Safety Data Sheet
Product Identifier Big D Metered Concentrated Room Deodorant All Fragrances
Other Means of
Identification
451, 452, 454, 455, 460, 462, 463, 464, 467, 468, 469, 471, 472, 473, 474, 475, 476, 478,
482, 483, & 484
Other Identification Metered Air Freshener
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Aerosol Products
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer
Air Freshener.
0846
InfoTrac, 800-535-5053, 24hr
Restrictions on Use None known.
Date of Preparation
August 15, 2018
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
H280 Contains gas under pressure; may explode if heated.
H222 Extremely flammable aerosol.
H319 Causes serious eye irritation.
P210 Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P261 Avoid breathing gas.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear eye protection/face protection.
GHS Classification
Other Hazards
None known.
Flammable aerosol - Category 1; Gas under pressure - Compressed gas; Serious eye damage/eye irritation - Category
2A; Specific target organ toxicity (single exposure) - Category 3
SDS No.:
Date of Preparation:
0846 Page
of
0701
August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
Big D Metered Concentrated Room Deodorant All
Fragrances
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Acetone 67-64-1 75
n-Butane 106-97-8 10
Propane 74-98-6 10
Fragrance No CAS 5
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. If skin irritation occurs
get medical advice/attention.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. Remove contact lenses, if present and easy to do. If eye irritation persists, get medical
advice/attention.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned.
First-aid Comments
Get medical advice/attention if you feel unwell or are concerned.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
May cause moderate to severe irritation.
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder or appropriate foam.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Closed containers may rupture violently when heated releasing contents.
In a fire, the following hazardous materials may be generated: flammable chemicals; irritating chemicals; toxic
chemicals; very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
For a massive fire, immediately evacuate the area and use unmanned hose holder or monitor nozzles.
Fire-fighters may enter the area if positive pressure SCBA and full Bunker Gear is worn.
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
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August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use the
personal protective equipment recommended in Section 8 of this safety data sheet. Do not touch damaged containers
or spilled product unless wearing appropriate protective equipment.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway. It is good practice to prevent releases into the
environment.
Methods and Materials for Containment and Cleaning Up
Review Section 7 (Handling) of this safety data sheet before proceeding with clean-up. Ventilate the area to prevent the
gas from accumulating, especially in confined spaces.
Other Information
Report spills to local health, safety and environmental authorities, as required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Do not puncture or incinerate container even when empty. Do not spray on an open flame or other ignition source. Do
not pierce or burn container, even after use. Prevent heating. Do not use near welding operations or other high energy
sources. Only use where there is adequate ventilation. Avoid breathing in this product. Prevent skin contact. Do not get
in eyes. Wash hands thoroughly after handling this material.
Conditions for Safe Storage
Restrict access to authorized personnel only. Store in an area that is: temperature-controlled, well-ventilated, out of
direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Acetone 500 ppm 750 ppm 1000
n-Butane 1000 ppm 800 ppm
Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles and face shield when contact is possible.
General ventilation is usually adequate.
Appearance Clear gas.
Odour Not available
Odour Threshold Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
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August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
pH Not available
Partition Coefficient,
n-Octanol/Water (Log Kow)
2.36 at 20 ºC (68 ºF) (estimated) (Propane)
Vapour Pressure ~ 18280.4 mm Hg (2437.4 kPa) at 68 ºF (estimated)
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point < -247.00 ºF (-155.00 ºC) (estimated) (Acetone)
Melting Point/Freezing Point Not available (melting)
Relative Density (water = 1) ~ 0.706 (estimated) at 20 ºC (68 ºF)
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature Not available
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Other Physical Property 3 Color: Not Available
Form: Aerosol
Physical State: Gas
GasPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
High temperatures. Temperatures above 122.0 ºF (50.0 ºC)
Incompatible Materials
None known.
Not corrosive to metals.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Information presented below is for the entire product, unless otherwise specified.
Ingestion; inhalation; skin contact; eye contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Acetone 76 mg/kg (mouse) (4-hour
exposure) (gas)
5800 mg/kg (rat) 20000 mg/kg (rabbit)
SDS No.:
Date of Preparation:
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August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
Skin Corrosion/Irritation
Human experience and animal tests show no or very mild irritation.
Serious Eye Damage/Irritation
Human experience shows serious eye irritation.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
May be harmful based on information for closely related materials.
Skin Absorption
No information was located.
Ingestion
Not a relevant route of exposure (gas).
Not harmful based on information for closely related chemicals.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Not known to be a respiratory sensitizer. Not known to be a skin sensitizer.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
Not known to harm the unborn child.
Reproductive Toxicity
Not known to cause effects on sexual function or fertility.
Germ Cell Mutagenicity
Not mutagenic.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
Not known to cause effects on or via lactation.
Not known to be an aspiration hazard.
Aspiration Hazard
n-Butane 1237 mg/L (mouse) (2-hour
exposure)
Propane 658 mg/L (rat) (4-hour
exposure)
Chemical Name IARC ACGIH® NTP OSHA
Acetone A4
Harmful, with long lasting effects to aquatic life.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
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Date of Preparation:
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August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
This product or its degradation products are expected to bioaccumulate.
Studies are not available.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Acetone 4740-6330 mg/L
(Oncorhynchus
mykiss (rainbow
trout); 96-hour; fresh
water)
21.6-23.9 mg/L
(Daphnia magna
(water flea); 48-hour;
fresh water)
SECTION 13. DISPOSAL CONSIDERATIONS
This product is classified as a D001 Hazardous Waste under RCRA. This product and its container must be disposed of
as hazardous waste. Do NOT dump into any sewers, on the ground or into any body of water. The container for this
product can present explosion or fire hazards, even when emptied. Do not cut, puncture, or weld on or near this
container. The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are
the responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950
Aerosols, flammable
2.1
US DOT
1950
Aerosols, flammable
2.1
IATA (Air)
1950
Aerosols, flammable
2.1
IMO (Marine)
Special Precautions
for User
Not applicable
Other Information
DOT: This material may ship by passenger plane as: UN1950, Aerosols, 2.1, Limited
Quantity. Must have a flammable label and Limited Quantity (Y) label if shipping by air.
DOT: This product meets the exception requirements of section 173.306 as a limited quantity
and may be shipped as a limited quantity.
IATA: This product meets the exception requirements as a limited quantity and may be
shipped as a limited quantity. Follow all rules and regulations to do so.
IMDG: This products meets the exception requirements as a limited quantity and may be
shipped as a limited quantity. Follow all rules and regulations.
Emergency Response
Guide No.
10L
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
Safety, Health and Environmental Regulations
SDS No.:
Date of Preparation:
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August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
CERCLA. (Acetone)
US Federal. (Acetone)
New Jersey Right To Know. (Propane). (n-Butane)
Pennsylvania Right To Know. (Acetone). (n-Butane). (Propane)
the SDS contains all of the information required by the Controlled Products Regulations.
Disclaimer
This Safety Data Sheet has been prepared in accordance with the Globally Harmonized
System for the Classification and Labeling of Chemical (GHS) TO the best of our knowledge
the information herein is accurate. However, the supplier makes no warranty and assume no
liability resulting from its use. In No event shall the supplier be liable for any claims, losses, or
damages of any third party resulting from the use of or reliance upon this information.
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Allin McDonald
Phone No.
405 618 9791
Health - 1 Flammability - 3 Instability - 0
SDS No.:
Date of Preparation:
0846 Page
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0707
August 15, 2018
Product Identifier: Big D Metered Concentrated Room Deodorant All Fragrances
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