH/MSHA approved self-contained breathing apparatus and protective clothing. Use a water spray to
cool containers involved in fire. Do not use direct water stream. Container storage areas exposed to direct flame
contact should be cooled with large quantities of water as needed to prevent weakening of container structure.
Keep containers cool until well after the fire is out to prevent rupture. Prevent runoff from fire control or dilution
from entering sewers, drains, drinking water supply, or any natural waterway.
6. ACCIDENTAL RELEASE MEASURES
6.1
Spills:
Secure spill area and deny entry to all unprotected individuals. Individuals involved in the cleanup should wear appropriate personal
protective equipment. Area may become slippery. Absorb product onto porous material, such as sand, clay, diatomaceous earth or
commercial absorbent material. Place into leak-proof, U.S. DOT-approved containers. If necessary, cover all drains and dike well
ahead of the spill to prevent runoff into sewers, drains, and all waterways. Contact appropriate local or provincial authorities for
assistance and/or reporting requirements.
SAFETY DATA SHEET
Page 3 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
7. HANDLING & STORAGE INFORMATION
7.1
Work & Hygiene Practices:
Wash hands thoroughly after using this product and before eating, drinking, or smoking. Remove soiled clothing to prevent prolonged skin
contact.
7.2
Storage & Handling:
Store at temperatures between 59-95 °F (15-35 °C) in a dry, well-ventilated location. Keep away from heat, sparks, open flame, and other
sources of ignition. Normal shelf-life: 2-3 years.
7.3
Special Precautions:
Empty containers can contain flammable vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1
Ventilation & Engineering Controls:
Use with adequate ventilation (e.g., open doors and windows, local exhaust ventilation). Ensure appropriate decontamination equipment
is available (e.g., sink, safety shower, eye-wash station).
8.2
Respiratory Protection:
None required, when used with adequate ventilation.
8.3
Eye Protection:
Wear safety glasses with side shields (ANSI Z87) under normal use conditions.
8.4
Hand Protection:
None required under normal conditions of use. However, may cause skin irritation in some sensitive individuals. In such cases, wear
rubber or impervious plastic gloves.
8.5
Body Protection:
Use as necessary to prevent skin contact.
9. PHYSICAL & CHEMICAL PROPERTIES
9.1
Density:
0.75 – 0.85
9.2
Boiling Point:
-25 °C @ 760 mmHg
9.3
Melting Point:
NA
9.4
Evaporation Rate:
0.11 (n-Butyl Acetate = 1.0)
9.5
Vapor Pressure:
87 psig @ 20 °C
9.6
Molecular Weight:
NA
9.7
Appearance & Color:
Light red, aerosol
9.8
Odor Threshold:
Ethereal/hydrocarbon odor
9.9
Solubility:
Not soluble in water
9.10
pH
ND
9.11
Viscosity:
10.0 cPs
9.12
Other Information:
Vapor Density = 2.4 (Air = 1.0)
10. STABILITY & REACTIVITY
10.1
Stability:
Stable under normal conditions of use (see section 7).
10.2
Hazardous Decomposition Products:
Change in color signifies exposure to ultraviolet light or exceeding shelf life. Will not degrade to unstable products. Discard solution.
10.3
Hazardous Polymerization:
Will not occur.
10.4
Conditions to Avoid:
Use or storage near open flames, sparks, high heat (>100 °F) or other heat sources, and proximity to incompatible substances and heavily
trafficked areas.
10.5
Incompatible Substances:
Strong oxidizers.
SAFETY DATA SHEET
Page 4 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
11. TOXICOLOGICAL INFORMATION
11.1
Toxicity Data:
This product has not been tested on animals to obtain toxicological data. There are toxicology data for the components of this product,
which are found in the scientific literature. These data have not been presented in this document.
11.2
Acute Toxicity:
See section 2.5
11.3
Chronic Toxicity:
See section 2.6
11.4
Suspected Carcinogen:
NE
11.5
Reproductive Toxicity:
This product is not reported to produce reproductive toxicity in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to produce reproductive effects in humans.
11.6
Irritancy of Product:
See Section 2.3
11.7
Biological Exposure Indices:
NE
11.8
Physician Recommendations:
Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1
Environmental Stability:
This product will slowly volatile from soil. Components of this product will slowly decompose into organic compounds.
12.2
Effects on Plants & Animals:
There is no specific data available for this product.
12.3
Effects on Aquatic Life:
Releases of large volumes of this product are expected to be harmful or fatal to overexposed aquatic life.
13. DISPOSAL CONSIDERATIONS
13.1
Waste Disposal:
Dispose of in accordance with federal, state or local regulations.
13.2
Special Considerations:
EPA Waste Code: D001 (characteristic – ignitability)
14. TRANSPORTATION INFORMATION
The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of tra nsportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1
49 CFR (GND):
CONSUMER COMMODITY, ORM-D (until 12/31/2020)
UN1950, AEROSOLS, 2.1, LTD QTY (IP VOL ≤ 1.0 L)
14.2
IATA (AIR):
CONSUMER COMMODITY, 9, ID8000 (≤ 500 ml)
UN1950, AEROSOLS, 2.1 (> 500 ml)
14.3
IMDG (OCN):
UN1950, AEROSOLS, 2.1, LTD QTY (IP VOL ≤ 1.0 L)
14.4
TDGR (Canadian GND):
MARK PACKAGE "LIMITED QUANTITY" or "QUANTITÉ LIMITÉE" or "LTD QTY" or "QUANT LTÉE" (≤ 1.0 L)
14.5
ADR/RID (EU):
UN1950, AEROSOLS, 2.1, LTD QTY (IP VOL ≤ 1.0 L)
14.6
SCT (Mexico):
UN1950, AEROSOLES, 2.1, CANTIDAD LIMITADA (IP VOL ≤ 1.0 L)
14.7
ADGR (Australia):
UN1950, AEROSOLS, 2.1, LTD QTY (IP VOL ≤ 1.0 L)
SAFETY DATA SHEET
Page 5 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
15. REGULATORY INFORMATION
15.1
SARA Reporting Requirements:
NA
15.2
SARA Threshold Planning Quantity:
NA
15.3
TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempt from inventory status.
15.4
CERCLA Reportable Quantity (RQ):
NA
15.5
Other Federal Requirements:
NA
15.6
Other Canadian Regulations
This product has been classified according to the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all of the information required by the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed on the Priorities Substances List.
15.7
State Regulatory Information:
The primary component of this product is not listed on the following state lists: California OSHA; California Proposition 65; Massachusetts
Right to Know List of Chemicals; New Jersey Right to Know List 8:59 Appendix A; Pennsylvania Hazardous Substances List 34 323 Appendix
A; Wisconsin Hazardous Substances List NR 605.09; Minnesota Hazardous Substances List; and Florida Toxic Substances List.
15.8
67/548/EEC (European Union) Requirements:
The primary component of this product is listed in Annex I of EU Directive 67/548/EEC:
Difluoroethane: Flammable, Harmful (F, Xn). Risk Phrases (R): 10-65 – Flammable. Harmful: may cause lung
damage if swallowed. Safety Phrases (S): 2-23-24-62 – Keep away from children. Do not breathe gas, fumes,
vapor or spray. Avoid contact with skin. If swallowed, do not induce vomiting: seek medical advice immediately
and show this MSDS or the container label.
WARNING! Flammable aerosol. Colorless, volatile liquid with ethereal and faint sweetish odor. Overexposure
may cause dizziness and loss of concentration. At higher levels, CNS depression and cardiac arrhythmia may
result from exposure. Vapors displace air and can cause asphyxiation in confined spaces.
Hazard Statements (H): H223 – Flammable aerosol.
Precautionary Statements (P): P210 – Keep away from heat/sparks/open flames/hot surfaces. P211 – Do not spray
on an open flame or other ignition source. P251 – Pressurized container. Do not pierce or burn, even after use.
P280 – Wear protective gloves and eyewear. P302 + P352 – IF ON SKIN – Wash with plenty of soap and water.
P312 – Call a Poison Control Center or doctor/physician if you feel unwell. P333 + P313 – If skin irritation or rash
occurs, get medical advise/attention. P321 – Refer to section 4 of this Safety Data Sheet (First Aid).
P305+P351+P338 – IF IN EYES - Rinse continuously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing. P501 – Dispose of contents/container through licensed treatment, storage or
disposal facility.
16. OTHER INFORMATION
16.1
Other Information:
NA
16.2
Terms & Definitions:
See last page of this Safety Data Sheet.
16.3
Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of ShipMate's & CAIG Laboratories, Inc.’s knowledge, the
information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed
and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only to the specific
product(s). If this product(s) is combined with other materials, all component properties must be considered. Data may be changed from
time to time. Be sure to consult the latest edition.
16.4
Prepared for:
CAIG Laboratories, Inc.
12200 Thatcher Court
Poway, CA 92064-6876
Tel: +1 (800) CAIG-123 (244-4123)
Fax: +1 (858) 486-8398 fax
http://www.caig.com/
16.5
Prepared by:
ShipMate, Inc.
P.O. Box 787
780 Buckaroo Trail Suite D
Sisters, OR 97759
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
SAFETY DATA SHEET
Page 6 of 6
MSDS-E-D100S-2
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58/EC & 1272/2008/EC Standards
MSDS Revision: 2.1
MSDS Revision Date: 08/20/2013
DEFINITION OF TERMS
CAS No.
Chemical Abstract Service Number
ACGIH
American Conference on Governmental Industrial Hygienists
TLV
Threshold Limit Value
OSHA
U.S. Occupational Safety and Health Administration
PEL
Permissible Exposure Limit
IDLH
Immediately Dangerous to Life and Health
CPR
Cardiopulmonary resuscitation - method in which a person whose heart has stopped
receives manual chest compressions and breathing to circulate blood and provide
oxygen to the body.
0
Minimal Hazard
HEALTH
1
Slight Hazard
FLAMMABILITY
2
Moderate Hazard
PHYSICAL HAZARDS
3
Severe Hazard
PERSONAL PROTECTION
4
Extreme Hazard
PERSONAL PROTECTION RATINGS:
A
G
B
H
C
I
D
J
E
K
F
X
Consult your supervisor or SOPs for special
handling directions.
Safety Glasses
Splash Goggles
Face Shield &
Eye Protection
Gloves Boots
Synthetic Apron
Full Suit
Dust Respirator
Full Face Respirator
Dust & Vapor Half-
Mask Respirator
Full Face Respirator
Airline Hood/Mask or
SCBA
Note: the dotted circle indicates that this respiratory protective equipment is
required for high concentrations or for large volume spills or releases of
product.
NA
Not Available
NR
No Results
NE
Not Established
ND
Not Determined
ML
Maximum Limit
SCBA
Self-Contained Breathing Apparatus
FLAMMABILITY LIMITS IN AIR:
Autoignition
Temperature
Minimum temperature required to initiate combustion in air with no other source of
ignition
LEL
Lower Explosive Limit - lowest percent of vapor in air, by volume, that will explode
or ignite in the presence of an ignition source
UEL
Upper Explosive Limit - highest percent of vapor in air, b y volume, that will explode
or ignite in the presence of an ignition source
0
Minimal Hazard
1
Slight Hazard
2
Moderate Hazard
3
Severe Hazard
4
Extreme Hazard
ACD
Acidic
ALK
Alkaline
COR
Corrosive
W
Use No Water
OX
Oxidizer
TREFOIL
Radioactive
LD50
Lethal Dose (solids & liquids) which kills 50% of the exposed animals s
LC
50
Lethal concentration (gases) which kills 50% of the exposed animal
ppm
Concentration expressed in parts of material per million parts
TD
lo
Lowest dose to cause a symptom
TCLo
Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or
TC, TCo, LClo, & LC
o
Lowest dose (or concentration) to cause lethal or toxic effects
IARC
International Agency for Research on Cancer
NTP
National Toxicology Program
RTECS
Registry of Toxic Effects of Chemical Substances
BCF
Bioconcentration Factor
TL
m
Median threshold limit
log KOW or log K
OC
Coefficient of Oil/Water Distribution
WHMIS
Canadian Workplace Hazardous Material Information System
DOT
U.S. Department of Transportation
TC
Transport Canada
EPA
U.S. Environmental Protection Agency
DSL
Canadian Domestic Substance List
NDSL
Canadian Non-Domestic Substance List
PSL
Canadian Priority Substances List
TSCA
U.S. Toxic Substance Control Act
EU
European Union (European Union Directive 67/548/EEC)
WGK
Wassergefährdungsklassen (German Water Hazard Class)
A B C
D1
D2
D3 E F
Compressed
Flammable
Oxidizing
Toxic
Irritation
Infectious
Corrosive
Reactive
C E F N O
T+
Xi
Xn
Corrosive
Explosive
Flammable
Harmful
Oxidizing
Toxic
Irritant
Harmful
GHS01
GHS02
GHS03
GHS04
GHS05
GHS06
GHS07
GHS08
GHS09
Explosive
Flammable
Oxidizer
Pressurized
Corrosive
Toxic
Harmful
Irritating
Health
Hazard
Environment
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
EXPOSURE LIMITS IN AIR:
FIRST AID MEASURES:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: HMIS
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
HAZARD RATINGS:
TOXICOLOGICAL INFORMATION:
OTHER STANDARD ABBREVIATIONS:
REGULATORY INFORMATION:
WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION (WHMIS) SYSTEM:
EC (67/548/EEC) INFORMATION:
CLP/GHS (1272/2008/EC) PICTOGRAMS:
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
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