Specific target organ
systemic toxicity - repeated
exposure (Oral)
GHS Label element
Hazard pictograms :
: C
Signal Word : Warning
Hazard Statements : H317 May cause an allergic skin reaction.
Precautionary Statements : Prevention:
ategory 2 (Blood)
H319 Causes serious eye irritation.
H373 May cause damage to organs (Blood) through prolonged
or repeated exposure if swallowed.
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of
SAFETY DATA SHEET
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Chemical Name
CAS-No.
Concentration (%)
Silicon dioxide
7631-86-9
>= 5 - < 10
Methyltri(ethylmethylketoxime)silane
22984-54-9
>= 1 - < 5
Vinyltri (methylethylketoxime) silane
2224-33-1
>= 1 - < 5
N-(3-(Trimethoxysilyl)propyl)ethylenediamine
1760-24-3
>= 0.1 - < 1
Methyltri(ethylmethylketoxime)silane
isomers
and oligomers
Not Assigned
>= 0.1 - < 1
Other hazards
None known.
SECTION 3.
Substance / Mixture : Mixture
Chemical nature : Silicone
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P363 Wash cont
Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant.
COMPOSITION/INFORMATION
Sealant
aminated clothing before reuse.
ON INGREDIENTS
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical ad-
If inhaled : If inhaled, remove to fresh air.
In case of skin contact : In case of contact, immediately flush skin with soap and plenty
vice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
Get medical attention if symptoms occur.
of water.
Remove contaminated clothing and shoes.
SAFETY DATA SHEET
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3 / 19
In case of eye contact : In case of contact, immediately flush eyes with plenty of water
If swallowed : If swallowed, DO NOT induce vomiting.
Most important symptoms
and effects, both acute and
delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection,
: May cause an allergic skin reaction.
Notes to physician : Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray
Unsuitable extinguishing
media
: N
Get medical
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Causes serious eye irritation.
May cau
exposure if swallowed.
and use the recommended personal protective equipment
when the potential for exposure exists.
Alcohol-resistant
chemical
Dry
Carbon dioxide
one known.
attention.
se damage to organs through prolonged or repeated
foam
(CO2)
Specific hazards during fire
fighting
Hazardous combustion products
Specific extinguishing methods
Special protective equipment
for fire-fighters
: Exposure to combustion products may be a hazard to health.
: Carbon oxides Silicon
oxides Formaldehyde
Nitrogen oxides (NOx)
: Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
: In the event of
Use personal protective equipment.
fire, wear self-contained breathing apparatus.
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
4 / 19
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Environmental precautions : Discharge into the environment must be avoided.
ds and materials for
Metho
containment and cleaning up
: Use personal protective equipment.
Follow safe handling advice and personal protective equipment recommendations.
Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
: Soak up with inert absorbent material.
For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be
pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to determine which regulations are applicable.
Sectio
ns 13 and 15 of this SDS provide information regarding
certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use only with adequate ventilation.
Advice on safe handling : Do not get on skin or clothing.
Do not
Do not get in
Handle in accordance with good industrial hygiene and safety
practice.
Keep away from water.
Protect from moisture.
Take care to prevent spills, waste and minimize relea
environment.
Conditions for safe storage : Keep in properly labeled containers.
Store in accordance with the particular national regulations.
Materials to avoid : Do not store with the following product types:
Strong oxidizing agents
swallow.
eyes.
se to the
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
5 / 19
Ingredients
CAS-No.
Value type
exposure)
Control parameconcentration
Basis
Silicon dioxide
7631-86-9
TWA (Dust)
20 Million
(Silica)
OSHA Z-3
TWA (Dust)
80 mg/m3
OSHA Z-3
TWA
6 mg/m3
(Silica)
NIOSH REL
Ingredients
CAS-No.
Methyltri(ethylmethylketoxime)
silane
22984-54-9
Vinyltri (methylethylketoxime)
silane
2224-33-1
N-(3ediamine
1760-24-3
Methyltri(ethylmethylketoxime)
silane isomers and oligomers
Not Assigned
Ingredients
CAS-No.
Value type
exposure)
Control parameconcentration
Basis
Ethyl methyl ketoxime
96-29-7
TWA
10 ppm
DCC OEL
Further information: Skin sensitization
TWA
10 ppm
US WEEL
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Hazardous components without workplace control parameters
(Trimethoxysilyl)propyl)ethylen
Occupational exposure limits of decomposition products
(Form of
ters / Permissible
particles per cubic
foot
/ %SiO2
(Silica)
Engineering measures : Processing may form hazardous compounds (see section
Personal protective equipment
Respiratory protection : General and local exhaust ventilation is recommended to
10).
(Form of
ters / Permissible
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardo
us chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
6 / 19
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Hand protection
Material : Impervious gloves
Remarks : Choose gloves to protect hands against chemicals depending
on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment:
Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
se precautions are for room temperature handling. Use at
The
elevated temperature or aerosol/spray applications may re-
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : paste
quire added precautions.
Color : colorless
Odor : slight
Odor Threshold : No data available
pH : Not applicable
Melting point/freezing point : No data available
Initial boiling point and boiling
range
Flash point : Not applicable
: Not applicable
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
7 / 19
Evaporation rate : Not applicable
Flammability (solid, gas) : Not classified as a flammability hazard
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : Not applicable
Relative vapor density : No data available
Relative density : 1.04
Solubility(ies)
Water solubility : No data available
Partition coefficient: noctanol/water
Autoignition temperature : No data available
: No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : Not
applicable
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
Molecular weight : No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reactions
Conditions to avoid : Exposure to moisture.
Incompatible materials : Oxidizing agents
: Use at elevated temperatures may form highly hazardous
compounds.
Can react with strong oxidizing agents.
Hazardo
contact with water or humid air.
Hazardous decomposition products will be formed at elevated
temperatures.
Water
us decomposition products will be formed upon
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
8 / 19
Hazardous decomposition products
Contact with water or hu-
SECTION 11. TOXICOLOGICAL INFORMATION
mid air
Thermal decomposition : Formaldehyde
Information on likely routes of exposure
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Exposure time: 4 h
Test atmosphere:
Assessment: The substance or mixture has no acute inhalation toxicity
Remarks: Information taken from reference works and the
literature.
Routes of exposure: Ingestion
Target Organs: Blood
Assessment: Shown to produce significant health effects in animals at concentrations of >10 to
100 mg/kg bw.
N-(3-(Trimethoxysilyl)propyl)ethylenediamine:
Routes of exposure: Ingestion
Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.
Methyltri(ethylmethylketoxime)silane
Routes of exposure: Ingestion
Target Organs: Blood
Assessment: Shown to produce significant health effects in animals at concentrations of >10 to
100 mg/kg bw.
Repeated dose toxicity
Ingredients:
Methyltri(ethylmethylketoxime)silane:
Species: Rat
Application Route: Ingestion
Target Organs: Blood
Remarks: Based on test data
isomers and oligomers:
Vinyltri (methylethylketoxime) silane:
Species: Rat
Application Route: Ingestion
Target Organs: Blood
Remarks: Based on data from similar materials
N-(3-(Trimethoxysilyl)propyl)ethylenediamine:
Application Route: Ingestion
Remarks: Based on test data
Methyltri(ethylmethylketoxime)silane
Species: Rat
Application Route: Ingestion
Target Organs: Blood
Remarks: Based on data from similar materials
Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks: During use of the material, small amounts of methylethylketoxime (MEKO) will be released. Rodents exposed to chronic MEKO inhalation throughout their lifetimes showed significant increases in liver tumor rates.
isomers and oligomers:
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
14 / 19
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Methyltri(ethylmethylketoxime)silane:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 120 mg/l
Exposure time: 96
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
Toxicity to daphnia and other
aquatic invertebrates
SARA 302 : No chemicals in this material are subject to the reporting
SARA 313 : This material does not contain any chemical components with
Calculated product RQ
Chronic Health
Hazard
requirements of SARA Title III, Section 302.
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
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Dimethyl siloxane, hydroxy-terminated
70131-67-8
70 - 90 %
Silicon dioxide
7631-86-9
5 - 10 %
Methyltri(ethylmethylketoxime)silane
22984-54-9
1 - 5 %
Dimethyl siloxane, hydroxy-terminated
70131-67-8
70 - 90 %
Silicon dioxide
7631-86-9
5 - 10 %
Methyltri(ethylmethylketoxime)silane
22984-54-9
1 - 5 %
Vinyltri (methylethylketoxime) silane
2224-33-1
1 - 5 %
US State Regulations
Pennsylvania Right To Know
New Jersey Right To Know
California Prop 65 WARNING: This product contains a chemical known in the
Methanol 67-56-1
The ingredients of this product are reported in the following inventories:
NZIoC : All ingredients listed or exempt.
State of California to cause birth defects or other reproductive
harm.
TSCA : All chemical substances in this material are included on or
exempted from listing on the TSCA Inventory of Chemical
Substances.
AICS : All ingredients listed or exempt.
IECSC : All ingredients listed or exempt.
ENCS/ISHL : All components are listed on ENCS/ISHL or exempted from
inventory listing.
KECI : All ingredients listed, exempt or notified.
PICCS : All ingredients listed or exempt.
DSL : All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
18 / 19
Instability
Health
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:
Flammability
2
Special hazard.
Full text of other abbreviations
DCC OEL : Dow Corning Guide
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
US WEEL : USA. Workplace Environmental Exposure Levels (WEEL)
DCC OEL / TWA : Time weighted average
NIOSH REL / TWA
OSHA Z-3 / TWA : 8-hour time weighted average
US WEEL / TWA : 8-hr TWA
Sources of key data used to
compile the Material Safety
Data Sheet
Revision Date : 04/04/2015
Items where changes have been made to the previous version are highlighted in the body of
this document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release
not be considered a warranty or quality specification of any type. The information pro-
shall
vided relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or
less specified in the text. Material users should review the information and recommendations
in the specific cont
cluding an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.
0
: Time-weighted average concentration for up to a 10-hour
ext of their intended manner of handling, use, processing and storage, in-
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
eral Dusts
workday during a 40-hour workweek
: Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/
in any process
2*
1
0
and
, un-
SAFETY DATA SHEET
SPIKES SPECIAL ADHESIVE
19 / 19
US / Z8
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