Safety Data Sheet
Product Identifier Big D Non-Para Block, Clean Breeze
Other Means of
Identification
063300, 068500, 069100, B0469105, & B0469205
Other Identification Non-Para Block, Clean Breeze
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Restroom Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Urinal Blocks.
0376
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H340 May cause genetic defects.
H361 Suspected of damaging fertility or the unborn child.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
GHS Classification
Acute toxicity (Oral) - Category 4; Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 1;
Skin sensitization - Category 1; Germ cell mutagenicity - Category 1B; Toxic to reproduction - Category 2
SDS No.:
Date of Preparation:
0376 Page
of
0701
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
Big D Non-Para Block, Clean Breeze
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTRE/doctor.
P321 Specific treatment (see on this label).
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Alcohols, C16-18, ethoxylated, solids 68439-49-6 51.71
Sodium sulfate 7757-82-6 31.37
Fatty acids, tallow, sodium salts 8052-48-0 12.56
Precipitated silica 112926-00-8 1.29
3-Octanol, 3,7-dimethyl- 78-69-3 0.49
7-Octen-2-ol, 2-methyl-6-methylene-, dihydro
deriv.
53219-21-9 0.40
2-Phenylethanol 60-12-8 0.33
TONALIDE 21145-77-7 0.28
Cinnamaldehyde, alpha-hexyl- 101-86-0 0.24
Benzenepentanol, gamma-methyl- 55066-48-3 0.14
Live Bacterial Cultures No CAS <0.10
Skin Contact
Rinse with lukewarm, gently flowing water for 5 minutes.
Eye Contact
SECTION 4. FIRST-AID MEASURES
First-aid Measures
SDS No.:
Date of Preparation:
0376 Page
of
0702
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned.
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
If in eyes:
May cause mild irritation.
If swallowed:
Symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective
materials.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
No special clean-up methods are necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
No special precautions are necessary.
Conditions for Safe Storage
Store in an area that is: temperature-controlled, dry.
SECTION 7. HANDLING AND STORAGE
SDS No.:
Date of Preparation:
0376 Page
of
0703
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Precipitated silica 3 mg/m3 5 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. OSHA = US
Occupational Safety and Health Administration.
Not normally required if product is used as directed.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance Blue. Particle Size: Not available
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not applicable
Flash Point Not applicable
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) > 1 at 20 ºC
Upper/Lower Flammability or
Explosive Limit
Not applicable (upper); Not applicable (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not applicable (kinematic)
Surface Tension Not applicable
Basic Physical and Chemical Properties
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
SDS No.:
Date of Preparation:
0376 Page
of
0704
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
Skin Corrosion/Irritation
There is limited evidence of mild irritation.
Serious Eye Damage/Irritation
There is limited evidence of mild irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Acute Toxicity
No information was located.
Aspiration Hazard
Skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Sodium sulfate 5989 mg/kg (mouse)
Precipitated silica > 10000 mg/kg (rat) > 5000 mg/kg (rabbit)
TONALIDE 570 mg/kg (rat) 7940 mg/kg (rat)
2-Phenylethanol 400 mg/kg (guinea pig) 5 mg/kg (guinea pig)
SDS No.:
Date of Preparation:
0376 Page
of
0705
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Not specifically listed.
No information was located.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
No information was located.
Persistence and Degradability
Mobility in Soil
Bioaccumulative Potential
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic
SDS No.:
Date of Preparation:
0376 Page
of
0706
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
CEPA - National Pollutant Release Inventory (NPRI)
Part 1A. (Poly(oxy-1,2-ethanediyl)-, alpha-(4-nonylphenyl)-omega-hydroxy-, branched)
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
Massachusetts Right To Know: DiPhenyl Ether (CAS 101-84-8) Diethyl Phthalate (CAS 84-66-2)
New Jersey Right To Know: DiPhenyl Ether (CAS 101-84-8) Diethyl Phthalate (CAS 84-66-2)
Pennsylvania Right To Know: DiPhenyl Ether (CAS 101-84-8) Diethyl Phthalate (CAS 84-66-2)
Rhode Island Right To Know: Diethyl Phthalate (CAS 84-66-2).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
March 20, 2015
Revision Indicators
Not applicable.
Health - 1 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0376 Page
of
0707
March 20, 2015
Product Identifier: Big D Non-Para Block, Clean Breeze
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