Big D Non-Para Block, Cherry
Product Identifier Big D Non-Para Block, Cherry
Other Means of
Identification
065700, 066900, 068900, B0466905, & B0468905
Other Identification Non-Para Block, Cherry
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Restroom Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Urinal Blocks.
0364
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
Precautionary Statement(s):
Prevention:
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
GHS Classification
Acute toxicity (Oral) - Category 4; Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 1;
Skin sensitization - Category 1; Specific target organ toxicity (single exposure) - Category 3
SDS No.:
Date of Preparation:
0364 Page
of
0701
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
Safety Data Sheet
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves.
P280 Wear eye protection/face protection.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTRE/doctor.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P330 Rinse mouth.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Alcohols, C16-18, ethoxylated, solids 68439-49-6 51.55
Sodium sulfate 7757-82-6 31.27
Fatty acids, tallow, sodium salts 8052-48-0 12.52
Benzaldehyde 100-52-7 1.872
Precipitated silica 112926-00-8 1.35
Ethyl acetate 141-78-6 0.47
Benzyl acetate 140-11-4 0.31
n-Amyl acetate 628-63-7 0.30
2-Methylbutyl acetate 624-41-9 0.16
Live Bacterial Cultures No CAS <0.10
Skin Contact
Rinse with lukewarm, gently flowing water for 5 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
SDS No.:
Date of Preparation:
0364 Page
of
0702
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned.
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
If in eyes:
May cause mild irritation.
If swallowed:
Symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective
materials.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
No special clean-up methods are necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
No special precautions are necessary.
Conditions for Safe Storage
Store in an area that is: temperature-controlled, dry.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
SDS No.:
Date of Preparation:
0364 Page
of
0703
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Precipitated silica 3 mg/m3 5 mg/m3
Ethyl acetate 400 ppm 1400
mg/m3
Benzyl acetate 10 ppm
n-Amyl acetate 50 ppm 100 ppm 525 mg/m3
2-Methylbutyl acetate 50 ppm 100 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. OSHA = US
Occupational Safety and Health Administration.
Not normally required if product is used as directed.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance Blue. Particle Size: Not available
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not applicable
Flash Point Not applicable
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) > 1 at 20 ºC
Upper/Lower Flammability or
Explosive Limit
Not applicable (upper); Not applicable (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Formula Not applicable
Not availableDecomposition Temperature
Viscosity Not applicable (kinematic)
Basic Physical and Chemical Properties
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
SDS No.:
Date of Preparation:
0364 Page
of
0704
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
Molecular Weight Not applicable
Bulk Density Not available
Surface Tension Not applicable
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
Skin Corrosion/Irritation
There is limited evidence of mild irritation.
Serious Eye Damage/Irritation
There is limited evidence of mild irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
Acute Toxicity
Skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Sodium sulfate 5989 mg/kg (mouse)
Precipitated silica > 10000 mg/kg (rat) > 5000 mg/kg (rabbit)
Benzaldehyde > 1300 mg/kg (rat) > 2000 mg/kg (guinea pig)
Ethyl acetate 16000 mg/L (rat) 5600 mg/m3 (rat) (2-hour
exposure)
Benzyl acetate 830 mg/kg (mouse) > 5000 mg/kg (rabbit)
SDS No.:
Date of Preparation:
0364 Page
of
0705
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Not specifically listed.
No information was located.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
No information was located.
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
No information was located.
Toxicity
Persistence and Degradability
Mobility in Soil
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
Benzaldehyde 0.8-1.44 mg/L
(Lepomis
macrochirus
(bluegill); 96-hour)
Ethyl acetate 200.32-225.42 mg/L
(48-hour)
n-Amyl acetate 65 mg/L (96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
SDS No.:
Date of Preparation:
0364 Page
of
0706
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
CEPA - National Pollutant Release Inventory (NPRI)
Part 1A. (Poly(oxy-1,2-ethanediyl)-, alpha-(4-nonylphenyl)-omega-hydroxy-, branched)
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
CERCLA. (2-Methylbutyl acetate). (Ethyl acetate). (n-Amyl acetate)
Massachusetts Right To Know. (Benzaldehyde). (Ethyl acetate). (n-Amyl acetate)
New Jersey Right To Know. (Benzaldehyde). (Ethyl acetate). (Benzyl acetate). (n-Amyl acetate)
Pennsylvania Right To Know. (Benzaldehyde). (Ethyl acetate). (n-Amyl acetate)
Rhode Island RTK hazardous substances. (Ethyl acetate). (n-Amyl acetate)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
March 13, 2015
Revision Indicators
Not applicable.
Health - 1 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0364 Page
of
0707
March 13, 2015
Product Identifier: Big D Non-Para Block, Cherry
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