Safety Data Sheet
Product Identifier Big D Gel D Viscid Aerosol Deodorant
Other Means of
Identification
070
Other Identification Viscid Aerosol Deodorant
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Aerosol Products
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Aerosol Deodorant.
0286
Big D Industries, 800 535 5053, 24hr (Infotrac)
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
H222 Extremely flammable aerosol.
Precautionary Statement(s):
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
Response:
P264 Wash thoroughly after handling.
Storage:
GHS Classification
Flammable aerosol - Category 1
SDS No.:
Date of Preparation:
0286 Page
of
0601
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
Big D Gel D Viscid Aerosol Deodorant
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
Hazard Not Otherwise Classified (HNOC): Static accumulating flammable liquid can become electrostatically charged
even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Other components below reportable Levels No CAS 80-90
n-Butane 106-97-8 2.5-10
Propane 74-98-6 2.5-10
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Immediately wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 15-20 minutes. Call
a Poison Centre or doctor if you feel unwell or are concerned.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion
Rinse mouth with water. Call a Poison Centre or doctor if you feel unwell or are concerned.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can irritate the nose and throat.
If on skin:
May cause mild irritation.
If in eyes:
May cause mild irritation.
If swallowed:
Can irritate the mouth, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0286 Page
of
0602
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
Specific Hazards Arising from the Chemical
Flammable aerosol.
Closed containers may rupture violently when heated releasing contents.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
A full-body encapsulating chemical protective suit with positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
Do not touch damaged containers or spilled product unless wearing appropriate protective equipment.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Only use where there is adequate ventilation. Eliminate heat and ignition sources such as sparks, open flames, hot
surfaces and static discharge. Post "No Smoking" signs.
Conditions for Safe Storage
Store in an area that is: cool, ventilated, out of direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
n-Butane 1000 ppm 800 ppm
Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles and face shield when contact is possible.
General ventilation is usually adequate.
pH Not available
Appearance compressed gas.
Odour Not available
Odour Threshold Not available
Initial Boiling Point/Range 212 ºF (100 ºC) (estimated)
Flash Point -156.0 ºF (-104.4 ºC)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0286 Page
of
0603
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Vapour Pressure 1443.30 mm Hg (192.44 kPa) at 68 ºF
Vapour Density (air = 1) Not available
Evaporation Rate Not available
Flash Point
Relative Density (water = 1) Not available
Upper/Lower Flammability or
Explosive Limit
9.5% (estimated) (upper); 1.9% (estimated) (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature Not available
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Other Physical Property 1 Specific Gravity 0.919 Estimated
GasPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
Open flames, sparks, static discharge, heat and other ignition sources.
Incompatible Materials
Strong oxidizing agents (e.g. perchloric acid).
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
LC50: No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Inhalation; eye contact; skin contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
n-Butane 1237 mg/L (mouse) (2-hour
exposure)
Propane 658 mg/L (rat) (4-hour
exposure)
SDS No.:
Date of Preparation:
0286 Page
of
0604
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
LD50 (oral): No information was located.
Skin Corrosion/Irritation
There is limited evidence of very mild irritation.
Serious Eye Damage/Irritation
There is limited evidence of very mild irritation.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
None known.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Not specifically listed.
No information was located.
Development of Offspring
No information was located.
No information was located.
Reproductive Toxicity
No information was located.
No information was located.
Germ Cell Mutagenicity
No information was located.
No information was located.
Interactive Effects
No information was located.
LD50 (dermal): No information was located.
Sexual Function and Fertility
No information was located.
Aspiration Hazard
No information was located.
Studies are not available.
There is no information available.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
SDS No.:
Date of Preparation:
0286 Page
of
0605
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950
AEROSOLS
2.1
US DOT
Special Precautions
for User
Please note: Read Safety instructions, SDS and emergency procedures before handling. US
DOT Exceptions: LTD QTY (See CFR)(Ground)
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
Not listed on the DSL or NDSL.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
California Proposition 65: Diethanolamine CAS 111-42-2 0.1 - 1.0% by wt.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130). (n-Butane). (Propane)
Massachusetts Right To Know. (n-Butane). (Propane)
New Jersey Right To Know. (n-Butane). (Propane)
Pennsylvania Right To Know. (n-Butane). (Propane)
Rhode Island Right To Know. (n-Butane). (Propane).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class B5 Class D2B
B5 - Flammable Aerosol; D2B - Toxic (Skin irritant; Eye irritant)
SECTION 16. OTHER INFORMATION
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
February 12, 2015
SDS No.:
Date of Preparation:
0286 Page
of
0606
February 12, 2015
Product Identifier: Big D Gel D Viscid Aerosol Deodorant
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