PRODUCT SAFETY INFORMATION SHEET
（
）
EN
PSIS
Page: 1 of 5
Issued: November 08, 2010
Revised: January 29, 2015
Versi on number: 9
PSIS No. 5VA926-P1-EUUSOTHER
Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku,
Nagoya 467-8561, Japan
Telephone (for information ) : + 81-52-824-2735
Product name: TZe cassette, TZ cassette
With regard to the model number, please find attached the list of the model
numbers.
Use of Product: These products are TZe cassette or TZ cassette for Brother Industries, Ltd. P-touch.
The above product consis ts of the following major parts and com ponents.
Also please find attached the SDS.
TZe cassette and TZ cassette are ‘Article’ and we have voluntarily made the SDS.
Name of part/Component Material SDS No.
1) Cassette case upper ABS N/A
2) Cassette case lower ABS N/A
3) Film tape PET N/A
4) Spacer PP or PET N/A
5) Ribbon clutch spring SWC or SWPB N/A
6) Ribbon clutch spring holder POM N/A
7) Take-up spool ABS or HIPS N/A
8) Take-up spool spring SUS N/A
9) T ape feed roller ABS or HIPS N/A
10) Adhesive tape rol l er PP N/A
11) Ta pe roller PE N/A
12) Sensor part s ABS N/A
13) Color indication PS or Paper N/A
14) TZe cassette ribbon /
-- 5VA926-M1-EUUSOTHER
TZ cassette ribbon
15) TZe cassette tape /
-- 5VA926-M2-EUUSOTHER
TZ cassette tap e
16) Spool ABS or AS or HIPS N/A
PRODUCT SAFETY INFORMATION SHEET
（
）
EN
TZe-111
TZe-111V
TZe-121
TZe-121V
TZe-131
TZe-1312PK
TZe-131V
TZe-132
TZe-133
TZe-135
TZe-141
TZe-141V
TZe-145
TZe-151
TZe-151V
TZe-161
TZe-161V
TZe-211
TZe-211V
TZe-221
TZe-221V
TZe-221V2
TZe-222
TZe-223
TZe-231
TZe-2312PK
TZe-231CIV
TZe-231S
TZe-231V
TZe-231V2
TZe-231V10
TZe-232
TZe-233
TZe-241
TZe-241CIV
TZe-241V
TZe-242
TZe-243
TZe-251
TZe-251CIV
TZe-251V
TZe-251V10
TZe-252
TZe-253
TZe-261
TZe-261CIV
TZe-261V
TZe-262
TZe-263
TZe-315
TZe-31M3
TZe-31V3
TZe-31VA
TZe-325
TZe-32M3
TZe-334
TZe-335
TZe-33M3
TZe-344
TZe-345
TZe-354
TZe-355
TZe-365
TZe-421
TZe-431
TZe-431S
TZe-435
TZe-441
TZe-451
TZe-461
TZe-521
TZe-531
TZe-535
TZe-541
TZe-545
TZe-551
TZe-555
TZe-561
TZe-611
TZe-611V
TZe-621
TZe-621V
TZe-631
TZe-631V
TZe-641
TZe-641V
TZe-651
TZe-651V
TZe-661
TZe-661V
TZe-721
TZe-731
TZe-735
TZe-741
TZe-751
TZe-AF131
TZe-AF231
TZe-B31
TZe-B41
TZe-B51
TZe-BA151
TZe-BA155
TZe-BW31
TZe-BY31
TZe-C31
TZe-C51
TZe-DB31
TZe-DH31
TZe-DL31
TZe-DP31
TZe-DW31
TZe-DY31
TZe-FX211
TZe-FX221
TZe-FX231
TZe-FX231CS
TZe-FX241
TZe-FX251
TZe-FX261
TZe-FX431
TZe-FX441
TZe-FX451
TZe-FX611
TZe-FX621
TZe-FX631
TZe-FX631CS
TZe-FX641
TZe-FX651
TZe-FX661
TZe-FX731
TZe-FX741
TZe-FX751
TZe-HP31
TZe-HY31
TZe-HW31
TZe-J231
TZe-M251
TZe-M31
TZe-M32
TZe-M33
TZe-M34
TZe-M35
TZe-M921
TZe-M931
TZe-M941
TZe-M951
TZe-M961
TZe-MB31
TZe-MQ835
TZe-MQ934
TZe-MQG35
TZe-MQL35
TZe-MQP35
TZe-MR35
TZe-MV31
TZe-MW31
TZe-N201
TZe-N221
TZe-N231
TZe-N241
TZe-N251
TZe-Q35V3
TZe-RY31
TZe-S121
TZe-S131
TZe-S135
TZe-S141
TZe-S151
TZe-S211
TZe-S221
TZe-S231
TZe-S231CS
TZe-S241
TZe-S241CS
TZe-S251
TZe-S261
TZe-S621
TZe-S631
TZe-S641
TZe-S641CS
TZe-S651
TZe-S661
TZe-S941
TZe-S951
TZe-S961
TZe-SE4
TZe-SG31
TZe-SM941
TZe-SM951
TZe-SM961
TZe-SW31
TZe-UB31
TZe-UP31
PSIS
Page: 2 of 5
Issued: November 08, 2010
Revised: January 29, 2015
Versi on number: 9
PSIS No. 5VA926-P1-EUUSOTHER
Model Number List
The model numbers to be c overed with PSIS No. 5VA926-P1-EUUSOTHER are as below.
PRODUCT SAFETY INFORMATION SHEET
（
）
EN
HGe-121
HGe-1215PK
HGe-131
HGe-1315PK
HGe-131V
HGe-131V5
HGe-141
HGe-1415PK
HGe-141V
HGe-141V5
HGe-151
HGe-1515PK
HGe-151V
HGe-151V5
HGe-161
HGe-1615PK
HGe-211
HGe-2115PK
HGe-221
HGe-2215PK
HGe-221V
HGe-221V5
HGe-231
HGe-2315PK
HGe-231V
HGe-231V5
HGe-241
HGe-2415PK
HGe-241V
HGe-241V5
HGe-251
HGe-2515PK
HGe-251V
HGe-251V5
HGe-261
HGe-2615PK
HGe-261V
HGe-261V5
HGe-621
HGe-6215PK
HGe-621V5
HGe-631
HGe-6315PK
HGe-631V
HGe-631V5
HGe-641
HGe-6415PK
HGe-641V
HGe-641V5
HGe-651
HGe-6515PK
HGe-651V
HGe-651V5
HGe-661
HGe-6615PK
HGe-9415PK
HGe-9515PK
HGe-9615PK
HGe-M931
HGe-M931V
HGe-M931V5
HGe-M941
HGe-M9415PK
HGe-M941V
HGe-M941V5
HGe-M951
HGe-M9515PK
HGe-M951V
HGe-M951V5
HGe-M961
HGe-S121
HGe-S1215PK
HGe-S131
HGe-S1315PK
HGe-S141
HGe-S1415PK
HGe-S151
HGe-S1515PK
HGe-S211
HGe-S2115PK
HGe-S221
HGe-S2215PK
HGe-S231
HGe-S2315PK
HGe-S231V
HGe-S241
HGe-S2415PK
HGe-S241V
HGe-S251
HGe-S2515PK
HGe-S251V
HGe-S261
HGe-S2615PK
HGe-S621
HGe-S6215PK
HGe-S631
HGe-S6315PK
HGe-S631V
HGe-S641
HGe-S6415PK
HGe-S641V
HGe-S651
HGe-S6515PK
HGe-S651V
HGe-S661
HGe-S6615PK
HGe-S9415PK
HGe-S9515PK
HGe-S9615PK
HGe-SM931
HGe-SM931V
HGe-SM941
HGe-SM941V
HGe-SM951
HGe-SM951V
HGe-SM961
HGe-SM961V5
Issued: November 08, 2010
Revised: January 29, 2015
Versi on number: 9
PSIS No. 5VA926-P1-EUUSOTHER
PSIS
Page: 3 of 5
PRODUCT SAFETY INFORMATION SHEET
（
）
EN
TZ-111
TZ-111V
TZ-121
TZ-121V
TZ-122
TZ-123
TZ-125
TZ-131
TZ-131V
TZ-132
TZ-133
TZ-135
TZ-141
TZ-141V
TZ-143
TZ-145
TZ-151
TZ-151V
TZ-152
TZ-153
TZ-155
TZ-161
TZ-161V
TZ-164
TZ-165
TZ-211
TZ-211V
TZ-221
TZ-2212PK
TZ-221V
TZ-221V2
TZ-222
TZ-223
TZ-231
TZ-2312PK
TZ-231CIV
TZ-231S
TZ-231V
TZ-231V10
TZ-231V2
TZ-232
TZ-233
TZ-241
TZ-241CIV
TZ-241V
TZ-2413
TZ-242
TZ-243
TZ-251
TZ-251CIV
TZ-251V
TZ-251V10
TZ-252
TZ-253
TZ-261
TZ-261CIV
TZ-261V
TZ-262
TZ-263
TZ-315
TZ-31M3
TZ-31V3
TZ-31VA
TZ-324
TZ-325
TZ-334
TZ-335
TZ-344
TZ-345
TZ-354
TZ-355
TZ-364
TZ-365
TZ-411
TZ-421
TZ-431
TZ-431S
TZ-435
TZ-441
TZ-451
TZ-455
TZ-461
TZ-511
TZ-521
TZ-531
TZ-535
TZ-541
TZ-545
TZ-551
TZ-555
TZ-561
TZ-611
TZ-611V
TZ-621
TZ-621V
TZ-631
TZ-631V
TZ-635
TZ-641
TZ-641V
TZ-651
TZ-651V
TZ-655
TZ-661
TZ-661V
TZ-711
TZ-721
TZ-731
TZ-735
TZ-741
TZ-751
TZ-755
TZ-761
TZ-831
TZ-841
TZ-851
TZ-931
TZ-941
TZ-951
TZ-A25
TZ-A31
TZ-A51
TZ-AF131
TZ-AF231
TZ-AFG31
TZ-AFP31
TZ-AFW31
TZ-B21
TZ-B31
TZ-B41
TZ-B51
TZ-BA151
TZ-BA155
TZ-BW31
TZ-BY31
TZ-C21
TZ-C31
TZ-C41
TZ-C51
TZ-D21
TZ-D231
TZ-D241
TZ-D31
TZ-D41
TZ-D51
TZ-D631
TZ-DB31
TZ-DB41
TZ-DC31
TZ-DE31
TZ-DF31
TZ-DG31
TZ-DH31
TZ-DH41
TZ-DL31
TZ-DL41
TZ-DP31
TZ-DV31A
TZ-DV31B
TZ-DW31
TZ-DY31
TZ-FX111
TZ-FX121
TZ-FX131
TZ-FX141
TZ-FX151
TZ-FX161
TZ-FX211
TZ-FX221
TZ-FX231
TZ-FX241
TZ-FX242
TZ-FX251
TZ-FX261
TZ-FX262
TZ-FX431
TZ-FX611
TZ-FX621
TZ-FX631
TZ-FX641
TZ-FX651
TZ-FX661
TZ-FX731
TZ-GB31
TZ-GY31
TZ-HB31
TZ-HW31
TZ-M21
TZ-M241
TZ-M251
TZ-M31
TZ-M41
TZ-M51
TZ-M831
TZ-M841
TZ-M851
TZ-M931
TZ-M941
TZ-M951
TZ-M961
TZ-MQ835
TZ-MQ934
TZ-MQG35
TZ-MQL35
TZ-MQP35
Issued: November 08, 2010
Revised: January 29, 2015
Versi on number: 9
PSIS No. 5VA926-P1-EUUSOTHER
PSIS
Page: 4 of 5
PRODUCT SAFETY INFORMATION SHEET
（
）
EN
TZ-N201
TZ-N211
TZ-N221
TZ-N231
TZ-N241
TZ-N251
TZ-N631
TZ-N641
TZ-N651
TZ-Q35V3
TZ-S111
TZ-S121
TZ-S131
TZ-S135
TZ-S141
TZ-S145
TZ-S151
TZ-S155
TZ-S161
TZ-S211
TZ-S221
TZ-S231
TZ-S231CS
TZ-S241
TZ-S241CS
TZ-S251
TZ-S261
TZ-S611
TZ-S621
TZ-S631
TZ-S641
TZ-S641CS
TZ-S651
TZ-S661
TZ-SE4
TZ-SM941
TZ-SM951
TZ-SM961
TZ-UB31
TZ-UP31
TZ-US31
HG-131
HG-131V
HG-131V5
HG-141
HG-1415PK
HG-141V
HG-141V5
HG-151
HG-1515PK
HG-151V
HG-151V5
HG-211
HG-221
HG-2215PK
HG-221V
HG-221V5
HG-231
HG-2315PK
HG-231V
HG-231V5
HG-241
HG-2415PK
HG-241V
HG-241V5
HG-251
HG-2515PK
HG-251V
HG-251V5
HG-261
HG-261V
HG-261V5
HG-621
HG-621V5
HG-631
HG-631V
HG-631V5
HG-641
HG-6415PK
HG-641V
HG-641V5
HG-651
HG-6515PK
HG-651V
HG-651V5
HG-M931
HG-M931V
HG-M931V5
HG-M941
HG-M9415PK
HG-M941V
HG-M941V5
HG-M951
HG-M9515PK
HG-M951V
HG-M951V5
Issued: November 08, 2010
Revised: January 29, 2015
Versi on number: 9
PSIS No. 5VA926-P1-EUUSOTHER
PSIS
Page: 5 of 5
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 1 / 11
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name
TZe ca s sette ribbon, TZ cassette ribbon
1.2 Relevant ident ified uses of the subst an ce or mixt ure and us e s advis ed ag ain st
Relevant Identified Use(s)
These products are ink ribbons for Brother Industries, Ltd. TZe cassette ribbon, TZ cassette ribbon.
1.3 Details of the supplier of the safety data sheet
Manufacturer
Brother Industries, Ltd.
15
-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Tele phone (for information): +81-52-824-2735
Imp orter (USA)
Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-800-284-4329
Importer (C an ada)
Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Euro pe)
Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Tele phone (for information): +44-161-330-6531
Importer (Aus tral ia)
Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Tele phone (for information): +61-2-9887-4344
E-mail Addres s
sds.inf o@brother.co.jp
1.4 Emergency telephone number
Emergency Telephone
(24 hours)
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33-1-45-425-959
-703-527-3887 (International)
-800-424-9300 (North America)
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 2 / 11
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Not classified as hazardous
Classification according to D ire ctiv e 19 99/4 5/EC
Not classified as hazardous
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
Hazard pi ct ograms
None
Signal Word
None
Hazard St at em en t s
None
Precautionary statements
None
2.3 Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioacc u mulati ng (vPvB).
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 3 / 11
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: Ink on substrate film (Mixture).
Chemical Name
CAS-No
EC-No
Classification
(67/548/EEC)
Classification
1272/2008)
Black
White
Red
Blue
w/w %
Gold
Carbon Black
1333-86-4
215-609-9
Not classified
Not classified
2-9
-
-
-
-
Paraff i n wax
8002-74-2
232-315-6
Not classified
Not classified
<=12
7
<=10
<=10
<=9
Titanium dioxide
13463-67-7
236-675-5
Not classified
Not classified
-
33-35
-
-
-
Silicon Dioxide
(amorphous)
7631-86-9
231-545-4
Not classified
Not classified
-
2
-
-
-
Copper
7440-50-8
231-159-6
Not classified
Not classified
-
-
-
-
<=17
Copper compound
**
**
Not classified
Not classified
-
-
-
<=4
-
Colorant
**
**
Not classified
Not classified
-
**
**
**
**
Resin
**
**
Not classified
Not classified
**
**
**
**
**
Wax
**
**
Not classified
Not classified
**
**
**
**
**
Additive
**
**
Not classified
Not classified
**
**
**
**
**
Synthetic resin
**
**
Not classified
Not classified
**
-
**
**
**
Organic Filler
**
**
Not classified
Not classified
**
-
**
**
**
Dispersant
**
**
Not classified
Not classified
**
-
**
**
**
Brass powder
**
**
Not classified
Not classified
-
-
-
-
**
Polyethylene
terephthalate film
**
**
Not classified
Not classified
**
**
**
**
**
For the full text of R-phrases and H-Statements see Section 16
** CONFIDENTIAL
SECTION 4: First aid measures
4.1 Descri p ti o n of fir st ai d mea su r es
Gener al ad vice
If symptoms persist, obtain medical attention.
Inhalation
Not applicable.
Skin contact
W ash affected skin wi th pl enty of water or s oap and water.
Eye contact
Obtain medical at t ention. If subs t ance has got in to the eyes , im m edi ately was h out with plenty of
water for at least 15 minutes.
Ingestion
Obtain medical at t ention. W ash ou t m outh with wat er and give 100 - 200 ml of water to drink.
4.2 Most important symptoms and
effects, both acute and delayed
No specif ic ef f ects and/or sym pt oms have b een r eported or kn ow n
4.3 Indication of any immediate
medical attenti on an d spe ci al
treatment needed
Treat symptomatically.
(EU Reg.
w/w%
w/w%
w/w%
w/w%
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 4 / 11
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable Extinguishing Media
Extinguish preferably with dry chemical, carbon dioxide, water mist, foam.
Unsuitable Extinguishing Media
Non e.
5.2 Special hazards arising from the
substance or mixture
No information available
5.3 Advice for firefighters
A self cont ained breat hi ng appar atus an d suitabl e pr ot ec ti v e cl othing should be worn in f ir e
conditions.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective
equipment and emergency
procedures
Not normally required.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and materials for
containment an d cle ani ng up
Not applicable
6.4 Reference to other sections
For personal protection: See section 8.
For disposal considerations: See section 13.
SECTION 7: Handling and storage
7.1 Precautions for saf e ha ndli ng
Avoid c ont act w ith skin and ey es .
7.2 Conditions for safe storage,
including any incompatibilities
Keep awa y fr om oxi dizing agents.
7.3 Specific end use(s)
These products are ink ribbons for Brother Industries, Ltd. TZe cassette ribbon, TZ cassette ribbon.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Occupational Exposure Limits
Chemical Name
Carbon Bl ac k
1333-86-4
ACGIH TLV
TWA: 3 mg/m3 inhalable fraction
OSHA PEL
TWA: 3.5 mg/m3
European Union
-
The United Kingdo m
STEL: 7 mg/m3
TWA: 3.5 mg/m3
France
TWA: 3.5 mg/m3
Spain
TWA: 3.5 mg/m3
Germany
Carc
Portugal
TWA: 3.5 mg/m3
Finland
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Denmark
TWA: 3.5 mg/m3
Poland
TWA: 4.0 mg/m3
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 5 / 11
Norway
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Ireland
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Chemical Name
Paraffi n w ax
8002-74-2
ACGIH TLV
TWA: 2 mg/m3 fume
OSHA PEL
-
European Union
-
The United Kingdo m
STEL: 6 mg/m3
TWA: 2 mg/m3
France
TWA: 2 mg/m3
Spain
TWA: 2 mg/m3
Portugal
TWA: 2 mg/m3
Finland
TWA: 1 mg/m3
Denmark
TWA: 2 mg/m3
Switzerland
TWA: 2 mg/m3
Poland
TWA: 2 mg/m3
Norway
TWA: 2 mg/m3
STEL: 4 mg/m3
Ireland
TWA: 2 mg/m3
STEL: 6 mg/m3
Chemical Name
Titanium dioxid e
13463-67-7
ACGIH TLV
TWA: 10 mg/m3
OSHA PEL
TWA: 15 mg/m3 total dust
European Union
-
The United Kingdo m
STEL: 30 mg/m3
STEL: 12 mg/m3
TWA: 4 mg/m3
France
TWA: 10 mg/m3
Spain
TWA: 10 mg/m3
Germany
Carc
Portugal
TWA: 10 mg/m3
Denmark
TWA: 6 mg/m3
Austria
STEL 10 mg/m3
TWA: 5 mg/m3
Switzerland
TWA: 3 mg/m3
Poland
NDSCh: 3 0 mg/ m3
TWA: 10.0 mg/m3 TWA: 10 mg/m3
Norway
TWA: 5 mg/m3
STEL: 10 mg/m3
Ireland
TWA: 10 mg/m3
TWA: 4 mg/m3
Chemical Name
Silicon Dioxide (amorphous)
7631-86-9
ACGIH TLV
-
OSHA PEL
20mppcf
80(mg/m3)/%SiO2
European Union
-
The United Kingdo m
STEL: 18 mg/m3
TWA: 2.4 mg/m3
Germany
TWA: 4 mg/m3
Austria
TWA: 4 mg/m3
TWA: 0.3 mg/m3
Switzerland
TWA: 4 mg/m3
TWA: 0.3 mg/m3
Norway
TWA: 1.5 mg/m3
STEL: 3 mg/m3
Ireland
TWA: 6 mg/m3
TWA: 2.4 mg/m3
TWA: 10 mg/m
3
STEL: 7.2 mg/m3
TWA: 6 mg/m
3
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 6 / 11
Chemical Name
Copper
7440-50-8
ACGIH TLV
TWA: 0.2 mg/m3 fume TWA: 1 mg/m3 Cu dust an d mis t
OSHA PEL
TWA: 1 mg/m3 dusts and mists (as Cu)
European Union
-
The United Kingdo m
STEL: 0.6 mg/m3
STEL: 2 mg/m3
TWA: 1 mg/m3
France
TWA: 0.2 mg/m3
STEL: 2 mg/m3
Spain
TWA: 0.2 mg/m3
TWA: 1 mg/m3
Germany
TWA: 0.1 mg/m3
Ceiling / Peak: 0.2 mg/m3
Portugal
TWA: 0.2 mg/m3
TWA: 1 mg/m3
The Nether l ands
TWA: 0.1 mg/m3
Finland
TWA: 1 mg/m3
TWA: 0.1 mg/m3
Denmark
TWA: 1.0 mg/m3
TWA: 0.1 mg/m3
Austria
STEL 4 mg/m3
TWA: 0.1 mg/m3
Switzerland
STEL: 0.2 ppm
TWA: 0.1 ppm
Poland
TWA: 0.2 mg/m3
Norway
TWA: 0.1 mg/m3
STEL: 3 mg/m3
Ireland
TWA: 0.2 mg/m3
STEL: 2 mg/m3
8.2 Exposure controls
Appropriat e engineering contr ol s
Good general ventilation should be sufficient under normal use.
Personal protective equipment
Not norm all y required . For use other th an in normal operating procedures (suc h as in th e ev en t of
large spill), the following should be applied:
Eye Protection
Safety goggles.
Hand Protection
Protec ti ve gl o ves .
Skin and bod y protect i on
Not normally required.
Respiratory protection
No special protective equipment required.
Environmental Exposure Controls
Not normally required.
TWA: 0.2 mg/m
TWA: 1 mg/m3
3
STEL 0.4 mg/m3
TWA: 1 mg/m
TWA: 1 mg/m3
STEL: 0.3 mg/m
TWA: 1 mg/m3
3
3
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 7 / 11
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Film
Color
Black. White. Red. Blue. Gold.
Odor
Slight w ax's od or
Odor Threshold
No information available
pH
Not applicable
Melting point/freezing point
Not applicable
Initial b oiling poi nt an d b oiling rang e
Not applicable
Fla s h Point
No information available
Evaporation rate
No information available
Flammability (solid, gas)
No information available
Upper/l ower flam m abil i t y or exp losive
limits
No information available
Vapor pr ess ur e
Not applicable
Vapor density
Not applicable
Relati ve d ens i t y
No information available
Solubility(ies)
Negligible (water)
Partition coeffic ient: n-octanol/water
No information available
Auto-ignition t em p er at ure
No information available
Decomposition temperature
No information available
Viscosity
Not applicable
Explosive properties
Not applicable
Oxidizi ng properties
No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
No information available.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous
reactions
No information available.
10.4 Conditio ns to avoid
Keep awa y fr om h eat . Avoid fric ti on, sparks , or other mean s of ign it i o n.
10.5 Incompatible materials
Strong o xi di zi ng ag ents.
10.6 Hazardous decomposition
products
Contains: Carbon monoxide, Carbon dioxide and Nitrogen oxides.
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 8 / 11
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation
No information available.
Eye contact
No information available.
Skin contact
No information available.
Ingestion
No information available.
Skin corrosion/irritation
No information available.
Serious eye damage/irritation
No information available.
Respiratory or ski n sen sitisati o n
No information available.
Mutagenicity
No information available.
Carcinogenicity
Printing inks: IARC Classification: Group 3 (Non-classified Human Carcinogen)
Titanium dioxide: IARC Classification: Group 2B (Possible human carcinogen)
Carbon Black: In 1996, the IARC re
human carcinogen). This classification is given to chemicals, for which there is inadequate human
evidence, but suf ficient ani m al evi d ence on whic h to b as e an opi n
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies performed
in animal models other than r
tumors.
Other ingredients of this product have not been classified as carcinogens according to IARC
monograph s, NT P and OS HA.
-evaluated carbon black as a Group 2B carcinogen (possible
ion of carcinogenici ty. The
ats did not sh ow an y associati on bet w e en c ar b on bl ac k and lung
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 9 / 11
SECTION 12: Ecological information
12.1 Toxicity
Chemical Name
Toxicity to algae
Toxicity to fish
Toxicity to daphnia and other
aquatic invertebrates
Carbon Black
1333-86-4
EC50: >5600 mg/ L 24 h
(Daphnia magna)
Silicon Dioxide (amorphous)
7631-86-9
EC50: 440 mg/L 72 h
(Pseudokirchneriella subcapitata)
LC50: 5000 mg/ L 96 h st at ic
(Brachydanio rerio)
EC50: 7600 mg/L 48 h
(Cer iodaphnia dubia)
Copper
7440-50-8
EC50: 0.0426 - 0. 0535 mg/ L 72 h
LC50: 0.0068 - 0.0156 mg/L 96 h
LC
rough
LC
through
(Poecilia reticulata)
EC50: 0.03 m g/L 48 h Static
12.2 Pers istance an d d egradabi li ty
No information available.
12.3 Bioa cc umulative potent i al
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB
assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).
12.6 Other adv erse eff ect s
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispos e of in accord ance with Fed er al, St ate, and loc al regulat i ons .
static (Pseudokirchneriella
subcapitata)
EC50: 0.031 - 0.054 mg/L 96 h
static (Pseudokirchneriella
subcapitata)
(Pimephales pr om el as )
LC50: 0.3 mg/L 96 h stat ic
(Pimephales pr om el as )
: 0.2 mg/L 96 h fl ow-through
LC
50
(Pimephales pr om el as )
: 0.052 mg/ L 96 h flow-th
50
(Onc orhynchus m yk is s )
LC50: 1.25 mg/L 96 h static
(Lepomis m acrochir us )
: 0.3 mg/L 96 h sem i-static
LC
50
(Cyprinus carpio)
: 0.8 mg/L 96 h stat ic
LC
50
(Cyprinus carpio)
: 0.112 mg/ L 96 h flow-
50
(Daphnia magna)
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 10 / 11
SECTION 14: Transport information
Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"
14.1 UN Nu mber
None
14.2 UN proper shippi ng na m e
None
14.3 Transport hazard class(es)
None
14.4 Packing Group
None
14.5 Environmental hazards
None
14.6 Special precautions for user
None
14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code
Not applicable
SECTION 15: Regulatory information
15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA:
Che
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent
orders; section 8(a) preliminary assessment information rules
data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article)
15.2 Chemical Safety Assessment
No.
All chemical substances contained in this product are and had been listed on the TSCA
mical Substances Inventory, and none is subject to any of the following TSCA requirements:
; and section 8(d) health and safety
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette ribbon, TZ cassette ribbon
(Please refer to PSIS to find the applicable models)
Version: 6
SDS No: 5VA926-M1-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 11 / 11
SECTION 16: Other information
Full text of R-phrases referred to
under sections 2 and 3
None
Full text of H-Statements referred to
under sections 2 and 3
None
Additional information
The information rel ates only t o this product. It m ay n ot be val id, if us ed in c omb in ation with an y
other materials or in any
other process, and it is based on our best k n ow l ed g e as of t h e dat e of
preparation (revision).
Revision Note
Updated for compliance with EU Regulations 453/2010 and 172/2008 (CLP).
References:
U.S. 29C FR P art 19 10
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Direct i ve 91 /3 22/EEC an d 20 00/39/EC
NTP 11th Report on Carcinogens
Abbreviations:
ACGIH: American Conference of Governmental Industrial Hygienists
IARC: International Agency for Research on Cancer
NOHSC: National Occupational Health and Safety Commission (Australia)
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (US)
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Act (US)
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 1 / 8
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name
TZe cassette tape, TZ cassette tape
1.2 Relevant ident ified uses of the subst an ce or mixt ure and us e s advis ed ag ain st
Relevant Identified Use(s)
These products are tapes for Brother Industries, Ltd. TZe cassette tape, TZ cassette tape
1.3 Details of the supplier of the safety data sheet
Manufacturer
Brother Industries, Ltd.
15
-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Tele phone (for information): +81-52-824-2735
Imp orter (USA)
Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-800-284-4329
Importer (C an ada)
Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Euro pe)
Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Tele phone (for information): +44-161-330-6531
Importer (Aus tral ia)
Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Tele phone (for information): +61-2-9887-4344
E-mail Addres s
sds.inf o@brother.co.jp
1.4 Emergency telephone number
Emergency Telephone
(24 hours)
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33-1-45-425-959
-703-527-3887 (International)
-800-424-9300 (North America)
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 2 / 8
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Not classified as hazardous
Classification according to D ire ctiv e 19 99/4 5/EC
Not classified as hazardous
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
Hazard pi ct ograms
None
Signal Word
None
Hazard St at em en t s
None
Precautionary statements
None
2.3 Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioacc u mu lating (vPvB).
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: TZe cassette tape (Article), TZ cassette tape (A rticle).
Chemical Name
CAS-No
EC-No
w/w%
Classification
(67/548/EEC)
Classification
(EU Reg. 1272/2008)
Polyester film
**
**
-
Not classified
Not classified
Ink
**
**
-
Not classified
Not classified
Acrylic adhesive
**
**
-
Not classified
Not classified
Liner
**
**
-
Not classified
Not classified
For the full text of R-phrases and H-Statements see Section 16
** CONFIDENTIAL
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 3 / 8
SECTION 4: First aid measures
4.1 Descri p ti o n of fir st ai d mea su r es
Gener al ad vice
If symptoms persist, obtain medical attention.
Inhalation
Not applicable.
Skin contact
W ash affected skin wi th pl enty of water or s oap and water.
Eye contact
Obtain medical at t ention. If subs t ance has got in to the eyes , im m edi ately was h out wit h pl enty of
water for at least 15 minutes.
Ingestion
Obtain medical at t ention. W ash ou t m outh with wat er and give 100 - 200 ml of water to drink.
4.2 Most important symptoms and
effects, both acute and delayed
No specif ic ef f ects and/or sym pt oms have b een r eported or kn ow n
4.3 Indication of any immediat e
medical attenti on an d spe ci al
treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable Extinguishing Media
Extinguish preferably with dry chemical, carbon dioxide, water, foam.
Unsuitable Extinguishing Media
Non e.
5.2 Special hazards arising from the
substance or mixture
No information available
5.3 Advice for firefighters
A self cont ained breat hi ng appar atus an d suitabl e pr ot ec ti v e cl othing should be worn in f ir e
conditions.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective
equipment and emergency
procedures
Not normally required.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and materials for
containment an d cle ani ng up
Not applicable
6.4 Reference to other sections
For personal protection: See section 8.
For disposal considerations: See section 13.
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 4 / 8
SECTION 7: Handling and storage
7.1 Precautions for saf e ha ndli ng
No special requirements.
7.2 Conditions for safe storage,
including any incompatibilities
Keep awa y fr om oxi dizing agents.
7.3 Specific end use(s)
These products are tapes for Brother Industries, Ltd. TZe cassette tape, TZ cassette tape.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriat e engineering contr ol s
Good general ventilation should be sufficient under normal use.
Personal protective equipment
Not norm all y required . For use other th an in normal operating procedures (suc h as in th e ev en t of
large spill), the following should be applied:
Eye Protection
Safety goggles.
Hand Protection
Protec ti ve gl o ves .
Skin and bod y protect i on
Not normally required.
Respiratory protection
No special protective equipment required.
Environmental Exposure Controls
Not normally required.
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 5 / 8
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Tape rolled
Color
Various colors
Odor
Odorless
Odor Threshold
No information available
pH
Not applicable
Melting point/freezing point
Not applicable
Initial b oiling poi nt an d b oiling rang e
Not applicable
Fla s h Point
Not applicable
Evaporation rate
Not applicable
Flammability (solid, gas)
No information available
Upper/l ower flam m abil i t y or exp losive
limits
No information available
Vapor pr ess ur e
Not applicable
Vapor density
Not applicable
Relati ve d ens i t y
No information available
Solubility(ies)
Insoluble (water)
Partition coeffic ient: n-octanol/water
No information available
Auto-ignition t em p er at ure
No information available
Decomposition temperature
No information available
Viscosity
Not applicable
Explosive properties
Not applicable
Oxidizi ng properties
No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
No information available.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous
reactions
No information available.
10.4 Conditio ns to avoid
Keep awa y fr om h eat . Avoid fric ti on, sparks , or other mean s of ign it i o n.
10.5 Incompatible materials
Strong o xi di zi ng ag ents.
10.6 Hazardous decomposition
products
Contains: Carbon monoxide, Carbon dioxide and Nitrogen oxi d es .
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 6 / 8
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation
No information available.
Eye contact
No information available.
Skin contact
No information available.
Ingestion
No information available.
Skin corrosion/irritation
No information available.
Serious eye damage/irritation
No information available.
Respiratory or ski n sen sitisati o n
No information available.
Mutagenicity
No information available.
Carcinogenicity
Ingredients of this product have not been classified as carcinogens according to IARC
monograph s, NT P and OS HA.
SECTION 12: Ecological information
12.1 Toxicity
No information available.
12.2 Pers istance an d d egradabi li ty
No information available
12.3 Bioa cc umulative potent i al
No information available
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB
assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).
12.6 Other adverse effects
No information available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispos e of in accord ance with Fed er al, St ate, and loc al regulat i ons .
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 7 / 8
SECTION 14: Transport information
Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"
14.1 UN Nu mber
None
14.2 UN proper shippi ng na m e
None
14.3 Transport hazard class(es)
None
14.4 Packing Group
None
14.5 Environmental hazards
None
14.6 Special precautions for user
None
14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code
Not applicable
SECTION 15: Regulatory information
15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA:
Chemical Substances Inventory, and none is subject to any of the following TSCA requirements:
section 4 test rules; proposed or final section 5(a)(2) significant new use
orders; section 8(a) preliminary assessment information rules; and section 8(d) health and safety
data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article)
15.2 Chemical Safety Assessment
No.
All chemical substances contained in this product are and had been listed on the TSCA
rules; section 5(e) consent
SAFETY DATA SHEET
Issuing Date: 08-November-2010
Revision Date: 10-November-2012
Product name: TZe cassette tape, TZ cassette tape
(Please refer to PSIS to find the applicable models)
Version: 4
SDS No: 5VA926-M2-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 8 / 8
SECTION 16: Other information
Full text of R-phrases referred to
under sections 2 and 3
None
Full text of H-Statements referred to
under sections 2 and 3
None
Additional information
The information rel ates only t o this product. It m ay n ot be val id, if us ed in c omb in ation with an y
other materials or in any other pr oc ess , an d it is b as ed on our b est k n ow l edge as of th e dat e of
preparation (revision).
Revision Note
Updated for compliance with EU Regulations 453/2010 and 172/2008 (CLP).
References:
U.S. 29C FR P art 19 10
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Mon ographs on th e E val u ati on C ar c in
EU Direct i ve 91 /3 22/EEC an d 20 00/39/EC
NTP 11th Report on Carcinogens
Abbreviations:
ACGIH: American Conference of Governmental Industrial Hygienists
IARC: International Agency for Research on Cancer
N
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (US)
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Act (US)
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)
ogenic Risks to Humans World Health Organization
OHSC: National Occupational Health and Safety Commission (Australia)
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