Page 1
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name
TN-410, TN-420, TN-450, TN-2010, TN-2210, TN-2220, TN-2015, TN-2215, TN-2225, TN-2030,
TN-2230, TN-2250, TN-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275 Toner
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant Identified Use(s)
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction
devices and fax receivers. The car
products stated. Information provided on this SDS is only consistent with the use specified by
Brother.
1.3 Details of the supplier of the safety data sheet
Manufacturer
Brother Industries, Ltd.
15
Telephone (for information): +81-52-824-2735
Importer (USA)
Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada)
Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe)
Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia)
Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address
sds.info@brother.co.jp
1.4 Emergency telephone number
Emergency Telephone
(24 hours)
CHEMTREC
+1
+1
+61
For France only:
Antipoison Center telephone number: ORFILA +33-1-45-425-959
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
tridge should be used as supplied by Brother and for use in the
-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
-703-527-3887 (International)
-800-424-9300 (North America)
-290372994 (Australia)
_________________________________________________________________________________________________________________
EN
Page 1 / 9
Page 2
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Not classified as hazardous
Classification according to Directive 1999/45/EC
Not classified as hazardous
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
Hazard pictograms
None
Signal Word
None
Hazard Statements
EUH208 - Contains 'Rosin, fumarated'. May produce an allergic reaction.
Precautionary statements
None
2.3 Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioaccumulating (vPvB).
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
_________________________________________________________________________________________________________________
EN
Page 2 / 9
Page 3
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: Polyester Toner (Mixture)
Chemical Name
CAS-No
EC-No
w/w%
Classification
(EU Reg. 1272/2008)
N,N-diethyl-N-methyl-2-(2-methyl-1
propenyl)oxyethanaminium
2-propenoate and ethenylbenzene
133350-42-2
-
5-10
Eye Irrit. 2 (H319)
Carbon Black (bound)
1333-86-4
215-609-9
2.5-5.5
Not classified
Rosin, fumarated
65997-04-8
266-040-8
1-2.5
Acute Tox. 4 (H302)
Skin Sens. 1 (H317)
Polyester resin
**
-
**
Not classified
For the full text of R-phrases and H-Statements see Section 16
** CONFIDENTIAL
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
If symptoms persist, obtain medical attention.
Inhalation
Obtain immediate medical attention. In case of accident by inhalation remove casualty to fresh air
and keep at rest.
Skin contact
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and
water.
Eye contact
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
Ingestion
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
4.2 Most important symptoms and
effects, both acute and delayed
Inhalation (dust): For large quantities: May cause irritation to the respiratory system. Increased
difficulty in breathing. Sneezing. Coughing.
Eye contact: May cause eye irritatio
Ingestion: May cause stomach ache. Unlikely route of exposure.
4.3 Indication of any immediate
medical attention and special
treatment needed
Treat symptomatically.
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
-oxo-2salt with 4-methylbenzenesulfonic
acid (1:1) polymer with butyl
Eye Dam. 1 (H318)
n.
_________________________________________________________________________________________________________________
EN
Page 3 / 9
Page 4
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable Extinguishing Media
Extinguish preferably with dry chemical, Water spray.
Unsuitable Extinguishing Media
Do not use water jet.
5.2 Special hazards arising from the
substance or mixture
May form explos ble dust clouds in air.
5.3 Advice for firefighters
Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust. Use
appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure
self
during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not having
suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective
equipment and emergency
procedures
Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter type
A/P may be appropriate.
6.2 Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water
drains.
6.3 Methods and materials for
containment and cleaning up
Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container
carefully. Sweep slowly to minimize generation of dust during cleanup. If a vacuum cleaner is used,
the motor must be rated as dust explosion proof.
Potential fo
environment due to pore size in the bag or filter.
6.4 Reference to other sections
For personal protection: See section 8.
For disposal considerations: See section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high concentrations of
dust. Avoid contact with eyes.
7.2 Conditions for safe storage,
including any incompatibilities
Keep away from oxidizing agents.
7.3 Specific end use(s)
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction
devices and fax receivers. This cartridge should be used as supplied by Brother and for use in the
products stated.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Occupational Exposure Limits
Chemical Name
Carbon Black (bound)
1333-86-4
ACGIH TLV
TWA: 3 mg/m3 inhalable fraction
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
-contained breathing apparatus (SCBA) during the attack phase of firefighting operations and
r very fine particles to be taken into the vacuum only to be passed back into the
_________________________________________________________________________________________________________________
EN
Page 4 / 9
Page 5
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
OSHA PEL
TWA: 3.5 mg/m3
European Union
-
The United Kingdom
STEL: 7 mg/m3
TWA: 3.5 mg/m3
France
TWA: 3.5 mg/m3
Spain
TWA: 3.5 mg/m3
Germany
Carc
Portugal
TWA: 3.5 mg/m3
Finland
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Denmark
TWA: 3.5 mg/m3
Poland
TWA: 4.0 mg/m3
Norway
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Ireland
TWA: 3.5 mg/m3
STEL: 7 mg/m3
Additional information
USA OSHA PEL (TWA): 15 mg/m3 (Total Dust) 5mg/m3 (Respirable Fraction).
ACGIH TLV (TWA): 10 mg/m3 (Inhalable particles) 3 mg/m3 (Respirable particles)
8.2 Exposure controls
Appropriate engineering controls
Good general ventilation should be sufficient under normal use.
Personal protective equipment
Not normally required. For use other than in normal operating procedures (such as in the event of
large spill), the following should be applied:
Eye Protection
Safety goggles.
Hand Protection
Protective gloves.
Skin and body protection
Long sleeved clothing and long pants.
Respiratory protection
Dust mask. (Large spillages: Respirator).
Environmental Exposure Controls
Avoid release to the environment.
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
_________________________________________________________________________________________________________________
EN
Page 5 / 9
Page 6
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Powder
Color
Black
Odor
Odorless
Odor Threshold
No information available
pH
Not applicable
Melting point/freezing point
No information available
Initial boiling point and boiling range
Not applicable
Flash Point
Not applicable
Evaporation rate
Not applicable
Flammability (solid, gas)
Not applicable
Upper/lower flammability or explosive
limits
No information available
Vapor pressure
Not applicable
Vapor density
Not applicable
Relative density
1.2 (H2O=1)
Solubility(ies)
Insoluble (water), Partially soluble (toluene, chloroform and tetrahydrofuran)
Partition coefficient: n-octanol/water
No information available
Auto-ignition temperature
No information available
Decomposition temperature
No information available
Viscosity
Not applicable
Explosive properties
Explosive limits of toner particles suspended in air approximately equal to that of coal dust.
Oxidizing properties
No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
No information available.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous
reactions
No information available.
10.4 Conditions to avoid
Keep away from heat. Avoid friction, sparks, or other means of ignition.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition
products
Contains: Carbon monoxide, Carbon dioxide and Nitrogen oxides.
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
_________________________________________________________________________________________________________________
EN
Page 6 / 9
Page 7
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation
Acute LC50 (4 hours)> 2.2 mg/l † (The highest technically achievable concentration) (Method:
OECD#403)
Acute LC
Recommendations on the Transport of Dangerous Goods 2.6.2.2.4.2 and IATA DGR 3.6.1.5.3.1)
Eye contact
No information available.
Skin contact
No information available.
Ingestion
Acute LD50 > 5000 mg/kg (Method: OECD#423)
Skin corrosion/irritation
Non-irritant. † (Method: OECD#404)
Serious eye damage/irritation
Minimal irritant to the eye. † (Method: OECD#405)
Respiratory or skin sensitisation
It is not a skin sensitizer. † (Method: OECD#406)
Mutagenicity
Ames test: Negative. (Method: OECD#471)
Carcinogenicity
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classification is given to chemicals, for which there is inadequate human
evidence, but sufficient animal evidence on which to base an opin
classification is based upon the development of lung tumors in rats receiving chronic inhalation
exposures to free carbon black at levels that induce particle overload of the lung. Studies performed
in animal models other than r
tumors. Moreover, a two
black demonstrated no association between toner exposure and tumor development in rats.
Other
monographs, NTP and OSHA.
†
This assessment is based on information available on similar products
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
(1 hour)> 8.8 mg/l (This figure is calculated according to the United Nations
50
ion of carcinogenicity. The
ats did not show any association between carbon black and lung
-year cancer bioassay using a typical toner preparation containing carbon
ingredients of this product have not been classified as carcinogens according to IARC
_________________________________________________________________________________________________________________
EN
Page 7 / 9
Page 8
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 12: Ecological information
12.1 Toxicity
Chemical Name
Toxicity to algae
Toxicity to fish
Toxicity to daphnia and other
aquatic invertebrates
Carbon Black (bound)
1333-86-4
EC50: >5600 mg/L 24 h
(Daphnia magna)
Rosin, fumarated
65997-04-8
LC50: 3.2 mg/L 96 h static
(Brachydanio rerio)
12.2 Persistance and degradability
No information available.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB
assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).
12.6 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of causing
burn injuries. Shred toner cartridges in a dust/explosion controlled environment. Finely dispersed
particles may form explosive mixtures in the air. Di
local regulations.
SECTION 14: Transport information
Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"
14.1 UN Number
None
14.2 UN proper shipping name
None
14.3 Transport hazard class(es)
None
14.4 Packing Group
None
14.5 Environmental hazards
None
14.6 Special precautions for user
None
14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code
Not applicable
Not regulated under DOT, IMDG, ADR, RID, IATA.
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
spose of in accordance with Federal, State, and
_________________________________________________________________________________________________________________
EN
Page 8 / 9
Page 9
SAFETY DATA SHEET
Issuing Date: 29-March-2010
Revision Date: 06-September-2016
Product name: TN-410, TN-420, TN-450, TN-2010, TN-2210,
TN
-2220, TN-2015, TN-2215, TN-2225, TN-2030, TN-2230, TN-2250,
TN
Toner
Version: 6.1
SDS No: BPB-01-EUUSOTHER
_________________________________________________________________________________________________________________
SECTION 15: Regulatory information
15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA:
Che
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent
orders; section 8(a) preliminary assessment information rules
data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article)
15.2 Chemical Safety Assessment
No.
SECTION 16: Other information
Full text of R-phrases referred to under
sections 2 and 3
R22 - Harmful if swallowed
R36
R41
R43 - May cause sensitization by skin contact
Full text of H-Statements referred to
under sections 2 a
H302 - Harmful if swallowed
H317
H318
H319 - Causes serious eye irritation
Additional information
The information relates only to this product. It may not be valid, if used in combination with any other
materials or in any other process, and it is based on our best knowledge as of the date of preparation
(revision).
Revision Note
(M)SDS sections updated: 1, 3.
References:
U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU
NTP 11th Report on Carcinogens
Abbreviations:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International carriage of Dangerous goods by Road (EU)
DGR: Dang
DOT: Department Of Transportation (US)
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.
NOHSC: National Occupational Health and Safety
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (US)
PEL: Permissible Exposure Limit
RID: Regulations concerning the International carriage of goods by Rail (EU).
STEL: Short Term Exposure Li
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Act (US)
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)
-2060, TN-2260, TN-2280, TN-2080, TN-2090, TN-2235, TN-2275
nd 3
All chemical substances contained in this product are and had been listed on the TSCA
mical Substances Inventory, and none is subject to any of the following TSCA requirements:
; and section 8(d) health and safety
- Irritating to eyes
- Risk of serious damage to eyes
- May cause an allergic skin reaction
- Causes serious eye damage
Directive 91/322/EEC and 2000/39/EC
erous Goods Regulations
mit
_________________________________________________________________________________________________________________
EN
Commission (Australia)
Page 9 / 9
Loading...