BRASSO 89334 User Manual

Page 1
Metal cleaning.
SAFETY DATA SHEET
Product name Distributed by
1. Product and company identification
: :
:
D8049596 v4.0
:
SDS #
Formulation #:
:
#8043677 v1.0
UPC Code / Sizes
:
62338-00117-06 (Noxon Metal Polish 12oz), 26600-89331-00 (Brasso Metal Polish 8oz), 56200-81382-01 (Brasso Metal Polish 142ml)
Brasso Metal Polish
:
Website:
http://www.rbnainfo.com
Emergency telephone number (Medical)
Emergency telephone number (Transport)
:
1-800-338-6167
1-800-424-9300 (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec:703-527-3887
:
This SDS is designed for workplace employees, emergency personnel and for other conditions and situations where there is greater potential for large-scale or prolonged exposure, in accordance with the requirements of USDOL Occupational Safety and Health Administration.
This SDS is not applicable for consumer use of our products. For consumer use, all precautionary and first aid language is provided on the product label in accordance with the applicable government regulations, and shown in Section 15 of this SDS.
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
Reckitt Benckiser LLC. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey 07054-0225 +1 973 404 2600
Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Telephone: +1 905 283 7000
1/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Brasso Metal Polish
Page 2
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
2. Hazards identification
Classification of the substance or mixture
FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (oral) - Category 4 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
:
Signal word
:
Warning
Hazard statements
:
Flammable liquid and vapor. Harmful if swallowed. Causes eye irritation.
Hazard pictograms
:
GHS label elements
Supplemental label elements
:
None known.
Hazards not otherwise classified
:
None known.
General
Prevention
:
Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion­proof electrical, ventilating, lighting and all material-handling equipment. Use only non­sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response
:
IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store in a well-ventilated place. Keep cool.
Disposal
:
Dispose of contents and container in accordance with all local, regional, national and international regulations.
:
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
Precautionary statements
3. Composition/information on ingredients
Mixture
:
Substance/mixture
Ammonia solution
5 - 10
1336-21-6
Ethanedioic acid, hydrate (1:2)
1 - 2.5
6153-56-6
Isopropyl alcohol
1 - 2.5
67-63-0
Ingredient name
CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
2/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 3
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. If irritation persists, get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Description of necessary first aid measures
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Harmful if swallowed. May be irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:::
Eye contact
:
Adverse symptoms may include the following: irritation watering redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
3/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 4
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
4. First aid measures
See toxicological information (Section 11)
5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use dry chemical,
CO₂,
water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
4/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 5
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
7. Handling and storage
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Isopropyl alcohol
ACGIH TLV (United States, 6/2013).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control
Occupational exposure limits
5/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 6
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
: Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
9. Physical and chemical properties
Physical state
Melting point
Liquid. [Viscous liquid.]
Not available.
Ammoniacal.
Odor
pH
Opaque. Light tan.
Color
Flash point
Closed cup: 40.56 to 43.33°C (105 to 110°F)
9.6 to 10.2
Not available.
Odor threshold
:
:
:
:
:
::Appearance
Boiling point
:
Not available.
6/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 7
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.104 to 1.14
Not available.
Not available.
Not available.
Evaporation rate
Not available.
Auto-ignition temperature
Not available.
Not available.
Viscosity
Dynamic (room temperature): 8000 to 11000 mPa·s (8000 to 11000 cP)
Partition coefficient: n­octanol/water
:
:
:
:::
::Flammability (solid, gas)
:
Not available.
Lower and upper explosive (flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.
Chemical stability
Reactive or incompatible with the following materials: oxidizing materials
:
:
:
Incompatible materials
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
Ammonia solution
Eyes - Severe irritant
Rabbit
-
250 Micrograms
-
Eyes - Severe irritant
Rabbit
-
0.5 minutes 1 milligrams
-
Isopropyl alcohol
Eyes - Moderate irritant
Rabbit
-
24 hours 100 milligrams
-
Eyes - Moderate irritant
Rabbit
-
10 milligrams
-
Eyes - Severe irritant
Rabbit
-
100 milligrams
-
Skin - Mild irritant
Rabbit
-
500
-
Product/ingredient name
Result
Score
Exposure
Observation
Species
Information on toxicological effects
Ammonia solution
LD50 Oral
Rat
350 mg/kg
-
Ethanedioic acid, hydrate (1:
2)
LD50 Oral
Rat
33 mg/kg
-
Isopropyl alcohol
LD50 Dermal
Rabbit
12800 mg/kg
-
LD50 Oral
Rat
5000 mg/kg
-
7/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 8
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
milligrams
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Isopropyl alcohol
Category 3
Not applicable.
Narcotic effects
Name
Category
Not available.
Aspiration hazard
Not available.
Route of exposure
Target organs Classification
Isopropyl alcohol
-3-
Product/ingredient name
NTP
IARC
OSHA
Information on the likely routes of exposure
Inhalation
:
Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Harmful if swallowed. May be irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
:
:
Eye contact
:
Adverse symptoms may include the following: irritation watering redness
:
Not available.
Potential acute health effects
8/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 9
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
11. Toxicological information
Not available.
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral
929.5 mg/kg
Route
ATE value
Acute toxicity estimates
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
12. Ecological information
Toxicity
Ammonia solution
Acute LC50 37 ppm Fresh water
Fish - Gambusia affinis - Adult
96 hours
Isopropyl alcohol
Acute LC50 1400000 µg/l Marine water
Crustaceans - Crangon crangon
48 hours
Acute LC50 4200 mg/l Fresh water
Fish - Rasbora heteromorpha
96 hours
Product/ingredient name
Species
Result
Exposure
LogP
ow
BCF
Potential
Bioaccumulative potential
Product/ingredient name
Isopropyl alcohol
0.05-low
Persistence and degradability
Soil/water partition coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
9/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 10
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
12. Ecological information
Other adverse effects
:
No known significant effects or critical hazards.
13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:
Disposal methods
14. Transport information
3
Limited quantity
DOT Classification
TDG Classification
3
Alcohols, n.o.s. RQ (ammonia)
III
UN1987
ALCOHOLS, N.O.S. (Isopropyl alcohol)
III
IMDG Class
ALCOHOLS, N.O.S. (Isopropyl alcohol)
3
III
Alcohols, n.o.s. (Isopropyl alcohol)
UN1987
IATA-DGR Class
3
Regulatory information
UN number
Proper shipping name
Classes
PG*
Label
Additional information
III
UN1987
Limited quantity
See DG List
UN1987
Limited quantity
Mexico Classification
UN1987
ALCOHOLES, N.E.P. (Isopropyl alcohol)
3
III
Limited quantity
PG* : Packing group
10/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 11
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311
: ammonia
:
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: All components are listed or exempted.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602 Class I Substances
:
Not listed
Clean Air Act Section 602 Class II Substances
:
Not listed
DEA List I Chemicals (Precursor Chemicals)
:
Not listed
DEA List II Chemicals (Essential Chemicals)
:
Not listed
The following components are listed: CALCIUM CARBONATE; ISOPROPYL ALCOHOL; AMMONIUM HYDROXIDE
Massachusetts
: SARA 313
Product name
CAS number
%
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
ammonia
1336-21-6
6.4159
Isopropyl alcohol
67-63-0
2.178
ammonia
1336-21-6
6.4159
Isopropyl alcohol
67-63-0
2.178
Form R - Reporting requirements
Supplier notification New York
:
The following components are listed: Ammonium hydroxide
New Jersey
:
The following components are listed: CALCIUM CARBONATE; LIMESTONE; ISOPROPYL ALCOHOL; 2-PROPANOL; AMMONIUM HYDROXIDE
State regulations
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Fire hazard Immediate (acute) health hazard
Ammonia solution
5 - 10
No.
No.
No.
Yes.
No.
Ethanedioic acid, hydrate (1:2)
1 - 2.5
No.
No.
No.
Yes.
No.
Isopropyl alcohol
1 - 2.5
Yes.
No.
No.
Yes.
No.
Name
%
Fire hazard
Sudden release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
11/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 12
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
15. Regulatory information
Signal word
:
Hazard statements
:
Precautionary measures
:
CAUTION
CAUSES EYE IRRITATION.
Contains Ammonia. May cause skin irritation. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water. If irritation persists, get medical attention. After contact with skin, wash immediately with plenty of water.
Label elements
Pennsylvania
:
The following components are listed: LIMESTONE; ETHANEDIOIC ACID, DIHYDRATE; 2-PROPANOL; AMMONIUM HYDROXIDE ((NH4)(OH))
The following components are listed: Isopropyl alcohol; Ammonia (total)
WHMIS (Canada)
Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Class D-2A: Material causing other toxic effects (Very toxic). Class E: Corrosive material
:
Canada
Canadian NPRI
:
Canada inventory
:
At least one component is not listed in DSL but all such components are listed in NDSL.
CEPA Toxic substances
:
None of the components are listed.
Canadian lists
16. Other information
Hazardous Material Information System (U.S.A.)
2
2
0
022
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
:
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Personal protection
B
12/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
Page 13
D8049596 v4.0
Conforms to USDOL OSHA 29CFR 1910.1200 HAZCOM
16. Other information
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue
Date of previous issue
Version
:::
Indicates information that has changed from previously issued version.
09/06/2016.
13/08/2014.
4
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Prepared by
:
Reckitt Benckiser LLC. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. FAX: 201-476-7770
Revision comments
:
Update as per OSHA GHS for US/CAN.
RB is a member of the CSPA Product Care Product Stewardship Program.
Key to abbreviations
:
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
13/13
09/06/2016.
Date of issue
:
SDS #
FF8043677 (D8049596)
:
Code #
D8049596 v4.0
:
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