Brother TZ-SE4 User Manual

PRODUCT SAFETY INFORMATION SHEET

（

）

EN

PSIS

Page: 1 of 5

Issued: November 08, 2010
Revised: July 01, 2016
Versi on number: 13
PSIS No. 5VA926-P1-EUUSOTHER

Brother Industries, Ltd.

15-1 Naeshiro-cho, Mizuho-ku,

Nagoya 467-8561, Japan

Telephone (for information) : [phone]

Product name: TZe cassette, TZ cassette

With regard to the model number, please find attached the list of the model
numbers.

Use of Product: These products are TZe cassette or TZ cassette for Brother Industries, Ltd. P-touch.

The above product consis ts of the following major parts and com ponents.
Also please find attac hed the SDS.

TZe cassette and TZ cassette are ‘Article’ and we have voluntarily made the SDS.

Name of part/Component Material SDS No.

1) Cassette case upper ABS N/A

2) Cassette case lower ABS N/A

3) Film tape PET N/A

4) Spacer PP or PET N/A

5) Ribbon clutch spr ing SWC or SWPB N/A

6) Ribbon clutch spr ing holder POM N/A

7) Take-up spool ABS or HIPS N/A

8) Take-up spool spring SUS N/A

9) T ape feed roller ABS or HIPS N/A

10) Adhesive tape rol l er PP N/A

11) Ta pe roller PE N/A

12) Sensor part s ABS N/A

13) Color indication PS or Paper N/A

14) TZe cassette ribbon /

-- 5VA926-M1-EUUSOTHER

TZ cassette ribbon

15) TZe cassette tape /

-- 5VA926-M2-EUUSOTHER

TZ cassette tap e

16) Spool ABS or AS or HIPS N/A

PRODUCT SAFETY INFORMATION SHEET

（

）

EN

TZe-111

TZe-111V

TZe-121

TZe-121V

TZe-131

TZe-1312PK

TZe-131S

TZe-131V

TZe-132

TZe-133

TZe-135

TZe-141

TZe-141V

TZe-145

TZe-151

TZe-151V

TZe-161

TZe-161V

TZe-211

TZe-211V

TZe-221

TZe-221V

TZe-221V2

TZe-222

TZe-223

TZe-231

TZe-2311

TZe-2312PK

TZe-2314PK

TZe-231CIV

TZe-231S

TZe-231V

TZe-231V2

TZe-231V10

TZe-232

TZe-2322

TZe-233

TZe-241

TZe-241CIV

TZe-241V

TZe-242

TZe-243

TZe-251

TZe-251CIV

TZe-251V

TZe-251V10

TZe-252

TZe-253

TZe-261

TZe-261CIV

TZe-261V

TZe-262

TZe-263

TZe-315

TZe-31M3

TZe-31V3

TZe-31VA

TZe-325

TZe-32M3

TZe-335

TZe-33M3

TZe-345

TZe-355

TZe-365

TZe-421

TZe-431

TZe-431S

TZe-435

TZe-441

TZe-451

TZe-461

TZe-521

TZe-531

TZe-535

TZe-541

TZe-545

TZe-551

TZe-555

TZe-561

TZe-611

TZe-611V

TZe-621

TZe-621V

TZe-631

TZe-631S

TZe-631V

TZe-641

TZe-641V

TZe-651

TZe-651V

TZe-661

TZe-661V

TZe-721

TZe-731

TZe-735

TZe-741

TZe-751

TZe-761

TZe-AF131

TZe-AF231

TZe-B31

TZe-B41

TZe-B51

TZe-BA151

TZe-BA155

TZe-BW31

TZe-BY31

TZe-C31

TZe-C51

TZe-DB31

TZe-DH31

TZe-DL31

TZe-DP31

TZe-DW31

TZe-DY31

TZe-FX211

TZe-FX221

TZe-FX231

TZe-FX231CS

TZe-FX241

TZe-FX251

TZe-FX261

TZe-FX431

TZe-FX441

TZe-FX451

TZe-FX551

TZe-FX611

TZe-FX621

TZe-FX631

TZe-FX631CS

TZe-FX641

TZe-FX651

TZe-FX661

TZe-FX731

TZe-FX741

TZe-FX751

TZe-HP31

TZe-HY31

TZe-HW31

TZe-J231

TZe-LG31

TZe-LW31

TZe-M251

TZe-M31

TZe-M32

TZe-M33

TZe-M35

TZe-M921

TZe-M931

TZe-M941

TZe-M951

TZe-M961

TZe-MB31

TZe-MPGG31

TZe-MPMC31

TZe-MPPF31

TZe-MPPH31

TZe-MPRG31

TZe-MPSL31

TZe-MPTP31

TZe-MPYS31

TZe-MQ531

TZe-MQ835

TZe-MQE31

TZe-MQF31

TZe-MQG35

TZe-MQL35

TZe-MQP35

TZe-MR35

TZe-MV31

TZe-MW31

TZe-N201

TZe-N221

TZe-N231

TZe-N241

TZe-N251

TZe-Q35V3

TZe-RY31

TZe-S121

TZe-S131

TZe-S135

TZe-S141

TZe-S151

TZe-S211

TZe-S221

TZe-S231

TZe-S231CS

TZe-S241

TZe-S241CS

TZe-S251

TZe-S261

TZe-S621

TZe-S631

TZe-S641

TZe-S641CS

TZe-S651

TZe-S661

TZe-S941

TZe-S951

TZe-S961

TZe-SE4

TZe-SE5

TZe-SG31

TZe-SM941

TZe-SM951

Issued: November 08, 2010
Revised: July 01, 2016
Versi on number: 13
PSIS No. 5VA926-P1-EUUSOTHER

Model Number List
The model numbers to be covered with PSIS No. 5VA926-P1-EUUSOTHER are as below.

PSIS

Page: 2 of 5

PRODUCT SAFETY INFORMATION SHEET

（

）

EN

TZe-SM961

TZe-SW31

TZe-UB31

TZe-UP31

TZe-YGP3PK

HGe-121

HGe-1215PK

HGe-131

HGe-1315PK

HGe-131V

HGe-131V5

HGe-141

HGe-1415PK

HGe-141V

HGe-141V5

HGe-151

HGe-1515PK

HGe-151V

HGe-151V5

HGe-161

HGe-1615PK

HGe-211

HGe-2115PK

HGe-221

HGe-2215PK

HGe-221V

HGe-221V5

HGe-231

HGe-2315PK

HGe-231V

HGe-231V5

HGe-241

HGe-2415PK

HGe-241V

HGe-241V5

HGe-251

HGe-2515PK

HGe-251V

HGe-251V5

HGe-261

HGe-2615PK

HGe-261V

HGe-261V5

HGe-621

HGe-6215PK

HGe-621V5

HGe-631

HGe-6315PK

HGe-631V

HGe-631V5

HGe-641

HGe-6415PK

HGe-641V

HGe-641V5

HGe-651

HGe-6515PK

HGe-651V

HGe-651V5

HGe-661

HGe-6615PK

HGe-9415PK

HGe-9515PK

HGe-9615PK

HGe-M931

HGe-M931V

HGe-M931V5

HGe-M941

HGe-M9415PK

HGe-M941V

HGe-M941V5

HGe-M951

HGe-M9515PK

HGe-M951V

HGe-M951V5

HGe-M961

HGe-S121

HGe-S1215PK

HGe-S131

HGe-S1315PK

HGe-S141

HGe-S1415PK

HGe-S151

HGe-S1515PK

HGe-S211

HGe-S2115PK

HGe-S221

HGe-S2215PK

HGe-S231

HGe-S2315PK

HGe-S231V

HGe-S241

HGe-S2415PK

HGe-S241V

HGe-S251

HGe-S2515PK

HGe-S251V

HGe-S261

HGe-S2615PK

HGe-S621

HGe-S6215PK

HGe-S631

HGe-S6315PK

HGe-S631V

HGe-S641

HGe-S6415PK

HGe-S641V

HGe-S651

HGe-S6515PK

HGe-S651V

HGe-S661

HGe-S6615PK

HGe-S9415PK

HGe-S9515PK

HGe-S9615PK

HGe-SM931

HGe-SM931V

HGe-SM941

HGe-SM941V

HGe-SM951

HGe-SM951V

HGe-SM961

HGe-SM961V5

Issued: November 08, 2010
Revised: July 01, 2016
Versi on number: 13
PSIS No. 5VA926-P1-EUUSOTHER

PSIS

Page: 3 of 5

PRODUCT SAFETY INFORMATION SHEET

（

）

EN

TZ-111

TZ-111V

TZ-121

TZ-121V

TZ-122

TZ-123

TZ-125

TZ-131

TZ-131V

TZ-132

TZ-133

TZ-135

TZ-141

TZ-141V

TZ-143

TZ-145

TZ-151

TZ-151V

TZ-152

TZ-153

TZ-155

TZ-161

TZ-161V

TZ-165

TZ-211

TZ-211V

TZ-221

TZ-2212PK

TZ-221V

TZ-221V2

TZ-222

TZ-223

TZ-231

TZ-2312PK

TZ-231CIV

TZ-231S

TZ-231V

TZ-231V10

TZ-231V2

TZ-232

TZ-233

TZ-241

TZ-241CIV

TZ-241V

TZ-2413

TZ-242

TZ-243

TZ-251

TZ-251CIV

TZ-251V

TZ-251V10

TZ-252

TZ-253

TZ-261

TZ-261CIV

TZ-261V

TZ-262

TZ-263

TZ-315

TZ-31M3

TZ-31V3

TZ-31VA

TZ-325

TZ-335

TZ-345

TZ-355

TZ-365

TZ-411

TZ-421

TZ-431

TZ-431S

TZ-435

TZ-441

TZ-451

TZ-455

TZ-461

TZ-511

TZ-521

TZ-531

TZ-535

TZ-541

TZ-545

TZ-551

TZ-555

TZ-561

TZ-611

TZ-611V

TZ-621

TZ-621V

TZ-631

TZ-631V

TZ-635

TZ-641

TZ-641V

TZ-651

TZ-651V

TZ-655

TZ-661

TZ-661V

TZ-711

TZ-721

TZ-731

TZ-735

TZ-741

TZ-751

TZ-755

TZ-761

TZ-831

TZ-841

TZ-851

TZ-931

TZ-941

TZ-951

TZ-A25

TZ-A31

TZ-A51

TZ-AF131

TZ-AF231

TZ-AFG31

TZ-AFP31

TZ-AFW31

TZ-B21

TZ-B31

TZ-B41

TZ-B51

TZ-BA151

TZ-BA155

TZ-BW31

TZ-BY31

TZ-C21

TZ-C31

TZ-C41

TZ-C51

TZ-D21

TZ-D231

TZ-D241

TZ-D31

TZ-D41

TZ-D51

TZ-D631

TZ-DB31

TZ-DB41

TZ-DC31

TZ-DE31

TZ-DF31

TZ-DG31

TZ-DH31

TZ-DH41

TZ-DL31

TZ-DL41

TZ-DP31

TZ-DV31A

TZ-DV31B

TZ-DW31

TZ-DY31

TZ-FX111

TZ-FX121

TZ-FX131

TZ-FX141

TZ-FX151

TZ-FX161

TZ-FX211

TZ-FX221

TZ-FX231

TZ-FX241

TZ-FX242

TZ-FX251

TZ-FX261

TZ-FX262

TZ-FX431

TZ-FX611

TZ-FX621

TZ-FX631

TZ-FX641

TZ-FX651

TZ-FX661

TZ-FX731

TZ-GB31

TZ-GY31

TZ-HB31

TZ-HW31

TZ-M21

TZ-M241

TZ-M251

TZ-M31

TZ-M41

TZ-M51

TZ-M831

TZ-M841

TZ-M851

TZ-M931

TZ-M941

TZ-M951

TZ-M961

TZ-MQ835

TZ-MQG35

TZ-MQL35

TZ-MQP35

TZ-N201

TZ-N211

TZ-N221

TZ-N231

TZ-N241

TZ-N251

TZ-N631

Issued: November 08, 2010
Revised: July 01, 2016
Versi on number: 13
PSIS No. 5VA926-P1-EUUSOTHER

PSIS

Page: 4 of 5

PRODUCT SAFETY INFORMATION SHEET

（

）

EN

TZ-N641

TZ-N651

TZ-Q35V3

TZ-S111

TZ-S121

TZ-S131

TZ-S135

TZ-S141

TZ-S145

TZ-S151

TZ-S155

TZ-S161

TZ-S211

TZ-S221

TZ-S231

TZ-S231CS

TZ-S241

TZ-S241CS

TZ-S251

TZ-S261

TZ-S611

TZ-S621

TZ-S631

TZ-S641

TZ-S641CS

TZ-S651

TZ-S661

TZ-SE4

TZ-SM941

TZ-SM951

TZ-SM961

TZ-UB31

TZ-UP31

TZ-US31

HG-131

HG-131V

HG-131V5

HG-141

HG-1415PK

HG-141V

HG-141V5

HG-151

HG-1515PK

HG-151V

HG-151V5

HG-211

HG-221

HG-2215PK

HG-221V

HG-221V5

HG-231

HG-2315PK

HG-231V

HG-231V5

HG-241

HG-2415PK

HG-241V

HG-241V5

HG-251

HG-2515PK

HG-251V

HG-251V5

HG-261

HG-261V

HG-261V5

HG-621

HG-621V5

HG-631

HG-631V

HG-631V5

HG-641

HG-6415PK

HG-641V

HG-641V5

HG-651

HG-6515PK

HG-651V

HG-651V5

HG-M931

HG-M931V

HG-M931V5

HG-M941

HG-M9415PK

HG-M941V

HG-M941V5

HG-M951

HG-M9515PK

HG-M951V

HG-M951V5

Issued: November 08, 2010
Revised: July 01, 2016
Versi on number: 13
PSIS No. 5VA926-P1-EUUSOTHER

PSIS

Page: 5 of 5

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 1 / 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name

TZe cassette ribbon, TZ cassette ribbon

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant Identified Use(s)

These products are ink ribbons for Brother Industries, Ltd. TZe cassette ribbon, TZ cassette ribbon.

1.3 Details of the supplier of the safety data sheet

Manufacturer

Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): [phone]

Importer (USA)

Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): [phone]

Importer (Canada)

Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): [phone]

Importer (Europe)

Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): [phone]

Importer (Australia)

Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): [phone]

E-mail Address

[e-mail]

1.4 Emergency telephone number

Emergency Telephone
(24 hours)

CHEMTREC
[phone] (International)
[phone] (North America)

For France only:
Antipoison Center telephone number: ORFILA [phone]

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 2 / 9

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Not classified as hazardous

Australia Classification

Not classified as hazardous according to the criteria of NOHSC

2.2 Label elements

Labelling according to Regulation (EC) No. 1272/2008

Hazard pictograms

None

Signal Word

None

Hazard Statements

None

Precautionary statements

None

2.3 Other hazards

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioaccumulating (vPvB).

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 3 / 9

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Description of the mixture: Ink on substrate film (Mixture).

Chemical Name

CAS-No

EC-No

Classification

(EU Reg.

1272/2008)

Black

w/w%

White
w/w%

Red

w/w%

Blue

w/w%

Carbon Black

1333-86-4

215-609-9

Not classified

2-9

-

-

-

Paraffin wax

8002-74-2

232-315-6

Not classified

<=12

7

<=10

<=10

Titanium dioxide

13463-67-7

236-675-5

Not classified

-

33-35

-

-

Silicon Dioxide

(amorphous)

7631-86-9

231-545-4

Not classified

-

2

-

-

Copper compound

**

**

Not classified

-

-

-

<=4

Colorant

**

**

Not classified

-

**

**

**

Resin

**

**

Not classified

**

**

**

**

Wax

**

**

Not classified

**

**

**

**

Additive

**

**

Not classified

**

**

**

**

Synthetic resin

**

**

Not classified

**

-

**

**

Organic Filler

**

**

Not classified

**

-

**

**

Dispersant

**

**

Not classified

**

-

**

**

Polyethylene

terephthalate film

**

**

Not classified

**

**

**

**

For the full text of R-phrases and H-Statements see Section 16

** CONFIDENTIAL

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

If symptoms persist, obtain medical attention.

Inhalation

Not applicable.

Skin contact

Wash affected skin with plenty of water or soap and water.

Eye contact

Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.

Ingestion

Obtain medical attention. Wash out mouth with water and give 100 - 200 ml of water to drink.

4.2 Most important symptoms and
effects, both acute and delayed

No specific effects and/or symptoms have been reported or known

4.3 Indication of any immediate
medical attention and special
treatment needed

Treat symptomatically.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 4 / 9

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable Extinguishing Media

Extinguish preferably with dry chemical, carbon dioxide, water mist, foam.

Unsuitable Extinguishing Media

None.

5.2 Special hazards arising from the
substance or mixture

No information available

5.3 Advice for firefighters

A self contained breathing apparatus and suitable protective clothing should be worn in fire
conditions.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective
equipment and emergency
procedures

Not normally required.

6.2 Environmental precautions

Avoid release to the environment.

6.3 Methods and materials for
containment and cleaning up

Not applicable

6.4 Reference to other sections

For personal protection: See section 8.
For disposal considerations: See section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes.

7.2 Conditions for safe storage,
including any incompatibilities

Keep away from oxidizing agents.

7.3 Specific end use(s)

These products are ink ribbons for Brother Industries, Ltd. TZe cassette ribbon, TZ cassette ribbon.

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Occupational Exposure Limits

Chemical Name

Carbon Black

1333-86-4

ACGIH TLV

TWA: 3 mg/m3 inhalable fraction

OSHA PEL

TWA: 3.5 mg/m3

European Union

-

The United Kingdom

STEL: 7 mg/m3

TWA: 3.5 mg/m3

France

TWA: 3.5 mg/m3

Spain

TWA: 3.5 mg/m3

Germany

Carc

Portugal

TWA: 3.5 mg/m3

Finland

TWA: 3.5 mg/m3

STEL: 7 mg/m3

Denmark

TWA: 3.5 mg/m3

Poland

TWA: 4.0 mg/m3

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 5 / 9

Norway

TWA: 3.5 mg/m3

STEL: 7 mg/m3

Ireland

TWA: 3.5 mg/m3

STEL: 7 mg/m3

Chemical Name

Paraffin wax

8002-74-2

ACGIH TLV

TWA: 2 mg/m3 fume

OSHA PEL

-

European Union

-

The United Kingdom

STEL: 6 mg/m3

TWA: 2 mg/m3

France

TWA: 2 mg/m3

Spain

TWA: 2 mg/m3

Portugal

TWA: 2 mg/m3

Finland

TWA: 1 mg/m3

Denmark

TWA: 2 mg/m3

Switzerland

TWA: 2 mg/m3

Poland

TWA: 2 mg/m3

Norway

TWA: 2 mg/m3

STEL: 4 mg/m3

Ireland

TWA: 2 mg/m3

STEL: 6 mg/m3

Chemical Name

Titanium dioxide

13463-67-7

ACGIH TLV

TWA: 10 mg/m3

OSHA PEL

TWA: 15 mg/m3 total dust

European Union

-

The United Kingdom

STEL: 30 mg/m3
STEL: 12 mg/m3

TWA: 10 mg/m3

TWA: 4 mg/m3

France

TWA: 10 mg/m3

Spain

TWA: 10 mg/m3

Germany

Carc

Portugal

TWA: 10 mg/m3

Denmark

TWA: 6 mg/m3

Austria

STEL 10 mg/m3

TWA: 5 mg/m3

Switzerland

TWA: 3 mg/m3

Poland

NDSCh: 30 mg/m3

TWA: 10.0 mg/m3 TWA: 10 mg/m3

Norway

TWA: 5 mg/m3

STEL: 10 mg/m3

Ireland

TWA: 10 mg/m3

TWA: 4 mg/m3

Chemical Name

Silicon Dioxide (amorphous)

7631-86-9

ACGIH TLV

-

OSHA PEL

20mppcf

80(mg/m3)/%SiO2

European Union

-

The United Kingdom

STEL: 18 mg/m3

STEL: 7.2 mg/m3

TWA: 6 mg/m3

TWA: 2.4 mg/m3

Germany

TWA: 4 mg/m3

Austria

TWA: 4 mg/m3

TWA: 0.3 mg/m3

Switzerland

TWA: 4 mg/m3

TWA: 0.3 mg/m3

Norway

TWA: 1.5 mg/m3

STEL: 3 mg/m3

Ireland

TWA: 6 mg/m3

TWA: 2.4 mg/m3

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 6 / 9

8.2 Exposure controls

Appropriate engineering controls

Good general ventilation should be sufficient under normal use.

Personal protective equipment

Not normally required. For use other than in normal operating procedures (such as in the event of
large spill), the following should be applied:

Eye Protection

Safety goggles.

Hand Protection

Protective gloves.

Skin and body protection

Not normally required.

Respiratory protection

No special protective equipment required.

Environmental Exposure Controls

Not normally required.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state

Film

Color

Black. White. Red. Blue.

Odor

Slight wax's odor

Odor Threshold

No information available

pH

Not applicable

Melting point/freezing point

Not applicable

Initial boiling point and boiling range

Not applicable

Flash Point

No information available

Evaporation rate

No information available

Flammability (solid, gas)

No information available

Upper/lower flammability or explosive
limits

No information available
Vapor pressure

Not applicable

Vapor density

Not applicable

Relative density

No information available

Solubility(ies)

Negligible (water)

Partition coefficient: n-octanol/water

No information available

Auto-ignition temperature

No information available

Decomposition temperature

No information available

Viscosity

Not applicable

Explosive properties

Not applicable

Oxidizing properties

No information available

9.2 Other information

No information available.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 7 / 9

SECTION 10: Stability and reactivity

10.1 Reactivity

No information available.

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous
reactions

No information available.

10.4 Conditions to avoid

Keep away from heat. Avoid friction, sparks, or other means of ignition.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition
products

Contains: Carbon monoxide, Carbon dioxide and Nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation

No information available.

Eye contact

No information available.

Skin contact

No information available.

Ingestion

No information available.

Skin corrosion/irritation

No information available.

Serious eye damage/irritation

No information available.

Respiratory or skin sensitisation

No information available.

Mutagenicity

No information available.

Carcinogenicity

Printing inks: IARC Classification: Group 3 (Non-classified Human Carcinogen)
Titanium dioxide: IARC Classification: Group 2B (Possible human carcinogen)
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible

human carcinogen). This classification is given to chemicals, for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies performed
in animal models other than rats did not show any association between carbon black and lung
tumors.

Other ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 8 / 9

SECTION 12: Ecological information

12.1 Toxicity

Chemical Name

Toxicity to algae

Toxicity to fish

Toxicity to daphnia and other

aquatic invertebrates

Carbon Black

1333-86-4

EC50: >5600 mg/L 24 h

(Daphnia magna)

Silicon Dioxide (amorphous)

7631-86-9

EC50: 440 mg/L 72 h

(Pseudokirchneriella subcapitata)

LC50: 5000 mg/L 96 h static

(Brachydanio rerio)

EC50: 7600 mg/L 48 h

(Ceriodaphnia dubia)

12.2 Persistance and degradability

No information available.

12.3 Bioaccumulative potential

No information available.

12.4 Mobility in soil

No information available.

12.5 Results of PBT and vPvB
assessment

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).

12.6 Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Dispose of in accordance with Federal, State, and local regulations.

SECTION 14: Transport information

Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"

14.1 UN Number

None

14.2 UN proper shipping name

None

14.3 Transport hazard class(es)

None

14.4 Packing Group

None

14.5 Environmental hazards

None

14.6 Special precautions for user

None

14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code

Not applicable

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 18-September-2015

Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)

Version: 7

SDS No: 5VA926-M1-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 9 / 9

SECTION 15: Regulatory information

15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture

EU:Not classified as dangerous for supply/use. (CLP Regulation)
USA: All chemical substances contained in this product are and had been listed on the TSCA

Chemical Substances Inventory, and none is subject to any of the following TSCA requirements:
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent
orders; section 8(a) preliminary assessment information rules; and section 8(d) health and safety
data reporting rules.

Canada: WHMIS: Not applicable. (Manufactured article)

15.2 Chemical Safety Assessment

No.

SECTION 16: Other information

Full text of H-Statements referred to
under sections 2 and 3

None

Additional information

The information relates only to this product. It may not be valid, if used in combination with any other
materials or in any other process, and it is based on our best knowledge as of the date of preparation
(revision).

Revision Note

Section 1, 2, 3, 8, 9,12,15,16

References:

U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens

Abbreviations:

ACGIH: American Conference of Governmental Industrial Hygienists
IARC: International Agency for Research on Cancer
NOHSC: National Occupational Health and Safety Commission (Australia)
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (US)
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Act (US)
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 1 / 8

SECTION 1: Identification of the substance/mixture and of the compan y/undertaking

1.1 Product identifier

Product name

TZe cassette tape, TZ cassette tape

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant Identified Use(s)

These products are tapes for Brother Industries, Ltd. TZe cassette tape, TZ cassette tape

1.3 Details of the supplier of the safety data sheet

Manufacturer

Brother Industries, Ltd.
15

-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan

Telephone (for information): [phone]

Importer (USA)

Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): [phone]

Importer (Canada)

Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): [phone]

Importer (Europe)

Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): [phone]

Importer (Australia)

Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): [phone]

E-mail Address

[e-mail]

1.4 Emergency telephone number

Emergency Telephone
(24 hours)

CHEMTREC
+1
+1

For France only:
Antipoison Center telephone number: ORFILA [phone]

-703-527-3887 (International)

-800-424-9300 (North America)

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 2 / 8

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Not classified as hazardous

Classification according to Directive 1999/45/EC

Not classified as hazardous

Australia Classification

Not classified as hazardous according to the criteria of NOHSC

2.2 Label elements

Labelling according to Regulation (EC) No. 1272/2008

Hazard pictograms

None

Signal Word

None

Hazard Statements

None

Precautionary statements

None

2.3 Other hazards

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioaccumulating (vPvB).

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Description of the mixture: TZe cassette tape (Article), TZ cassette tape (Article).

Chemical Name

CAS-No

EC-No

w/w%

Classification

(67/548/EEC)

Classification

(EU Reg. 1272/2008)

Polyester film

**

**

-

Not classified

Not classified

Ink

**

**

-

Not classified

Not classified

Acrylic adhesive

**

**

-

Not classified

Not classified

Liner

**

**

-

Not classified

Not classified

For the full text of R-phrases and H-Statements see Section 16

** CONFIDENTIAL

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 3 / 8

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

If symptoms persist, obtain medical attention.

Inhalation

Not applicable.

Skin contact

Wash affected skin with plenty of water or soap and water.

Eye contact

Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.

Ingestion

Obtain medical attention. Wash out mouth with water and give 100 - 200 ml of water to drink.

4.2 Most important symptoms and
effects, both acute and delayed

No specific effects and/or symptoms have been reported or known

4.3 Indication of any immediate
medical attention and special
treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable Extinguishing Media

Extinguish preferably with dry chemical, carbon dioxide, water, foam.

Unsuitable Extinguishing Media

None.

5.2 Special hazards arising from the
substance or mixture

No information available

5.3 Advice for firefighters

A self contained breathing apparatus and suitable protective clothing should be worn in fire
conditions.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective
equipment and emergency
procedures

Not normally required.

6.2 Environmental precautions

Avoid release to the environment.

6.3 Methods and materials for
containment and cleaning up

Not applicable

6.4 Reference to other sections

For personal protection: See section 8.
For disposal considerations: See section 13.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 4 / 8

SECTION 7: Handling and storage

7.1 Precautions for safe handling

No special requirements.

7.2 Conditions for safe storage,
including any incompatibilities

Keep away from oxidizing agents.

7.3 Specific end use(s)

These products are tapes for Brother Industries, Ltd. TZe cassette tape, TZ cassette tape.

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

Good general ventilation should be sufficient under normal use.

Personal protective equipment

Not normally required. For use other than in normal operating procedures (such as in the event of
large spill), the following should be applied:

Eye Protection

Safety goggles.

Hand Protection

Protective gloves.

Skin and body protection

Not normally required.

Respiratory protection

No special protective equipment required.

Environmental Exposure Contro ls

Not normally required.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 5 / 8

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state

Tape rolled

Color

Various colors

Odor

Odorless

Odor Threshold

No information available

pH

Not applicable

Melting point/freezing point

Not applicable

Initial boiling point and boiling range

Not applicable

Flash Point

Not applicable

Evaporation rate

Not applicable

Flammability (solid, gas)

No information available

Upper/lower flammability or explosive
limits

No information available
Vapor pressure

Not applicable

Vapor density

Not applicable

Relative density

No information available

Solubility(ies)

Insoluble (water)

Partition coefficient: n-octanol/water

No information available

Auto-ignition temperature

No information available

Decomposition temperature

No information available

Viscosity

Not applicable

Explosive properties

Not applicable

Oxidizing properties

No information available

9.2 Other information

No information available.

SECTION 10: Stability and reactivity

10.1 Reactivity

No information available.

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous
reactions

No information available.

10.4 Conditions to avoid

Keep away from heat. Avoid friction, sparks, or other means of ignition.

10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition
products

Contains: Carbon monoxide, Carbon dioxide and Nitrogen oxides.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 6 / 8

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Inhalation

No information available.

Eye contact

No information available.

Skin contact

No information available.

Ingestion

No information available.

Skin corrosion/irritation

No information available.

Serious eye damage/irritation

No information available.

Respiratory or skin sensitisation

No information available.

Mutagenicity

No information available.

Carcinogenicity

Ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA.

SECTION 12: Ecological information

12.1 Toxicity

No information available.

12.2 Persistance and degradability

No information available

12.3 Bioaccumulative potential

No information available

12.4 Mobility in soil

No information available.

12.5 Results of PBT and vPvB
assessment

This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).

12.6 Other adverse effects

No information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Dispose of in accordance with Federal, State, and local regulations.

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 7 / 8

SECTION 14: Transport information

Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"

14.1 UN Number

None

14.2 UN proper shipping name

None

14.3 Transport hazard class(es)

None

14.4 Packing Group

None

14.5 Environmental hazards

None

14.6 Special precautions for user

None

14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code

Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture

EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA:

Che
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent
orders; section 8(a) preliminary assessment information rules
data reporting rules.

Canada: WHMIS: Not applicable. (Manufactured article)

15.2 Chemical Safety Assessment

No.

All chemical substances contained in this product are and had been listed on the TSCA

mical Substances Inventory, and none is subject to any of the following TSCA requirements:

; and section 8(d) health and safety

SAFETY DATA SHEET

Issuing Date: 08-November-2010

Revision Date: 01-July-2016

Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)

Version: 5

SDS No: 5VA926-M2-EUUSOTHER

_________________________________________________________________________________________________________________

_________________________________________________________________________________________________________________

EN

Page 8 / 8

SECTION 16: Other information

Full text of R-phrases referred to
under sections 2 and 3

None

Full text of H-Statements referred to
under sections 2 and 3

None

Additional information

The information relates only to this product. It may not be valid, if used in combination with any
other materials or in any other process, and it is based on our best knowledge as of the date of
preparation (revision).

Revision Note

Updated for compliance with EU Regulations 453/2010 and 172/2008 (CLP).

References:

U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens

Abbreviations:

ACGIH: American Conference of Governmental Industrial Hygienists
IARC: International Agency for Research on Cancer
NOHSC: National Occupational Health and Safety Commission (Australia)
NTP: National Toxico
OSHA: Occupational Safety and Health Administration (US)
PEL: Permiss ble Exposure Limit
STEL: Short Term Exposure Limit
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Act (US)
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)

logy Program (US)